81 research outputs found
Magnetic properties of a new cobalt hydrogen vanadate with a dumortierite-like structure: Co13.5(OH)6(H0.5VO3.5)2(VO4)6
The magnetic properties of a novel cobalt-based hydrogen vanadate,
Co13.5(OH)6(H0.5VO3.5)2(VO4)6, are reported. This new magnetic material was
synthesized in single-crystal form using a conventional hydrothermal method.
Its crystal structure was determined from single-crystal X-ray diffraction data
and was also characterized by scanning electron microscopy. Its crystal
framework has a dumortierite-like structure consisting of large hexagonal and
trigonal channels; the large hexagonal channels contain one-dimensional chains
of face-sharing CoO6 octahedra linked to the framework by rings of VO4
tetrahedra, while the trigonal channels are occupied by chains of disordered
V2O4 pyramidal groups. The magnetic properties of this material were
investigated by DC magnetic measurements, which indicate the occurrence of
antiferromagnetic interactions
MECHANISM OF THE PHASE CHANGE IN PbK2LiNb5O15: Dielectric, structural, and Raman scattering studies
Experiments reveal that PbK2LiNb5O15 which belongs to the tetragonal tungsten bronze family presents paraelectric and ferroelectric phases and a complex structural change between them. High and low temperature phases are of symmetry P4/mbm and Pba2 respectively, so that this change is also of ferroelastic type. As presented here, crystallographic results hint at a displacive character of the ferroelectric ordering but show a more complex behaviour, with a clear order-disorder mechanism which accompanies the appearance of ferroelasticity. To complete our knowledge of this material, we have performed Raman experiments which exhibit a low frequency mode, but no clear soft mode is observed
Tailoring the photovoltaic effect in (111) oriented BiFeO/LaFeO superlattices
Ferroelectric and photovoltaic properties of (BiFeO)/(LaFeO) superlattices grown by pulsed laser deposition have been investigated (Λ being the bilayer thickness). For a high concentration of BiFeO a ferroelectric state is observed simultaneously with a switchable photovoltaic response. In contrast for certain concentration of LaFeO a non-switchable photovoltaic effect is evidenced. Such modulation of the PV response in the superlattices is attributed to the ferroelectric to paraelectric phase transition which is controlled with the increase of x. Remarkably, concomitant to this change of PV mechanism, a change of the conduction mechanism also seems to take place from a bulk-limited to an interface-limited
transport as x increases
Enhanced RCP and large inverse magnetocaloric effect of CoFeO nanoparticles synthesized by auto-combustion method
This work focuses on the microstructure, magnetic properties and
magnetocaloric effect of CoFeO (CFO) nanoparticles elaborated by
sol-gel auto combustion method. The XRD investigation indicates that CFO is
crystallized in a cubic spinel structure and the SEM micrograph shows a fine
quasi-spherical with an average grain sizes of 160 nm. The temperature
dependence of the Raman spectra reveals the ferromagnetic to paramagnetic
(FM-PM) transition started from 723 K and the magnetization versus temperature
measurements shows the Curie temperature located at T = 785 K. Large
value of magnetocaloric temperature change of T =11.2 K with a high RCP
of 687.56 J Kg are achieved indirectly via the Maxwell approach making
our CFO nanopowder suitable candidate for both environmentally friendly
magnetic refrigeration and medical applications at ambient temperature
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