Trends and phenomenology of ozone pollution episodes in Spain

Pòster amb el resum gràfic de la tesi doctoral en curs, que forma part de l'exposició "Doctorat en Recursos Naturals i Medi Ambient de la UPC Manresa. 30 anys formant en recerca a la Catalunya Central 1992-2022".Postprint (published version

Trends and patterns of air quality in Santa Cruz de Tenerife (Canary Islands) in the period 2011–2015

Air quality trends and patterns in the coastal city of Santa Cruz de Tenerife (Canary Islands, Spain) for the period 2011–2015 were analyzed. The orographic and meteorological characteristics, the proximity to the African continent, and the influence of the Azores anticyclone in combination with the anthropogenic (oil refinery, road/maritime traffic) and natural emissions create specific dispersion conditions. SO2, NO2, PM10, PM2.5, and O3 pollutants were assessed. The refinery was the primary source of SO2; EU hourly and daily average limit values were exceeded during 2011 and alert thresholds were reached in 2011 and 2012. WHO daily mean guideline was occasionally exceeded. Annual averages in the three stations that registered the highest concentrations in 2011 and 2012 were between 9.3 and 20.4 µg/m3. The spatial analysis of SO2 concentrations with respect to prevailing winds corroborates a clear influence of the refinery to the SO2 levels. In 2014 and 2015, the refinery did not operate and the concentrations fell abruptly to background levels of 2.5–7.1 µg/m3 far below from WHO AQG. NO2 EU limit values, as well as WHO AQG for the period 2011–2015, were not exceeded. The progressive dieselization of the vehicle fleet caused an increment on NO2 annual mean concentrations (from 2011 to 2015) measured at two stations close to busy roads 25 to 31 µg/m3 (+21%) and 27 to 35 µg/m3 (+29%). NOx daily and weekly cycles (working days and weekends) were characterized. An anti-correlation was found between NOx and O3, showing that O3 is titrated by locally emitted NO. Higher O3 concentrations were reported because less NOx emitted during the weekends showing a clear weekend effect. Saharan dust intrusions have a significant impact on PM levels. After subtracting natural sources contribution, none of the stations reached the EU maximum 35 yearly exceedances of daily means despite seldom exceedances at some stations. None of the stations exceeded the annual mean EU limit values; however, many stations exceeded the annual mean WHO AQG. Observed PM10 annual average concentrations in all the stations fluctuated between 10.1 and 35.3 µg/m3, where background concentrations were 6.5–24.4 µg/m3 and natural contributions: 4.2–9.1 µg/m3. No PM10 temporal trends were identified during the period except for an effect of washout due to the rain: concentrations were lower in 2013 and 2014 (the most rainy years of the period). None of the stations reached the PM2.5 annual mean EU 2015 limit value. However, almost all the stations registered daily mean WHO AQG exceedances. During 2015, PM2.5 concentrations were higher than the previous years (2015, 8.8–12.3 µg/m3; 2011–2014, 3.7–9.6 µg/m3). O3 complied with EU target values; stricter WHO AQG were sometimes exceeded in all the stations for the whole time periodPeer ReviewedPostprint (published version

2005-2017 Ozone trends and potential benefits of local measures as deduced from air quality measurements in the north of the Barcelona metropolitan area

We analyzed 2005–2017 data sets on ozone (O3) concentrations in an area (the Vic Plain) frequently affected by the atmospheric plume northward transport of the Barcelona metropolitan area (BMA), the atmospheric basin of Spain recording the highest number of exceedances of the hourly O3 information threshold (180¿µg¿m-3). We aimed at evaluating the potential benefits of implementing local-BMA short-term measures to abate emissions of precursors. To this end, we analyzed in detail spatial and time variations of concentration of O3 and nitrogen oxides (NO and NO2, including OMI remote sensing data for the latter). Subsequently, a sensitivity analysis is done with the air quality (AQ) data to evaluate potential O3 reductions in the north of the BMA on Sundays compared with weekdays as a consequence of the reduction in regional emissions of precursors. The results showed a generalized decreasing trend for regional background O3 as well as the well-known increase in urban O3 and higher urban NO decreasing slopes compared with those of NO2. The most intensive O3 episodes in the Vic Plain are caused by (i) a relatively high regional background O3 (due to a mix of continental, hemispheric–tropospheric and stratospheric contributions); by (ii) intensive surface fumigation from mid-troposphere high O3 upper layers arising from the concatenation of the vertical recirculation of air masses; but also by (iii) an important O3 contribution from the northward transport/channeling of the pollution plume from the BMA. The high relevance of the local-daily O3 contribution during the most intense pollution episodes is clearly supported by the O3 (surface concentration) and NO2 (OMI data) data analysis. A maximum decrease potential (by applying short-term measures to abate emissions of O3 precursors) of 49¿µg¿O3¿m-3 (32¿%) of the average diurnal concentrations was determined. Structurally implemented measures, instead of episodically, could result in important additional O3 decreases because not only the local O3 coming from the BMA plume would be reduced, but also the recirculated O3 and thus the intensity of O3 fumigation in the plain. Therefore, it is highly probable that both structural and episodic measures to abate NOx and volatile organic compound (VOC) emissions in the BMA would result in evident reductions of O3 in the Vic PlainPeer ReviewedPostprint (author's final draft

Phenomenology of 2005-2017 high ozone pollution episodes over nothern Barcelona Metropolitan Area

Study of historical data series of surface air pollutants, atmospheric variables, NASA's OMI satellite records and others parameters to assess the phenomenology of high ozone pollution episodes at one of the most affected areas in Spain (Vic plain region

Phenomenology of 2005-2017 high ozone pollution episodes over nothern Barcelona Metropolitan Area

Study of historical data series of surface air pollutants, atmospheric variables, NASA's OMI satellite records and others parameters to assess the phenomenology of high ozone pollution episodes at one of the most affected areas in Spain (Vic plain region

Trends and patterns of air quality in Santa Cruz de Tenerife (Canary Islands) in the period 2011–2015

Air quality trends and patterns in the coastal city of Santa Cruz de Tenerife (Canary Islands, Spain) for the period 2011–2015 were analyzed. The orographic and meteorological characteristics, the proximity to the African continent, and the influence of the Azores anticyclone in combination with the anthropogenic (oil refinery, road/maritime traffic) and natural emissions create specific dispersion conditions. SO2, NO2, PM10, PM2.5, and O3 pollutants were assessed. The refinery was the primary source of SO2; EU hourly and daily average limit values were exceeded during 2011 and alert thresholds were reached in 2011 and 2012. WHO daily mean guideline was occasionally exceeded. Annual averages in the three stations that registered the highest concentrations in 2011 and 2012 were between 9.3 and 20.4 µg/m3. The spatial analysis of SO2 concentrations with respect to prevailing winds corroborates a clear influence of the refinery to the SO2 levels. In 2014 and 2015, the refinery did not operate and the concentrations fell abruptly to background levels of 2.5–7.1 µg/m3 far below from WHO AQG. NO2 EU limit values, as well as WHO AQG for the period 2011–2015, were not exceeded. The progressive dieselization of the vehicle fleet caused an increment on NO2 annual mean concentrations (from 2011 to 2015) measured at two stations close to busy roads 25 to 31 µg/m3 (+21%) and 27 to 35 µg/m3 (+29%). NOx daily and weekly cycles (working days and weekends) were characterized. An anti-correlation was found between NOx and O3, showing that O3 is titrated by locally emitted NO. Higher O3 concentrations were reported because less NOx emitted during the weekends showing a clear weekend effect. Saharan dust intrusions have a significant impact on PM levels. After subtracting natural sources contribution, none of the stations reached the EU maximum 35 yearly exceedances of daily means despite seldom exceedances at some stations. None of the stations exceeded the annual mean EU limit values; however, many stations exceeded the annual mean WHO AQG. Observed PM10 annual average concentrations in all the stations fluctuated between 10.1 and 35.3 µg/m3, where background concentrations were 6.5–24.4 µg/m3 and natural contributions: 4.2–9.1 µg/m3. No PM10 temporal trends were identified during the period except for an effect of washout due to the rain: concentrations were lower in 2013 and 2014 (the most rainy years of the period). None of the stations reached the PM2.5 annual mean EU 2015 limit value. However, almost all the stations registered daily mean WHO AQG exceedances. During 2015, PM2.5 concentrations were higher than the previous years (2015, 8.8–12.3 µg/m3; 2011–2014, 3.7–9.6 µg/m3). O3 complied with EU target values; stricter WHO AQG were sometimes exceeded in all the stations for the whole time periodPeer Reviewe

2005-2017 Ozone trends and potential benefits of local measures as deduced from air quality measurements in the north of the Barcelona metropolitan area

We analyzed 2005–2017 data sets on ozone (O3) concentrations in an area (the Vic Plain) frequently affected by the atmospheric plume northward transport of the Barcelona metropolitan area (BMA), the atmospheric basin of Spain recording the highest number of exceedances of the hourly O3 information threshold (180¿µg¿m-3). We aimed at evaluating the potential benefits of implementing local-BMA short-term measures to abate emissions of precursors. To this end, we analyzed in detail spatial and time variations of concentration of O3 and nitrogen oxides (NO and NO2, including OMI remote sensing data for the latter). Subsequently, a sensitivity analysis is done with the air quality (AQ) data to evaluate potential O3 reductions in the north of the BMA on Sundays compared with weekdays as a consequence of the reduction in regional emissions of precursors. The results showed a generalized decreasing trend for regional background O3 as well as the well-known increase in urban O3 and higher urban NO decreasing slopes compared with those of NO2. The most intensive O3 episodes in the Vic Plain are caused by (i) a relatively high regional background O3 (due to a mix of continental, hemispheric–tropospheric and stratospheric contributions); by (ii) intensive surface fumigation from mid-troposphere high O3 upper layers arising from the concatenation of the vertical recirculation of air masses; but also by (iii) an important O3 contribution from the northward transport/channeling of the pollution plume from the BMA. The high relevance of the local-daily O3 contribution during the most intense pollution episodes is clearly supported by the O3 (surface concentration) and NO2 (OMI data) data analysis. A maximum decrease potential (by applying short-term measures to abate emissions of O3 precursors) of 49¿µg¿O3¿m-3 (32¿%) of the average diurnal concentrations was determined. Structurally implemented measures, instead of episodically, could result in important additional O3 decreases because not only the local O3 coming from the BMA plume would be reduced, but also the recirculated O3 and thus the intensity of O3 fumigation in the plain. Therefore, it is highly probable that both structural and episodic measures to abate NOx and volatile organic compound (VOC) emissions in the BMA would result in evident reductions of O3 in the Vic PlainPeer Reviewe

Lessons from the COVID-19 air pollution decrease in Spain: Now what?

We offer an overview of the COVID-19 -driven air quality changes across 11 metropolises in Spain with the focus on lessons learned on how continuing abating pollution. Traffic flow decreased by up to 80% during the lockdown and remained relatively low during the full relaxation (June and July). After the lockdown a significant shift from public transport to private vehicles (+21% in Barcelona) persisted due to the pervasive fear that using public transport might increase the risk of SARS-CoV-2 infection, which need to be reverted as soon as possible. NO2 levels fell below 50% of the WHO annual air quality guidelines (WHOAQGs), but those of PM2.5 were reduced less than expected due to the lower contributions from traffic, increased contributions from agricultural and domestic biomass burning, or meteorological conditions favoring high secondary aerosol formation yields. Even during the lockdown, the annual PM2.5 WHOAQG was exceeded in cities within the NE and E regions with high NH3 emissions from farming and agriculture. Decreases in PM10 levels were greater than in PM2.5 due to reduced emissions from road dust, vehicle wear, and construction/demolition. Averaged O3 daily maximum 8-h (8hDM) experienced a generalized decrease in the rural receptor sites in the relaxation (June–July) with -20% reduced mobility. For urban areas O3 8hDM responses were heterogeneous, with increases or decreases depending on the period and location. Thus, after canceling out the effect of meteorology, 5 out of 11 cities experienced O3 decreases during the lockdown, while the remaining 6 either did not experience relevant reductions or increased. During the relaxation period and coinciding with the growing O3 season (June–July), most cities experienced decreases. However, the O3 WHOAQG was still exceeded during the lockdown and full relaxation periods in several cities. For secondary pollutants, such as O3 and PM2.5, further chemical and dispersion modeling along with source apportionment techniques to identify major precursor reduction targets are required to evaluate their abatement potential.The present work was supported by the Spanish Ministerio para la Transición Ecológica y Reto Demográfico (17CAES010), the “Agencia Estatal de Investigación” from the Spanish Ministry of Science and Innovation (IDAEA-CSIC is a Centre of Excellence Severo Ochoa CEX2018-000794-S), FEDER funds under the project CAIAC (PID2019- 108990RB-I00), and by the Generalitat de Catalunya (AGAUR 2017 SGR41). We would like to thank the Spanish Meteorological Office (AEMET) for providing meteorological data as well as NASA for providing OMI-NO2 data. BSC co-authors acknowledge the support of the Copernicus Atmosphere Monitoring Service (CAMS), which is implemented by the European Centre for Medium-Range Weather Forecasts (ECMWF) on behalf of the European Commission, the Ministerio de Ciencia, Innovación y Universidades (MICINN) (RTI2018-099894-BI00, CGL2017-88911-R), the Agencia Estatal de Investigación (PID2019-108086RA-I00/AEI/0.13039/501100011033), the AXA Research Fund, and PRACE and RES for awarding access to Marenostrum4 based in Spain at the Barcelona Supercomputing Center. H. Petetin also acknowledges the European Union's Horizon 2020 - Research and Innovation Framework Programme under the H2020 Marie Skłodowska-Curie Actions grant agreement H2020-MSCACOFUND-2016-754433.Peer ReviewedArticle signat per 20 autors/es: Xavier Querol (a), Jordi Massagué (a, b), Andrés Alastuey (a), Teresa Moreno (a), Gotzon Gangoiti (c), Enrique Mantilla (d), José Jaime Duéguez (d), Miguel Escudero (e), Eliseo Monfort (f), Carlos Pérez García-Pandog (h), Hervé Petetin (g), Oriol Jorba (g), Víctor Vázquez (i, j), Jesús de la Rosa (k), Alberto Campos (l), Marta Muñóz (l), Silvia Monge (l), María Hervás (l), Rebeca Javato (l), María J. Cornide (l) a- Institute of Environmental Assessment and Water Research, IDAEA-CSIC, Barcelona 08034, Spain b- Department of Mining, Industrial and ICT Engineering, Universitat Politècnica de Catalunya - BarcelonaTech (UPC), Manresa 08242, Spain c- Department of Chemical and Environmental Engineering, University of Basque Country, Leioa 48940, Spain d- Centro de Estudios Ambientales del Mediterráneo, CEAM, València 46980, Spain e- Centro Universitario de la Defensa, Academia General Militar, Zaragoza 50090, Spain f- Instituto de Tecnología Cerámica ITC-UJI, Castelló 12006, Spain g- Barcelona Supercomputing Center, BSC-CNS, Barcelona 08034, Spain h- ICREA, Catalan Institution for Research and Advanced Studies, Barcelona 08010, Spain i- Department of Ecology, Faculty of Sciences, University of Málaga, 29071 Málaga, Spain j- Department of Research and Development, Coccosphere Environmental Analysis, 29120 Málaga, Spain k- Department of Geology, University of Huelva, Unidad de Investigación Associada a IDAEA-CSIC, Huelva 21819, Spain l- D.G. Calidad y Evaluación Ambiental del Ministerio de Transición Ecológica y Reto Demográfico, Madrid 28071, SpainPostprint (published version