81 research outputs found
Large oxygen-isotope effect in Sr_{0.4}K_{0.6}BiO_{3}: Evidence for phonon-mediated superconductivity
Oxygen-isotope effect has been investigated in a recently discovered
superconductor Sr_{0.4}K_{0.6}BiO_{3}. This compound has a distorted perovskite
structure and becomes superconducting at about 12 K. Upon replacing ^{16}O with
^{18}O by 60-80%, the T_c of the sample is shifted down by 0.32-0.50 K,
corresponding to an isotope exponent of alpha_{O} = 0.40(5). This isotope
exponent is very close to that for a similar bismuthate superconductor
Ba_{1-x}K_{x}BiO_{3} with T_c = 30 K. The very distinctive doping and T_c
dependencies of alpha_{O} observed in bismuthates and cuprates suggest that
bismuthates should belong to conventional phonon-mediated superconductors while
cuprates might be unconventional supercondutors.Comment: 9 pages, 5 figure
Photoemission and band-calculation studies of the charge-density wave in CuV2S4
We have studied the electronic structure and its changes across the charge-density-wave (CDW) transition in spinel-type CuV2S4 by photoemission spectroscopy and first-principles band-structure calculations. The photoemission spectra show pseudogap-like behavior and the gap size is estimated to be ~90 meV. The large energy scale of the pseudogap compared to the transition temperature and its anomalous temperature dependence implies that the involved interaction is in the strong-coupling regime. The calculated electronic susceptibility χ(q) shows a small peak at q≃11/40[110], which is consistent with the observed wave vector q≃¼[110] characterizing the CDW. This result suggests that Fermi surface nesting is at least partly responsible for the CDW formatio
The Field Perturbation Theory of the Double Correlated Phase in High Temperature Superconductors
The Double-Correlated phase in HTSC, and its treatment by field perturbation
theory, is established. In particular, we define the ground state, the
quasi-particle excitations, and construct an appropriate field. We also derive
the unperturbed Hamiltonian, and the propagators for the unperturbed state.
Then we discuss the perturbation Hamiltonian, and show that the Hartree diagram
is significant for both the pseudogap and the superconductive order parameter,
and suggest that it yields the major contribution to these parameters.Comment: 23 pages Of MSWord in PDF format, 1 figur
Weak antiferromagnetism due to Dzyaloshinskii-Moriya interaction in BaCuOCl
The antiferromagnetic insulating cuprate BaCuOCl contains
folded CuO chains with four magnetic copper ions () per unit cell.
An underlying multiorbital Hubbard model is formulated and the superexchange
theory is developed to derive an effective spin Hamiltonian for this cuprate.
The resulting spin Hamiltonian involves a Dzyaloshinskii-Moriya term and a more
weak symmetric anisotropic exchange term besides the isotropic exchange
interaction. The corresponding Dzyaloshinskii-Moriya vectors of each magnetic
Cu-Cu bond in the chain reveal a well defined spatial order. Both, the
superexchange theory and the complementary group theoretical consideration,
lead to the same conclusion on the character of this order. The analysis of the
ground-state magnetic properties of the derived model leads to the prediction
of an additional noncollinear modulation of the antiferromagnetic structure.
This weak antiferromagnetism is restricted to one of the Cu sublattices.Comment: 13 pages, 1 table, 4 figure
BCS theory for s+g-wave superconductivity borocarbides Y(Lu)NiBC
The s+g mixed gap function \Delta_k=\Delta {[(1-x)-x\sin^4\theta\cos4\phi]}
(x: weight of g-wave component) has been studied within BCS theory. By suitable
consideration of the pairing interaction, we have confirmed that the
coexistence of s- and g-wave, as well as the state with equal s and g
amplitudes (i.e., x=1/2) may be stable. This provides the semi-phenomenological
theory for the s+g-wave superconductivity with point nodes which has been
observed experimentally in borocarbides YNi_2B_2C and possibly in LuNi_2B_2C.Comment: 5 pages, 3 figure
Ab Initio Evidence for the Formation of Impurity d(3z^2-r^2) Holes in Doped La_{2-x}Sr_xCuO_4
Using the spin unrestricted Becke-3-Lee-Yang-Parr density functional, we
computed the electronic structure of explicitly doped La_{2-x}Sr_xCuO_4 (x =
0.125, 0.25, and 0.5). At each doping level, an impurity hole band is formed
within the undoped insulating gap. This band is well-localized to CuO_6
octahedra adjacent to the Sr impurities. The nature of the impurity hole is
A_{1g} in symmetry, formed primarily from the z^2 orbital on the Cu and p_z
orbitals on the apical O's. There is a strong triplet coupling of this hole
with the intrinsic B_{1g} Cu x^2-y^2/O1 p_{sigma} hole on the same site.
Optimization of the c coordinate of the apical O's in the doped CuO_6
octahedron lead to an asymmetric anti-Jahn-Teller distortion of the O2 atoms
toward the central Cu. In particular, the O2 atom between the Cu and Sr is
displaced 0.26 A while the O2 atom between the Cu and La is displaced 0.10 A.
Contrary to expectations, investigation of a 0.1 A enhanced Jahn-Teller
distortion of this octahedron does not force formation of an x^2-y^2 hole, but
instead leads to migration of the z^2 hole to the four other CuO_6 octahedra
surrounding the Sr impurity. This latter observation offers a simple
explanation for the bifurcation of the Sr-O2 distance revealed in x-ray
absorption fine structure data.Comment: Submitted to Phys. Rev. B. See http://www.firstprinciples.com for
more informatio
Superconductivity and Electronic Structure of Perovskite MgCNi3
The electronic structure, stability, electron phonon coupling and
superconductivity of the non-oxide perovskite MgCNi are studied using
density functional calculations. The band structure is dominated by a Ni
derived density of states peak just below the Fermi energy, which leads to a
moderate Stoner enhancement, placing MgCNi in the range where spin
fluctuations may noticeably affect transport, specific heat and
superconductivity, providing a mechanism for reconciling various measures of
the coupling . Strong electron phonon interactions are found for the
octahedral rotation mode and may exist for other bond angle bending modes. The
Fermi surface contains nearly cancelling hole and electron sheets that give
unusual behavior of transport quantities particularly the thermopower. The
results are discussed in relation to the superconductivity of MgCNi.Comment: 4 pages, RevTex, 5 ps figure
Non-cubic layered structure of Ba(1-x)K(x)BiO3 superconductor
Bismuthate superconductor Ba(1-x)K(x)BiO3 (x=0.27-0.49, Tc=25-32K) grown by
an electrolysis technique was studied by electron diffraction and
high-resolution electron microscopy. The crystalline structure thereof has been
found to be non-cubic, of the layered nature, and non-centrosymmetric, with the
lattice parameters a ~ ap, c ~ 2ap (ap is a simple cubic perovskite cell
parameter) containing an ordered arrangement of barium and potassium. The
evidence for the layered nature of the bismuthate superconductor removes the
principal crystallographic contradiction between bismuthate and cuprate high-Tc
superconductors.Comment: 4 pages, 3 figures, to be published in Physical Review B as a Rapid
Communicatio
Anomalous spectral weight in photoemission spectra of the hole doped Haldane chain Y2-xSrxBaNiO5
In this paper, we present photoemission experiments on the hole doped Haldane
chain compound . By using the photon energy dependence of
the photoemission cross section, we identified the symmetry of the first
ionisation states (d type). Hole doping in this system leads to a significant
increase in the spectral weight at the top of the valence band without any
change in the vicinity of the Fermi energy. This behavior, not observed in
other charge transfer oxides at low doping level, could result from the
inhomogeneous character of the doped system and from a Ni 3d-O 2p hybridization
enhancement due to the shortening of the relevant Ni-O distance in the
localized hole-doped regions.Comment: 5 pages, 4 figure
Electronic structure of NiS_{1-x}Se_x
We investigate the electronic structure of the metallic NiSSe
system using various electron spectroscopic techniques. The band structure
results do not describe the details of the spectral features in the
experimental spectrum, even for this paramagnetic metallic phase. However, a
parameterized many-body multi-band model is found to be successful in
describing the Ni~2 core level and valence band, within the same model. The
asymmetric line shape as well as the weak intensity feature in the Ni~2 core
level spectrum has been ascribed to extrinsic loss processes in the system. The
presence of satellite features in the valence band spectrum shows the existence
of the lower Hubbard band, deep inside the metallic regime, consistent
with the predictions of the dynamical mean field theory.Comment: To be published in Physical Review B, 18 pages and 5 figure
- …