Structural and Physical Properties of CaFe4As3 Single Crystals

We report the synthesis, and structural and physical properties of CaFe4As3 single crystals. Needle-like single crystals of CaFe4As3 were grown out of Sn flux and the compound adopts an orthorhombic structure as determined by X-ray diffraction measurements. Electrical, magnetic, and thermal properties indicate that the system undergoes two successive phase transitions occurring at TN1 ~ 90 K and TN2 ~ 26 K. At TN1, electrical resistivities (\rho(b) and \rho(ac)) are enhanced while magnetic susceptibilities (\chi(b) and \chi(ac)) are reduced in both directions parallel and perpendicular to the b-axis, consistent with the scenario of antiferromagnetic spin-density-wave formation. At TN2, specific heat reveals a slope change, and \chi(ac) decreases sharply but \chi(b) has a clear jump before it decreases again with decreasing temperature. Remarkably, both \rho(b) and \rho(ac) decrease sharply with thermal hysteresis, indicating the first-order nature of the phase transition at TN2. At low temperatures, \rho(b) and \rho(ac) can be described by {\rho} = {\rho}0 + AT^\alpha ({\rho}0, A, and {\alpha} are constants). Interestingly, these constants vary with applied magnetic field. The ground state of CaFe4As3 is discussed.Comment: 15 pages, 8 figures, Submitted to Physical Review

Origin of the butterfly magnetoresistance in a Dirac nodal-line system

We report a study on the magnetotransport properties and on the Fermi surfaces (FS) of the ZrSi(Se,Te) semimetals. Density Functional Theory (DFT) calculations, in absence of spin orbit coupling (SOC), reveal that both the Se and the Te compounds display Dirac nodal lines (DNL) close to the Fermi level $\varepsilon_F$ at symmorphic and non-symmorphic positions, respectively. We find that the geometry of their FSs agrees well with DFT predictions. ZrSiSe displays low residual resistivities, pronounced magnetoresistivity, high carrier mobilities, and a butterfly-like angle-dependent magnetoresistivity (AMR), although its DNL is not protected against gap opening. As in Cd$_3$As$_2$, its transport lifetime is found to be 10$^2$ to 10$^3$ times larger than its quantum one. ZrSiTe, which possesses a protected DNL, displays conventional transport properties. Our evaluation indicates that both compounds most likely are topologically trivial. Nearly angle-independent effective masses with strong angle dependent quantum lifetimes lead to the butterfly AMR in ZrSiSe

Dimensional crossover in the electrical and magnetic properties of the layered LaSb2 superconductor under pressure: The role of phase fluctuations

We present electrical transport, magnetization, and ac as well as dc magnetic susceptibility measurements of the highly anisotropic compound LaSb2. Our data display a very broad anisotropic transition upon cooling below 2.5 K into a clean superconducting state with a field-dependent magnetization that is consistent with type I behavior. We identify distinct features of two-dimensionality in both the transport and magnetic properties. Application of hydrostatic pressure induces a two- to three-dimensional crossover evidenced by a reduced anisotropy and transition width. The superconducting transition appears phase-fluctuation-limited at ambient pressure, with fluctuations observed for temperatures greater than eight times the superconducting critical temperature. © 2011 American Physical Society

A new spin-anisotropic harmonic honeycomb iridate

The physics of Mott insulators underlies diverse phenomena ranging from high temperature superconductivity to exotic magnetism. Although both the electron spin and the structure of the local orbitals play a key role in this physics, in most systems these are connected only indirectly --- via the Pauli exclusion principle and the Coulomb interaction. Iridium-based oxides (iridates) open a further dimension to this problem by introducing strong spin-orbit interactions, such that the Mott physics has a strong orbital character. In the layered honeycomb iridates this is thought to generate highly spin-anisotropic interactions, coupling the spin orientation to a given spatial direction of exchange and leading to strongly frustrated magnetism. The potential for new physics emerging from such interactions has driven much scientific excitement, most recently in the search for a new quantum spin liquid, first discussed by Kitaev \cite{kitaev_anyons_2006}. Here we report a new iridate structure that has the same local connectivity as the layered honeycomb, but in a three-dimensional framework. The temperature dependence of the magnetic susceptibility exhibits a striking reordering of the magnetic anisotropy, giving evidence for highly spin-anisotropic exchange interactions. Furthermore, the basic structural units of this material suggest the possibility of a new family of structures, the `harmonic honeycomb' iridates. This compound thus provides a unique and exciting glimpse into the physics of a new class of strongly spin-orbit coupled Mott insulators.Comment: 12 pages including bibliography, 5 figure