Sources and sinks for atmospheric N_2O

Observations of the temporal and spatial distribution of N_2O in solution are not yet sufficient to permit quantitative assessment of the role of the ocean in the budget of atmospheric N_2O. Consideration of the global nitrogen cycle suggests that the land should be the primary source of N_2O. The gas is removed in the atmosphere by photolysis and by reaction with O(¹D), and there may be additional sinks in the ocean

Sources and sinks for atmospheric N2O

Observations of the temporal and spatial distribution of N2O in solution are not yet sufficient to permit quantitative assessment of the role of the ocean in the budget of atmospheric N2O. Consideration of the global nitrogen cycle suggests that the land should be the primary source of N2O. The gas is removed in the atmosphere by photolysis and by reaction with O(1D), and there may be additional sinks in the ocean

Ozone depletion, greenhouse gases, and climate change

This symposium was organized to study the unusual convergence of a number of observations, both short and long term that defy an integrated explanation. Of particular importance are surface temperature observations and observations of upper atmospheric temperatures, which have declined significantly in parts of the stratosphere. There has also been a dramatic decline in ozone concentration over Antarctica that was not predicted. Significant changes in precipitation that seem to be latitude dependent have occurred. There has been a threefold increase in methane in the last 100 years; this is a problem because a source does not appear to exist for methane of the right isotopic composition to explain the increase. These and other meteorological global climate changes are examined in detail

Green Solvent Selection for Emulsifiable Concentrate Agrochemical Formulations

Emulsifiable concentrates are a common form of agrochemical formulation in which a high quantity of active ingredient is typically dissolved in an aromatic hydrocarbon solvent. There are considerable health and environmental hazards associated with the solvents in emulsifiable concentrates, and finding alternatives was deemed worthy of investigation. Using a combination of in silico modeling and experimental testing, a number of alternative safer solvents have been tested for the agrochemicals pendimethalin, prochloraz, and pyraclostrobin. Cyclohexanone, diethyl carbonate, ethyl acetate, and dihydrolevoglucosenone (Cyrene) were observed to be effective solvents

Vertical Transport Rates in the Stratosphere in 1993 from Observations of CO2, N2O and CH4

Measurements of CO2, N2O and CH4 are analyzed to define hemispheric average vertical exchange rates in the lower stratosphere from November 1992 to October 1993. Effective vertical diffusion coefficients were small in summer, less than or equal to 1 m(exp 2)/sec at altitudes below 25 km; values were similar near the tropopause in winter, but increased markedly with altitude. The analysis suggests possibly longer residence times for exhaust from stratospheric aircraft, and more efficient transport from 20 km to the middle stratosphere, than predicted by many current models. Seasonally-resolved measurements of stratospheric CO2 and N2O provide significant new constraints on rates for global-scale vertical transport