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Reference values and clinical predictors of bone strength for HR-pQCT-based distal radius and tibia strength assessments in women and men.
Reference values for radius and tibia strength using multiple-stack high-resolution peripheral quantitative computed tomography (HR-pQCT) with homogenized finite element analysis are presented in order to derive critical values improving risk prediction models of osteoporosis. Gender and femoral neck areal bone mineral density (aBMD) were independent predictors of bone strength.
INTRODUCTION
The purpose was to obtain reference values for radius and tibia bone strength computed by using the homogenized finite element analysis (hFE) using multiple stacks with a HR-pQCT.
METHODS
Male and female healthy participants aged 20-39 years were recruited at the University Hospital of Bern. They underwent interview and clinical examination including hand grip, gait speed and DXA of the hip. The nondominant forearm and tibia were scanned with a double and a triple-stack protocol, respectively, using HR-pQCT (XCT II, SCANCO Medical AG). Bone strength was estimated by using the hFE analysis, and reference values were calculated using quantile regression. Multivariable analyses were performed to identify clinical predictors of bone strength.
RESULTS
Overall, 46 women and 41 men were recruited with mean ages of 25.1 (sd 5.0) and 26.2 (sd 5.2) years. Sex-specific reference values for bone strength were established. Men had significantly higher strength for radius (mean (sd) 6640 (1800) N vs. 4110 (1200) N; p < 0.001) and tibia (18,200 (4220) N vs. 11,970 (3150) N; p < 0.001) than women. In the two multivariable regression models with and without total hip aBMD, the addition of neck hip aBMD significantly improved the model (p < 0.001). No clinical predictors of bone strength other than gender and aBMD were identified.
CONCLUSION
Reference values for radius and tibia strength using multiple HR-pQCT stacks with hFE analysis are presented and provide the basis to help refining accurate risk prediction models. Femoral neck aBMD and gender were significant predictors of bone strength
How chemistry controls electron localization in 3d1 perovskites: A Wannier-function study
In the series of 3d1 t2g perovskites, SrVO3--CaVO3--LaTiO3--YTiO3 the
transition-metal d electron becomes increasingly localized and undergoes a Mott
transition between CaVO3 and LaTiO3. By defining a low-energy Hubbard
Hamiltonian in the basis of Wannier functions for the t2g LDA band and solving
it in the single-site DMFT approximation, it was recently shown[1] that
simultaneously with the Mott transition there occurs a strong suppression of
orbital fluctuations due to splitting of the t2g levels. The present paper
reviews and expands this work, in particular in the direction of exposing the
underlying chemical mechanisms by means of ab initio LDA Wannier functions
generated with the NMTO method. The Wannier functions for the t2g band exhibit
covalency between the transition-metal t2g, the large cation-d, and the
oxygen-p states; this covalency, which increases along the series, turns out to
be responsible not only for the splittings of the t2g levels, but also for
non-cubic perturbations of the hopping integrals, both of which are decisive
for the Mott transition. We find good agreement with the optical and
photoemission spectra, with the crystal-field splittings and orbital
polarizations recently measured for the titanates, and with the metallization
volume for LaTiO3. The metallization volume for YTiO3 is predicted. Using
super-exchange theory, we reproduce the observed magnetic orders in LaTiO3 and
YTiO3, but the results are sensitive to detail, in particular for YTiO3 which,
without the Jahn-Teller distortion, would be AFM C- or A-type, rather than FM.
Finally, we show that it possible to unfold the orthorhombic t2g LDA
bandstructure to a pseudocubic zone. In this zone, the lowest band is separated
from the two others by a direct gap and has a width, W_I, which is
significantly smaller than that, W, of the entire t2g band. The progressive
GdFeO3-type distortion favours electron localization by decreasing W, by
increasing the splitting of the t2g levels and by decreasing W_I. Our
conclusions concerning the roles of GdFeO3-type and JT distortions agree with
those of Mochizuki and Imada [2].Comment: Published version, final. For high resolution figures see
http://www.fkf.mpg.de/andersen/docs/pub/abstract2004+/pavarini_02.pd
The Photophysics of the Carrier of Extended Red Emission
Interstellar dust contains a component which reveals its presence by emitting
a broad, unstructured band of light in the 540 to 950 nm wavelength range,
referred to as Extended Red Emission (ERE). The presence of interstellar dust
and ultraviolet photons are two necessary conditions for ERE to occur. This is
the basis for suggestions which attribute ERE to an interstellar dust component
capable of photoluminescence. In this study, we have collected all published
ERE observations with absolute-calibrated spectra for interstellar
environments, where the density of ultraviolet photons can be estimated
reliably. In each case, we determined the band-integrated ERE intensity, the
wavelength of peak emission in the ERE band, and the efficiency with which
absorbed ultraviolet photons are contributing to the ERE. The data show that
radiation is not only driving the ERE, as expected for a photoluminescence
process, but is modifying the ERE carrier as manifested by a systematic
increase in the ERE band's peak wavelength and a general decrease in the photon
conversion efficiency with increasing densities of the prevailing exciting
radiation. The overall spectral characteristics of the ERE and the observed
high quantum efficiency of the ERE process are currently best matched by the
recently proposed silicon nanoparticle (SNP) model. Using the experimentally
established fact that ionization of semiconductor nanoparticles quenches their
photoluminescence, we proceeded to test the SNP model by developing a
quantitative model for the excitation and ionization equilibrium of SNPs under
interstellar conditions for a wide range of radiation field densities.Comment: 42 p., incl. 8 fig. Accepted for publication by Ap
La(, ) cross sections constrained with statistical decay properties of La nuclei
The nuclear level densities and -ray strength functions of
La were measured using the La(He, ),
La(He, He) and La(d, p) reactions. The
particle- coincidences were recorded with the silicon particle
telescope (SiRi) and NaI(Tl) (CACTUS) arrays. In the context of these
experimental results, the low-energy enhancement in the A140 region is
discussed. The La( cross sections were calculated
at - and -process temperatures using the experimentally measured nuclear
level densities and -ray strength functions. Good agreement is found
between La( calculated cross sections and previous
measurements
Seamless integration of the coastal ocean in global marine carbon cycle modeling
We present the first global ocean-biogeochemistry model that uses a telescoping high resolution for an improved representation of coastal carbon dynamics: ICON-Coast. Based on the unstructured triangular grid topology of the model, we globally apply a grid refinement in the land-ocean transition zone to better resolve the complex circulation of shallow shelves and marginal seas as well as ocean-shelf exchange. Moreover, we incorporate tidal currents including bottom drag effects, and extend the parameterizations of the model's biogeochemistry component to account explicitly for key shelf-specific carbon transformation processes. These comprise sediment resuspension, temperature-dependent remineralization in the water column and sediment, riverine matter fluxes from land including terrestrial organic carbon, and variable sinking speed of aggregated particulate matter. The combination of regional grid refinement and enhanced process representation enables for the first time a seamless incorporation of the global coastal ocean in model-based Earth system research. In particular, ICON-Coast encompasses all coastal areas around the globe within a single, consistent ocean-biogeochemistry model, thus naturally accounting for two-way coupling of ocean-shelf feedback mechanisms at the global scale. The high quality of the model results as well as the efficiency in computational cost and storage requirements proves this strategy a pioneering approach for global high-resolution modeling. We conclude that ICON-Coast represents a new tool to deepen our mechanistic understanding of the role of the land-ocean transition zone in the global carbon cycle, and to narrow related uncertainties in global future projections
Nonthermal Emission from a Supernova Remnant in a Molecular Cloud
In evolved supernova remnants (SNRs) interacting with molecular clouds, such
as IC 443, W44, and 3C391, a highly inhomogeneous structure consisting of a
forward shock of moderate Mach number, a cooling layer, a dense radiative shell
and an interior region filled with hot tenuous plasma is expected. We present a
kinetic model of nonthermal electron injection, acceleration and propagation in
that environment and find that these SNRs are efficient electron accelerators
and sources of hard X- and gamma-ray emission. The energy spectrum of the
nonthermal electrons is shaped by the joint action of first and second order
Fermi acceleration in a turbulent plasma with substantial Coulomb losses.
Bremsstrahlung, synchrotron, and inverse Compton radiation of the nonthermal
electrons produce multiwavelength photon spectra in quantitative agreement with
the radio and the hard emission observed by ASCA and EGRET from IC 443. We
distinguish interclump shock wave emission from molecular clump shock wave
emission accounting for a complex structure of molecular cloud. Spatially
resolved X- and gamma- ray spectra from the supernova remnants IC 443, W44, and
3C391 as might be observed with BeppoSAX, Chandra XRO, XMM, INTEGRAL and GLAST
would distinguish the contribution of the energetic lepton component to the
gamma-rays observed by EGRET.Comment: 14 pages, 4 figure, Astrophysical Journal, v.538, 2000 (in press
Analytical model of brittle destruction based on hypothesis of scale similarity
The size distribution of dust particles in nuclear fusion devices is close to
the power function. A function of this kind can be the result of brittle
destruction. From the similarity assumption it follows that the size
distribution obeys the power law with the exponent between -4 and -1. The model
of destruction has much in common with the fractal theory. The power exponent
can be expressed in terms of the fractal dimension. Reasonable assumptions on
the shape of fragments concretize the power exponent, and vice versa possible
destruction laws can be inferred on the basis of measured size distributions.Comment: 10 pages, 3 figure
Optical Spectroscopy of Galactic Cirrus Clouds: Extended Red Emission in the Diffuse Interstellar Medium
We present initial results from the first optical spectroscopic survey of
high latitude Galactic cirrus clouds. The observed shape of the cirrus spectrum
does not agree with that of scattered ambient Galactic starlight. This mismatch
can be explained by the presence of Extended Red Emission (ERE) in the diffuse
interstellar medium, as found in many other astronomical objects, probably
caused by photoluminescence of hydrocarbons. The integrated ERE intensity,
I_ERE \approx 1.2 x 10^{-5} erg s^{-1} cm^{-2} sr^{-1}, is roughly a third of
the scattered light intensity, consistent with recent color measurements of
diffuse Galactic light. The peak of the cirrus ERE (lambda_{0} \sim 6000 AA) is
shifted towards short (bluer) wavelengths compared to the ERE in sources
excited by intense ultraviolet radiation, such as HII regions (lambda_{0} sim
8000 AA); such a trend is seen in laboratory experiments on hydrogenated
amorphous carbon films.Comment: 7 pages, 2 figures. Accepted for publication in ApJ Letter
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