On the heterogeneous character of water's amorphous polymorphism

In this letter we report {\it in situ} small--angle neutron scattering results on the high--density (HDA) and low-density amorphous (LDA) ice structures and on intermediate structures as found during the temperature induced transformation of HDA into LDA. We show that the small--angle signal is characterised by two $Q$ regimes featuring different properties ($Q$ is the modulus of the scattering vector defined as $Q = 4\pi\sin{(\Theta)}/\lambda_{\rm i}$ with $\Theta$ being half the scattering angle and $\lambda_{\rm i}$ the incident neutron wavelength). The very low--$Q$ regime ($< 5\times 10^{-2}$ \AA $^{-1}$) is dominated by a Porod--limit scattering. Its intensity reduces in the course of the HDA to LDA transformation following a kinetics reminiscent of that observed in wide--angle diffraction experiments. The small--angle neutron scattering formfactor in the intermediate regime of $5 \times 10^{-2} < Q < 0.5$ \AA$^{-1}$ HDA and LDA features a rather flat plateau. However, the HDA signal shows an ascending intensity towards smaller $Q$ marking this amorphous structure as heterogeneous. When following the HDA to LDA transition the formfactor shows a pronounced transient excess in intensity marking all intermediate structures as strongly heterogeneous on a length scale of some nano--meters

Incident Analysis &amp; Digital Forensics in SCADA and Industrial Control Systems

SCADA and industrial control systems have been traditionally isolated in physically protected environments. However, developments such as standardisation of data exchange protocols and increased use of IP, emerging wireless sensor networks and machine-to-machine communication mean that in the near future related threat vectors will require consideration too outside the scope of traditional SCADA security and incident response. In the light of the significance of SCADA for the resilience of critical infrastructures and the related targeted incidents against them (e.g. the development of stuxnet), cyber security and digital forensics emerge as priority areas. In this paper we focus on the latter, exploring the current capability of SCADA operators to analyse security incidents and develop situational awareness based on a robust digital evidence perspective. We look at the logging capabilities of a typical SCADA architecture and the analytical techniques and investigative tools that may help develop forensic readiness to the level of the current threat environment requirements. We also provide recommendations for data capture and retention

Ammonia adsorption and decomposition on a tungsten /211/ surface

Ammonia adsorption and decomposition on tungsten 211 surface studied by mass spectrometry, electron diffraction, and changes in work functio

First steps in the oxidation of a /110/ nickel surface

Initial steps in oxidation of nickel surface studied using low energy back-reflection electron diffractio

Electron beam chemistry produces high purity metals

Application of radiation chemistry for deposition of metals by irradiation of aqueous solutions with high energy electrons is presented. Design of reaction vessel for irradiation of solution is illustrated. Features of radiochemical technique and procedures followed are described

Species Abundance Patterns in Complex Evolutionary Dynamics

An analytic theory of species abundance patterns (SAPs) in biological networks is presented. The theory is based on multispecies replicator dynamics equivalent to the Lotka-Volterra equation, with diverse interspecies interactions. Various SAPs observed in nature are derived from a single parameter. The abundance distribution is formed like a widely observed left-skewed lognormal distribution. As the model has a general form, the result can be applied to similar patterns in other complex biological networks, e.g. gene expression.Comment: 4 pages, 3 figures. Physical Review Letters, in pres