Fabrication of high temperature piezoelectric ceramics by sol gel method

This research covers the fabrication of piezoelectric ceramics using a sol gel method. Commercial high temperature transducers are typically fabricated by a milled oxide method. The sol gel method presented here produced purer samples that can be prepared at lower temperatures than conventional milled oxide preparations. The performance of the samples as piezoelectric transducers was also investigated, with the samples produced by sol gel method exceeding the piezoelectric response of the commercial samples

Electron paramagnetic resonance investigation of the free radicals in the gas and particulate phases of cigarette smoke using spin-trapping techniques

Free radicals in cigarette smoke have been studied using spin trapping EPR techniques. 2R4F reference cigarettes were smoked using 35 ml puff volumes of 2 seconds duration, once every 60 seconds. The particulate phase of the smoke was separated from the gas phase by passing the smoke through a Cambridge filter pad. For both phases, free radicals were measured and identified. A range of spin-traps was employed: PBN, DMPO, DEPMPO, and DPPH-PBN. In the gas-phase, short-lived carbon- and oxygen- centered radicals were identified; the ratios between them changed during the smoking runs. For the first puffs, C-centered radicals predominated while for the later puffs, O-centered radicals were mainly observed. The particulate phase and the ‘tar’ were studied as well

Journal of Physics: Conference Series / Regional lung deposition of aged and diluted sidestream tobacco smoke

Since aged and diluted smoke particles are in general smaller and more stable than mainstream tobacco smoke, it should be possible to model their deposition on the basis of their measured particle diameters. However in practice, measured deposition values are consistently greater than those predicted by deposition models. Thus the primary objective of this study was to compare theoretical predictions obtained by the Monte Carlo code IDEAL with two human deposition studies to attempt to reconcile these differences. In the first study, male and female volunteers inhaled aged and diluted sidestream tobacco smoke at two steady-state concentrations under normal tidal breathing conditions. In the second study, male volunteers inhaled aged and diluted sidestream smoke labelled with 212Pb to fixed inhalation patterns. Median particle diameters in the two studies were 125 nm (CMD) and 210 nm (AMD), respectively. Experimental data on total deposition were consistently higher than the corresponding theoretical predictions, exhibiting significant inter-subject variations. However, measured and calculated regional deposition data are quite similar to each other, except for the extra-thoracic region. This discrepancy suggests that either the initial particle diameter decreases upon inspiration and/or additional deposition mechanisms are operating in the case of tobacco smoke particles.(VLID)220918

Electron paramagnetic resonance of the free radicals in the gas-and particulate phases of cigarette smoke using spin-trapping. ARKIVOC

Abstract Free radicals in cigarette smoke have been studied using spin trapping EPR techniques. 2R4F reference cigarettes were smoked using 35 ml puff volumes of 2 seconds duration, once every 60 seconds. The particulate phase of the smoke was separated from the gas phase by passing the smoke through a Cambridge filter pad. For both phases, free radicals were measured and identified. A range of spin-traps was employed: PBN, DMPO, DEPMPO, and DPPH-PBN. In the gas-phase, short-lived carbon-and oxygen-centered radicals were identified; the ratios between them changed during the smoking runs. For the first puffs, C-centered radicals predominated while for the later puffs, O-centered radicals were mainly observed. The particulate phase and the 'tar' were studied as well

Assessment of an in vitro whole cigarette smoke exposure system: The Borgwaldt RM20S 8-syringe smoking machine

<p>Abstract</p> <p>Background</p> <p>There have been many recent developments of <it>in vitro </it>cigarette smoke systems closely replicating <it>in vivo </it>exposures. The Borgwaldt RM20S smoking machine (RM20S) enables the serial dilution and delivery of cigarette smoke to exposure chambers for <it>in vitro </it>analyses. In this study we have demonstrated reliability and robustness testing of the RM20S in delivering smoke to <it>in vitro </it>cultures using an in-house designed whole smoke exposure chamber.</p> <p>Results</p> <p>The syringe precision and accuracy of smoke dose generated by the RM20S was assessed using a methane gas standard and resulted in a repeatability error of ≤9%. Differential electrical mobility particle spectrometry (DMS) measured smoke particles generated from reference 3R4F cigarettes at points along the RM20S. 53% ± 5.9% of particles by mass reached the chamber, the remainder deposited in the syringe or connecting tubing and ~16% deposited in the chamber. Spectrofluorometric quantification of particle deposition within chambers indicated a positive correlation between smoke concentration and particle deposition. <it>In vitro </it>air-liquid interface (ALI) cultures (H292 lung epithelial cells), exposed to whole smoke (1:60 dilution (smoke:air, equivalent to ~5 μg/cm²)) demonstrated uniform smoke delivery within the chamber.</p> <p>Conclusions</p> <p>These results suggest this smoke exposure system is a reliable and repeatable method of generating and exposing ALI <it>in vitro </it>cultures to cigarette smoke. This system will enable the evaluation of future tobacco products and individual components of cigarette smoke and may be used as an alternative <it>in vitro </it>tool for evaluating other aerosols and gaseous mixtures such as air pollutants, inhaled pharmaceuticals and cosmetics.</p

Interaction between SH0 guided waves and tilted surface-breaking cracks in plates

The interaction between SH0 guided waves and simple defects is well understood and documented, and the SH0 and related torsional guided waves are commonly used in inspection. However, tilted and branching cracks, for which vertical notches are a poor approximation, are found in some environments, particularly when pipes are buried in alkaline soils. This paper studies the interaction between SH0 guided waves and tilted, surface-breaking cracks, investigating the effect of the tilt and depth of the defect. The incident wave interacts with the tilted crack to generate a transmitted wave, a reflected wave and a wave trapped below the crack. It is shown that the direction of the tilt of the crack relative to the incident wave direction does not affect the scattering behaviour. Additionally, the axial extent of the crack plays a major role in the reflectivity of the crack, leading to transmission nulls in some configurations. These transmission nulls appear for all crack depths, the frequency range over which the transmission is significantly reduced increasing with crack depth. This behaviour is shown to be analogous to the acoustic energy flow in a duct when a Helmholtz resonator is introduced. The null is not seen above the SH1 cut-off as the propagating signals are no longer mono-modal. The existence of a transmission null and corresponding reflection maximum is promising for the detection of small defects and measurement of the frequency at which the null occurs will assist with defect characterisation. Experimental validations of the key results are presented