67 research outputs found
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Melt segregation from silicic crystal mushes: a critical appraisal of possible mechanisms and their microstructural record.
One of the outstanding problems in understanding the behavior of intermediate-to-silicic magmatic systems is the mechanism(s) by which large volumes of crystal-poor rhyolite can be extracted from crystal-rich mushy storage zones in the mid-deep crust. The mechanisms commonly invoked are hindered settling, micro-settling, and compaction. The concept of micro-settling involves extraction of grains from a crystal framework during Ostwald ripening and has been shown to be non-viable in the metallic systems for which it was originally proposed. Micro-settling is also likely to be insignificant in silicic mushes, because ripening rates are slow for quartz and plagioclase, contact areas between grains in a crystal mush are likely to be large, and abundant low-angle grain boundaries promote grain coalescence rather than ripening. Published calculations of melt segregation rates by hindered settling (Stokes settling in a crystal-rich system) neglect all but fluid dynamical interactions between particles. Because tabular silicate minerals are likely to form open, mechanically coherent, frameworks at porosities as high as ~ 75%, settling of single crystals is only likely in very melt-rich systems. Gravitationally-driven viscous compaction requires deformation of crystals by either dissolution-reprecipitation or dislocation creep. There is, as yet, no reported microstructural evidence of extensive, syn-magmatic, internally-generated, viscous deformation in fully solidified silicic plutonic rocks. If subsequent directed searches do not reveal clear evidence for internally-generated buoyancy-driven melt segregation processes, it is likely that other factors, such as rejuvenation by magma replenishment, gas filter-pressing, or externally-imposed stress during regional deformation, are required to segregate large volumes of crystal-poor rhyolitic liquids from crustal mushy zones
Plagioclase Growth Rates Control Three-grain Junction Geometry in Dolerites and Gabbros
Measurements of dihedral angles at three-grain junctions in gabbros, involving two grains of plagioclase and one grain of another mineral, demonstrate that the median dihedral angle is generally the same for all minerals in any sample. The few exceptions to this can be attributed to reaction or to the cessation of growth of plagioclase during the last stages of solidification of highly evolved liquids that do not crystallize volumetrically important amounts of plagioclase. The dihedral angle is therefore primarily controlled by the growth behavior of plagioclase in the last remaining liquid. The final value of the dihedral angle is controlled by the extent to which plagioclase growth is accommodated on the (010) faces: low angles form when growth on the (010) faces is minor compared with that on the other growth faces, and high angles form when the (010) faces accommodate significant growth. The response of dihedral angles to changes in crystallization time is therefore explained by the changing response of plagioclase growth to cooling rate, with limited growth on (010) faces during rapid cooling (leading to a low dihedral angle) and more significant growth at slow cooling (leading to high dihedral angle). The correspondence between dihedral angle and plagioclase grain shape (as quantified by the average apparent aspect ratio observed in thin section) is clearly evident for non-fractionated bodies such as dolerite sills. Although the stratigraphic variation of the overall plagioclase grain shape in the floor cumulates of the Skaergaard Intrusion is broadly similar to that observed in sills, there is no correspondence to observed augite�plagioclase�plagioclase dihedral angles, which show a step-wise stratigraphic variation, corresponding to changes in the liquidus assemblage. This decoupling occurs because plagioclase growth in layered intrusions occurs in two stages, the first at, or close to, the magma�mush interface and the second within the mush. Chemical maps of samples on either side of the augite-in dihedral angle step demonstrate a step-wise change in the aspect ratio of the plagioclase grown during the second stage, with the aspect ratio of this stage corresponding to that predicted from the dihedral angles. Plagioclase shape in layered intrusions thus records two separate thermal regimes, with the overall shape controlled by the global cooling rate of the intrusion, and the second (minor) stage within the mushy layer reflecting local thermal buffering controlled by the liquidus assemblage of the bulk magma. Dihedral angles in layered intrusions record the second thermal regime
The thickness of the crystal mush on the floor of the Bushveld magma chamber.
The thickness of the crystal mush on magma chamber floors can be constrained using the offset between the step-change in the median value of dihedral angles formed at the junctions between two grains of plagioclase and a grain of another phase (typically clinopyroxene, but also orthopyroxene and olivine) and the first appearance or disappearance of the liquidus phase associated with the step-change in median dihedral angle. We determined the mush thickness in the Rustenburg Layered Suite of the Bushveld Complex at clinopyroxene-in (in Lower Main Zone) and magnetite-in (in Upper Zone). We also examined an intermittent appearance of cumulus apatite in Upper Zone, using both the appearance and disappearance of cumulus apatite. In all cases, the mush thickness does not exceed 4Â m. These values are consistent with field observations of a mechanically rigid mush at the bases of both magnetitite and chromitite layers overlying anorthosite. Mush thickness of the order of a few metres suggests that neither gravitationally-driven compaction nor compositional convection within the mush layer is likely to have been important processes during solidification: adcumulates in the Bushveld are most likely to have formed at the top of the mush during primary crystallisation. Similarly, it is unlikely either that migration of reactive liquids occurs through large stretches of stratigraphy, or that layering is formed by mechanisms other than primary accumulation
Crystal settling and convection in the Shiant Isles Main Sill
The 168 m-thick Shiant Isles Main Sill is a composite body, dominated by an early, 24 m-thick, picrite sill formed by the intrusion of a highly olivine-phyric magma, and a later 135 m-thick intrusion of olivine-phyric magma that split the earlier picrite into a 22 m-thick lower part and a 2 m-thick upper part, forming the picrodolerite/crinanite unit (PCU). The high crystal load in the early picrite prevented effective settling of the olivine crystals, which retain their initial stratigraphic distribution. In contrast, the position of the most evolved rocks of the PCU at a level ~80% of its total height point to significant accumulation of crystals on the floor, as evident by the high olivine mode at the base of the PCU. Crystal accumulation on the PCU floor occurred in two stages. During the first, most of the crystal load settled to the floor to form a modally and size-sorted accumulation dominated by olivine, leaving only the very smallest olivine grains still in suspension. The second stage is recorded by the coarsening-upwards of individual olivine grains in the picrodolerite, and their amalgamation into clusters which become both larger and better sintered with increasing stratigraphic height. Large clusters of olivine are present at the roof, forming a foreshortened mirror image of the coarsening-upwards component of the floor accumulation. The coarsening-upwards sequence records the growth of olivine crystals while in suspension in a convecting magma, and their aggregation into clusters, followed by settling over a prolonged period (with limited trapping at the roof). As olivine was progressively lost from the convecting magma, crystal accumulation on the (contemporaneous) floor of the PCU was increasingly dominated by plagioclase, most likely forming clusters and aggregates with augite and olivine, both of which form large poikilitic grains in the crinanite. While the PCU is unusual in being underlain by an earlier, still hot, intrusion that would have enhanced any driving force for convection, we conclude from comparison with microstructures in other sills that convection is likely in tabular bodies >100 m thickness
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Insights Into Magma Chamber Processes From the Relationship Between Fabric and Grain Shape in Troctolitic Cumulates
The strength of foliations defined by shape preferred orientation of plagioclase in troctolitic cumulates from the Layered Series of the Skaergaard intrusion, and the Rum Eastern Layered Intrusion, increases as the grains become more tabular, due either to the greater propensity of highly non-equant grains to be re-arranged by magmatic currents or tectonic disruption of poorly consolidated mush, or by the effects of a pre-existing shape preferred orientation on final grain shape in fully solidified rocks. The stratigraphic evolution of grain shape, microstructures and fabrics in the lowest 320 m of the Skaergaard Layered Series records the progressive inflation of the chamber to its final size. During the earliest stages of solidification, the extent of in situ nucleation and growth on the chamber floor decreased upward through the stratigraphy, due to the development of a thermally insulating blanket of mush on the floor. An upward increase in foliation strength as the chamber inflated to its final size was a result of the increasing strength of convection of the bulk magma and an increasing contribution to the floor mush of crystals derived from the walls of the enlarging magma chamber. Plagioclase in the troctolites in the open-system magma chamber of the Rum Eastern Layered Intrusion is generally more equant than that in the Skaergaard intrusion, perhaps related to the slower crystal growth on the margins of the continuously replenished Rum chamber. Significant sub-solidus modification of original igneous microstructures is observed in Rum troctolites from parts of the stratigraphy recording frequent replenishment events
Microstructural evolution of silicate immiscible liquids in ferrobasalts
Abstract: An experimental study of the microstructural evolution of an immiscible basaltic emulsion shows that the Fe-rich liquid forms homogeneously nucleated droplets dispersed in a continuous Si-rich liquid, together with droplets heterogeneously nucleated on plagioclase, magnetite, and pyroxene. Heterogeneous nucleation is likely promoted by localised compositional heterogeneities around growing crystals. The wetting angle of Fe-rich droplets on both plagioclase and magnetite increases with decreasing temperature. Droplet coarsening occurs by a combination of diffusion-controlled growth and Ostwald ripening, with an insignificant contribution from coalescence. Characteristic microstructures resulting from the interaction of immiscible Fe-rich liquid with crystal grains during crystal growth can potentially be used as an indicator of liquid unmixing in fully crystallised natural samples. In magma bodies < ~ 10 m in size, gravitationally driven segregation of immiscible Fe-rich droplets is unlikely to be significant
Microstructural evidence for crystallization regimes in mafic intrusions: a case study from the Little Minch Sill Complex, Scotland
The magma forming the 20 m thick crinanitic/picrodoleritic Dun Raisburgh sill, part of the Little Minch Sill Complex of NW Scotland, comprised a mafic carrier liquid with a crystal cargo of plagioclase and olivine (1 vol%). The olivine component of the cargo settled on the floor of the intrusion while the more buoyant plagioclase component remained suspended during solidification, resulting in a relatively high plagioclase content in the centre of the sill. The settled olivine grains form a lower fining-upwards sequence overlain by a poorly sorted accumulation formed of grains that grew within the convecting magma. The accumulation of olivine on the sill floor occurred over 5–10 weeks, synchronous with the upwards-propagation of a solidification front comprising a porous (~ 70 vol% interstitial liquid) plagioclase-rich crystal mush
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Magma chambers versus mush zones: constraining the architecture of sub-volcanic plumbing systems from microstructural analysis of crystalline enclaves.
There are clear microstructural differences between mafic plutonic rocks that formed in a dynamic liquid-rich environment, in which crystals can be moved and re-arranged by magmatic currents, and those in which crystal nucleation and growth are essentially in situ and static. Crystalline enclaves, derived from deep crustal mushy zones and erupted in many volcanic settings, afford a unique opportunity to use the understanding of microstructural development, established from the study of intrusive plutons, to place constraints on the architecture of sub-volcanic systems. Here, we review the relevant microstructural literature, before applying these techniques to interrogate the crystallization environments of enclaves from the Kameni Islands of Santorini and Rábida Volcano in the Galápagos. Crystals in samples of deep-sourced material from both case studies preserve evidence of at least some time spent in a liquid-rich environment. The Kameni enclaves appear to record an early stage of crystallization during which crystals were free to move, with the bulk of crystallization occurring in a static, mushy environment. By contrast, the Rábida enclaves were sourced from an environment in which hydrodynamic sorting and re-arrangement by magmatic currents were common, consistent with a liquid-rich magma chamber. While presently active volcanoes are thought to be underlain by extensive regions rich in crystal mush, these examples preserve robust evidence for the presence of liquid-rich magma chambers in the geological record. This article is part of the Theo Murphy meeting issue 'Magma reservoir architecture and dynamics'
Mean grain diameters from thin sections: matching the average to the problem
It is common practice to estimate a mean diameter for spherical or sub-spherical particles or vesicles in a rock by multiplying the average diameter of the approximately circular cross-sections visible in thin-section by a factor of 1.273. This number-weighted average may be dominated by the hard-to-measure fine tail of the size distribution, and is unlikely to be representative of the average particle diameter of greatest interest for a wide range of geological problems or processes. Average particle size can be quantified in a variety of ways, based on the mass or surface area of the particles, and here we provide exact relations of these different average measures to straightforward measurements possible in thin-section, including an analysis of how many particles to measure to achieve a desired level of uncertainty. The use of average particle diameter is illustrated firstly with a consideration of the accumulation of olivine phenocrysts on the floor of the 135m thick picrodolerite/crinanite unit of the Shiant Isles Main Sill. We show that the 45m thick crystal pile on the sill floor could have formed by crystal settling within a few months. The second geological example is provided by an analysis of the sizes of exsolved Fe-rich droplets during unmixing of a basaltic melt in a suite of experimental charges. We show that the size distribution cannot be explained by sudden nucleation, followed by either Ostwald ripening or Brownian coalescence. We deduce that a continuous process of droplet nucleation during cooling is likely to have occurred
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