Dichloromethylation of enones by carbon nitride photocatalysis

Small organic radicals are ubiquitous intermediates in photocatalysis and are used in organic synthesis to install functional groups and to tune electronic properties and pharmacokinetic parameters of the final molecule. Development of new methods to generate small organic radicals with added functionality can further extend the utility of photocatalysis for synthetic needs. Herein, we present a method to generate dichloromethyl radicals from chloroform using a heterogeneous potassium poly(heptazine imide) (K-PHI) photocatalyst under visible light irradiation for C1-extension of the enone backbone. The method is applied on 15 enones, with γ,γ-dichloroketones yields of 18–89%. Due to negative zeta-potential (−40 mV) and small particle size (100 nm) K-PHI suspension is used in quasi-homogeneous flow-photoreactor increasing the productivity by 19 times compared to the batch approach. The resulting γ,γ-dichloroketones, are used as bifunctional building blocks to access value-added organic compounds such as substituted furans and pyrroles

Experimental Investigation of the Effect of Transient Overvoltages on XLPE-insulated HVDC Cables

HVDC cables are subject to several types of impulses superimposed on the rated DC voltage during their service lifetime. Temporary Overvoltages (TOVs) and Superimposed Switching impulses (SSIs) are considered some of the most challenging due to the relatively long impulse duration. This paper aims at investigating experimentally the effect of TOVs and SSIs on XLPE insulation for extruded HVDC cables. 0.15-mm-thick DC-XLPE specimens, aged by applying TOVs and SSIs, are characterized using dielectric analyzer and Fourier Transform InfraRed spectroscopy (FTIR) to detect the aging effects on the insulation. Results show an increase in the imaginary part of permittivity, ε", accompanied with the appearance of additional dipolar polarization losses peaks. The amplitude and frequency of the aforementioned peaks vary with the amplitude and the number of applied TOVs and SSIs. An increase in electrical conductivity is also noticed with aging. FTIR results show absorbance peaks in the aged specimens likely due to the intramolecular bonds rupture accompanied with the formation of aging products. In summary, SSIs and TOVs cause a noticeable reduction of insulating properties in XLPE specimens. The higher the peak of the transient, the greater the aging effect

PRIMI RISULTATI DI UN INDAGINE SULLO STATO DELLE SISTEMAZIONI IDRAULICO-FORESTALI NEL BACINO DELL’ARNO

Il presente lavoro è relativo ai risultati ottenuti con il primo stato d’avanzamento di una ricerca sullo stato delle Sistemazioni Idraulico-Forestali per assegnate aree di indagine comprese nel bacino del fiume Arno affidata dall’ Autorità di Bacino del Fiume Arno al Dipartimento di Ingegneria Agraria e Forestale dell’Università degli Studi di Firenze. Innanzi tutto, è stata condotta un’analisi preventiva, mediante un database, di documentazione relativa alle opere idrauliche già censite in precedenti lavori (prof. Grazi) con identificazione della posizione geografica delle opere stesse con l’ausilio di software GIS. A questa prima fase sono seguiti la predisposizione di una opportuna scheda di rilievo (sia cartacea sia elettronica) e quindi sopralluoghi in campo condotti mediante l’ausilio di un GPS collegato a computer palmare per il supporto cartografico di base. Rilievi di dettaglio sono stati condotti nei torrenti dell’area del Mugello, già oggetto di studi risalenti a una trentina di anni fa per la valutazione delle pendenze di compensazione (Falciai et al.) che sono stati utilizzati spesso in letteratura (Ferro et al., Pica et al., etc.). Con riferimento ad altre zone campione del bacino (es. Casentino e Area Fiorentina), la documentazione storica ed il sopralluogo in campo (su base statistica) ha avuto lo scopo di rintracciare le opere esistenti e verificare l’attendibilità e la confrontabilità dei vari censimenti eseguiti anche da altri Enti preposti. In particolare si è analizzato il dimensionamento delle opere ed il loro stato attuale di conservazione ed efficienza, confrontandolo con quanto riportato in eventuali elaborati progettuali e nei censimenti precedenti. Eventuali danneggiamenti dei manufatti possono essere derivati dalle valutazioni in sede progettuale, da scarsa o inesistente manutenzione o da mutate caratteristiche in alveo e nel bacino. Per avere qualche indicazione in proposito si è valutata la portata di progetto a partire dalle dimensioni delle gavete considerate come stramazzi in parete grossa e se ne è stimato il tempo di ritorno, mediante i modelli AlTo (Regione Toscana) e Idrarno (Autorità di Bacino). Questa fase ha richiesto un lavoro preventivo di queries spaziali che hanno lo scopo di attribuire il codice dell’asta a cui appartengono le opere idrauliche in esame (all’interno del reticolo idrografico del modello AlTo e all’interno del reticolo “Sistema Acque” dell’Autorità di Bacino dell’Arno). Questa operazione consente, inoltre, il collegamento tra il contenuto informativo del geodatabase dell’Autorità di Bacino con il sistema di regionalizzazione delle portate di piena della Regione Toscana. Mediante la misura delle caratteristiche dimensionali dell’opera si sono cercate di ricavare anche indicazioni statistiche riguardo alla pendenza di compensazione dei corsi d’acqua in esame. Le verifiche in campo ha permesso anche una descrizione delle condizioni generali dell’alveo in cui sono situate le opere e dei versanti siti in prossimità delle opere stesse. I dati raccolti sono stati immessi in un geodatabase opportunamente costruito secondo lo standard di quello esistente presso l’Autorità di Bacino del Fiume Arno e quindi elaborati per la ricerca delle relazioni tra le caratteristiche delle opere e la pendenza attuale dell’alveo nonché la stima della necessità, per i corsi d’acqua esaminati, di opere atte a garantire la continuità fluviale per la ittiofauna (Pini Prato e Barneschi)

A-DInSAR performance for updating landslide inventory in mountain areas. An example from Lombardy region (Italy)

This work focuses on the capabilities and limitations of the Advanced Satellite SAR (Synthetic Aperture Radar) Interferometry (A-DInSAR) in wooded and mountainous regions, with the aim to get insights on the performances for studying slow-moving landslides. The considered critical issues are related to the SAR acquisition geometries (angle of incidence of the satellite line of sight, ascending and descending geometries) and to the physical and morphological features of the slopes (land use, aspect and slope angles), which influence the measuring points coverage. 26 areas in Lombardy Region (Italy), affected by known slope instability phenomena, have been analyzed through A-DInSAR technique, using COSMO-SkyMed images. The results allowed to outline general considerations about the effectiveness of A-DInSAR analysis of a single dataset (descending or ascending dataset), selected accordingly to the aspect of the slopes. Moreover, we aimed to quantitatively describe the capability to update the state of activity of several previously mapped landslides using satellite SAR Interferometry results. Although in a wooded and mountainous region, where the chances of retrieving radar targets for satellite SAR analysis are generally low, the A-DInSAR results have allowed to detect landslides’ reactivations or new landslides and to update the inventory for about 70% of the investigated areas

Effect of material elastic properties and surface roughness on grip performances of ski boot soles under wet and icy conditions

A set of thermoplastic materials employed in soles for alpine skiing boots were characterized in terms of chemical composition, cristallinity, hardness, surface roughness, and grip. The results of friction experiments on different substrates reproducing the real environmental scenarios point out that materials provide more grip as they become softer. Moreover, higher roughness results in lower dynamic coefficient of friction (COF). Finite element simulations corroborate the experimental measures of COF and let to rationalize the role of material elasticity and surface roughness on the frictional characteristics of soles. The measure of grip on an inclined wet surface provides analogous results, indicating that COF can be used as key performance indicator in the design of ski-boot soles and of other anti-slip equipments in wet and icy environments

Demographic genetics of the endangered Amiata donkey breed

The demogenetic structure of the Amiata donkey, an endangered breed from Central Italy, was investigated using information from pedigrees. Genealogical data of 602 donkeys reared in Tuscany were recorded in a database and analysed by the computer package ENDOG. Population size increased from 89 subjects in 1995 to 503 (129 males and 374 females) in 2005. Animals were distributed among 152 herds, but the effective number of herds was 21, suggesting that a small number of herds provided stallions for the entire breed. The maximum number of traced generation was 4, the mean maximum generation was 1.14, the mean com- plete generation was 0.53, and the mean equivalent generation was 0.78. The average relatedness coeffi- cient (AR) in the 503 alive animals was 0.94% while the mean F was 0.29% so the effective population size was 172.41. Among 24 animals with a 4-generation history, 3 (12.5%) were 25% inbred. Although the incompleteness of genealogical information did not permit accurate inference of the current values of popu- lation genetic parameters, the present work represents a first step towards an efficient management of the breed

Genetic variability of three local cattle breeds (Calvana, Pontremolese, Garfagnina) by STR analysis

AbstractThe dramatic size contraction of local cattle breeds due to replacement with cosmopolite improved breeds highlights the need for native genetic resources conservation. In 1985, the Anagraphic Register of local cattle breeds and small-size ethnic groups was established by the Italian Ministry of Agriculture and Forestry. Calvana, Pontremolese and Garfagnina are among the included breeds. They are all native from Tuscany. Present breeding area covers the provinces of Firenze, Prato, Pistoia and Siena for the Calvana breed (around 280 heads), while it is restricted to the province of Lucca for both Garfagnina (around 180 heads) and Pontremolese. This latter breed consists, nowadays, of less than 40 heads, while being around 15000 in 1940s.The characterization of the genetic structure and variability via molecular markers could provide useful information for breed management and conservation. In the present study, a total of 149 animals, evenly distributed among the three breeds, were genetically char..

Factorization methods for Noncommutative KP and Toda hierarchy

We show that the solution space of the noncommutative KP hierarchy is the same as that of the commutative KP hierarchy owing to the Birkhoff decomposition of groups over the noncommutative algebra. The noncommutative Toda hierarchy is introduced. We derive the bilinear identities for the Baker--Akhiezer functions and calculate the $N$-soliton solutions of the noncommutative Toda hierarchy.Comment: 7 pages, no figures, AMS-LaTeX, minor corrections, final version to appear in Journal of Physics