6 research outputs found
Equipartition of Current in Parallel Conductors on Cooling Through the Superconducting Transition
Our experiments show that for two or more pieces of a wire, of different
lengths in general, combined in parallel and connected to a dc source, the
current ratio evolves towards unity as the combination is cooled to the
superconducting transition temperature Tc, and remains pinned at that value
below it. This re-distribution of the total current towards equipartition
without external fine tuning is a surprise. It can be physically understood in
terms of a mechanism that involves the flux-flow resistance associated with the
transport current in a wire of type-II superconducting material. It is the fact
that the flux-flow resistance increases with current that drives the current
division towards equipartition.Comment: Revised version of J.Phys. Condens.Matter; vol. 18(2006) L143-L147 14
pages including 3 figures; provided an explanation in terms of the physical
mechanism of flux flow induced resistance that is proportional to the
impressed current. We are adding a simple, physically robust derivation of
our equipartition without taking resort to the minimum dissipation principl
Equipartition of current in parallel conductors on cooling through the superconducting transition
Our experiments show that for two or more pieces of a wire, of different lengths in general, combined in parallel and connected to a dc source, the current ratio evolves towards unity as the combination is cooled to the superconducting transition temperature Tc, and remains pinned at that value below it. This redistribution of the total current towards equipartition without external fine-tuning is a surprise. It can be physically understood in terms of a mechanism that involves the flux-flow resistance associated with the transport current in a wire of type-II superconducting material. It is a fact that the flux-flow resistance increases with the current that drives the current division towards equipartition
HSQC experiment of probe molecules aligned in thermotropic liquid crystals: Sensitivity and resolution enhancement in the indirect dimension
The spectra of molecules oriented in liquid crystalline media are dominated by partially averaged dipolar couplings. In the HSQC, due to the inefficient hetero-nuclear dipolar decoupling in the indirect dimension, normally carried out by using a \pi pulse, there is a considerable loss of resolution. Furthermore, in such strongly orienting media the and dipolar couplings leads to fast dephasing of transverse magnetization causing inefficient polarization transfer and hence the loss of sensitivity in the indirect dimension. In this study we have carried out HSQC experiment with efficient polarization transfer from to for molecules aligned in liquid crystalline media. The homonuclear dipolar decoupling using FFLG during the INEPT transfer delays and also during evolution period combined with the \pi pulse heteronuclear decoupling in the period has been applied. The studies showed a significant reduction in partially averaged dipolar couplings and thereby enhancement in the resolution and sensitivity in the indirect dimension. This has been demonstrated on pyridazine and pyrimidine oriented in the liquid crystal. The two closely resonating carbons in pyrimidine are better resolved in the present study compared to the earlier work [H.S. Vinay Deepak, Anu Joy, N. Suryaprakash, Determination of natural abundance and dipolar couplings of molecules in a strongly orienting media using two-dimensional inverse experiments, Magn. Reson. Chem. 44(2006) 553–565]
13C-1H HSQC Experiment of Probe Molecules Aligned in Thermotropic Liquid Crystals: Sensitivity and Resolution Enhancement in the Indirect Dimension
The spectra of molecules oriented in liquid crystalline media are dominated by partially averaged dipolar couplings. In the 13C–1H HSQC, due to the inefficient hetero-nuclear dipolar decoupling in the indirect dimension, normally carried out by using a π pulse, there is a considerable loss of resolution. Furthermore, in such strongly orienting media the 1H–1H and 13C–1H dipolar couplings leads to fast dephasing of transverse magnetization causing inefficient polarization transfer and hence the loss of sensitivity in the indirect dimension. In this study we have carried out 13C–1H HSQC experiment with efficient polarization transfer from 1H to 13C for molecules aligned in liquid crystalline media. The homonuclear dipolar decoupling using FFLG during the INEPT transfer delays and also during evolution period combined with the π pulse heteronuclear decoupling in the t1 period has been applied. The studies showed a significant reduction in partially averaged dipolar couplings and thereby enhancement in the resolution and sensitivity in the indirect dimension. This has been demonstrated on pyridazine and pyrimidine oriented in the liquid crystal. The two closely resonating carbons in pyrimidine are better resolved in the present study compared to the earlier work [H.S. Vinay Deepak, Anu Joy, N. Suryaprakash, Determination of natural abundance 15N–1H and 13C–1H dipolar couplings of molecules in a strongly orienting media using two-dimensional inverse experiments, Magn. Reson. Chem. 44 (2006) 553–565]
Equipartition of Current in Parallel Conductors on Cooling Through the Superconducting Transition
Our experiments show that for two or more pieces of different lengths of a wire combined in parallel and connected to a dc source, the current ratio evolves towards unity as the combination is cooled to the superconducting transition temperature Tc, and remains pinned at that value below it. This equipartition of the total current is a surprise, but can be understood in terms of the progressive depression of superconducting fluctuations in the transition region due to the transport current. This equipartition without fine tuning is derived analytically from the Onsager-Rayleigh least dissipation principle governing the self organization (redistribution) of the current
Equipartition of Current in Parallel Conductors on Cooling Through the Superconducting Transition
Our experiments show that for two or more pieces of different lengths of a wire combined in parallel and connected to a dc source, the current ratio evolves towards unity as the combination is cooled to the superconducting transition temperature Tc, and remains pinned at that value below it. This equipartition of the total current is a surprise, but can be understood in terms of the progressive depression of superconducting fluctuations in the transition region due to the transport current. This equipartition without fine tuning is derived analytically from the Onsager-Rayleigh least dissipation principle governing the self organization (redistribution) of the current