11 research outputs found
Host (dealuminated Y zeolite)–guest (zirconium tetraphenylporphyrin) nanocomposite materials. An efficient catalyst in the oximation of aldehydes
Improvement in nanocomposite host (nanocavity of dealuminated zeolite Y)-guest (12-molybdophosphoric acid) catalytic activity and its application to the one-pot three-component synthesis of tetrahydrobenzo[<i>b</i>]pyrans
An appropriate one-pot synthesis of dihydropyrimidinones catalyzed by heteropoly acid supported on zeolite: An efficient and reusable catalyst for the Biginelli reaction
Design of OH-Substituted CeTPP-TiO2/NaY Nanocomposite and Investigation of Synergistic Enhanced Photocatalytic Activity for Degradation of 4-NP
Host (nanocavity of zeolite-Y)–guest (molybdophosphoric acid) nanocomposite materials: An efficient catalyst for solvent-free synthesis and deprotection of 1,l-diacetates
Host (nanocavity of dealuminated zeolite-Y)-guest (12-molybdophosphoric acid) nanocomposite material: An efficient and reusable catalyst for synthesis of 14-substituted-14-H-dibenzo[<i>a</i>,<i>j</i>] xanthenes under thermal and microwave irradiation conditions
Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene
Extended lead(II) architectures engineered: Via tetrel bonding interactions
The evaluation of N0-(pyridin-2-ylmethylene)nicotinohydrazide (HLI) and N,N0 0 0-bis(1-(pyridin-2-yl)-
ethylidene)carbazide (H2LII) as linker precursors in the synthesis of novel PbII extended structures is described.
An equimolar one-pot reaction of PbX2 (X = NO3
, CH3COO) salts with HLI and H2LII in MeOH at 60 1C in
a branched tube apparatus leads to heteroleptic complexes [Pb(HLI)(NO3)2]n (1), [Pb(LI)(CH3O)]n (2),
[Pb2(H2LII)(NO3)4] (3) and [Pb2(HLII)(CH3COO)3]n (4), respectively. The nature of the anion in the parent PbII
salt also influences the final structure. In all complexes, the PbII center exhibits a hemidirected coordination
geometry with all the covalent bonds being concentrated on one hemisphere of the coordination sphere.
The sterically available PbII ion participates in Pb O/N tetrel bonding or Pb Cg interaction as evidenced
from the detailed structural and topological analysis of the described complexes. As a result of these
interactions, the structures of all four compounds can be extended to a higher dimensional framework,
which is further stabilized by hydrogen N\u2013H O/C\u2013H O and dihydrogen C\u2013H H\u2013C bonds and/or p p
stacking interactions. The complementary Hirshfeld surface analysis of the discrete complex 3, considering
covalent bonds, showed that the structure is highly dominated by H X (X = O, H and C) and O Y (Y = O,
Pb, C and N) contacts, of which the O Pb/H/N/C contacts are highly favoured. DFT based charge and
energy decomposition (ETS-NOCV) calculations are performed in order to shed light on the nature of the
non-covalent interactions that determine the stability of the obtained structures