1,719 research outputs found
Discovery of interstellar isocyanogen (CNCN): further evidence that dicyanopolyynes are abundant in space
It is thought that dicyanopolyynes could be potentially abundant interstellar
molecules, although their lack of dipole moment makes it impossible to detect
them through radioastronomical techniques. Recently, the simplest member of
this chemical family, cyanogen (NCCN), was indirectly probed for the first time
in interstellar space through the detection of its protonated form toward the
dense clouds L483 and TMC-1. Here we present a second firm evidence of the
presence of NCCN in interstellar space, namely the detection of the metastable
and polar isomer isocyanogen (CNCN). This species has been identified in L483
and tentatively in TMC-1 by observing various rotational transitions in the 3
mm band with the IRAM 30m telescope. We derive beam-averaged column densities
for CNCN of 1.6e12 cm-2 in L483 and 9e11 cm-2 in TMC-1, which imply fractional
abundances relative to H2 in the range (5-9)e-11. While the presence of NCCN in
interstellar clouds seems out of doubt owing to the detection of NCCNH+ and
CNCN, putting tight constraints on its abundance is still hampered by the poor
knowledge of the chemistry that links NCCN with NCCNH+ and especially with
CNCN. We estimate that NCCN could be fairly abundant, in the range 1e-9 - 1e-7
relative to H2, as other abundant nitriles like HCN and HC3N.Comment: Accepted for publication in ApJ Letter
Detection of interstellar HCS and its metastable isomer HSC: new pieces in the puzzle of sulfur chemistry
We present the first identification in interstellar space of the thioformyl
radical (HCS) and its metastable isomer HSC. These species were detected toward
the molecular cloud L483 thanks to observations carried out with the IRAM 30m
telescope in the 3 mm band. We derive beam-averaged column densities of 7e12
cm-2 for HCS and 1.8e11 cm-2 for HSC, which translate to fractional abundances
relative to H2 of 2e-10 and 6e-12, respectively. Although the amount of sulfur
locked by these radicals is low, their detection allows to put interesting
constraints on the chemistry of sulfur in dark clouds. Interestingly, the
H2CS/HCS abundance ratio is found to be quite low, around 1, in contrast with
the oxygen analogue case, in which the H2CO/HCO abundance ratio is around 10 in
dark clouds. Moreover, the radical HCS is found to be more abundant than its
oxygen analogue, HCO. The metastable species HOC, the oxygen analogue of HSC,
has not been yet observed in space. These observational constraints are
confronted with the outcome of a recent model of the chemistry of sulfur in
dark clouds. The model underestimates the fractional abundance of HCS by at
least one order of magnitude, overestimates the H2CS/HCS abundance ratio, and
does not provide an abundance prediction for the metastable isomer HSC. These
observations should prompt a revision of the chemistry of sulfur in
interstellar clouds.Comment: Accepted for publication in A&A Letter
A phytosociological survey of the boreal forest (Vaccinio-Piceetea) in North America
A survey of syntaxa of vegetation of North American boreal forests (class Vaccinio-Piceetea) is presented. This
phytosociological survey, carried out combining the Braun-Blanquet method with numerical syntaxonomical analyses
(cluster and correspondence analysis), describes the associations of the North American boreal forests, which
have several species, varieties or vicariant species in common with their Eurasian counterparts, and can be placed
in the class Vaccinio-Piceetea. By means of tabular and multivariate analyses, 2084 North American relevés were
compared with 3273 relevés from European, Japanese and Korean boreal forest, to describe and typify 4 orders, 10
alliances and 37 associations. Diagnostic tables, ordination, clustering, and climatic, edaphic and biogeographical data were used to show floristic affinities among these syntaxa and interpret their distribution areas. Syntaxa were briefly characterized by their floristic composition, physiognomy, succession, zonation, and biogeographical distribution
Investigation of HNCO isomers formation in ice mantles by UV and thermal processing: an experimental approach
Current gas phase models do not account for the abundances of HNCO isomers
detected in various environments, suggesting a formation in icy grain mantles.
We attempted to study a formation channel of HNCO and its possible isomers by
vacuum-UV photoprocessing of interstellar ice analogues containing HO,
NH, CO, HCN, CHOH, CH, and N followed by warm-up, under
astrophysically relevant conditions. Only the HO:NH:CO and HO:HCN
ice mixtures led to the production of HNCO species. The possible isomerization
of HNCO to its higher energy tautomers following irradiation or due to ice
warm-up has been scrutinized. The photochemistry and thermal chemistry of
HO:NH:CO and HO:HCN ices was simulated using the Interstellar
Astrochemistry Chamber (ISAC), a state-of-the-art ultra-high-vacuum setup. The
ice was monitored in situ by Fourier transform mid-infrared spectroscopy in
transmittance. A quadrupole mass spectrometer (QMS) detected the desorption of
the molecules in the gas phase. UV-photoprocessing of
HO:NH:CO/HO:HCN ices lead to the formation of OCN as main
product in the solid state and a minor amount of HNCO. The second isomer HOCN
has been tentatively identified. Despite its low efficiency, the formation of
HNCO and the HOCN isomers by UV-photoprocessing of realistic simulated ice
mantles, might explain the observed abundances of these species in PDRs, hot
cores, and dark clouds
Nascent bipolar outflows associated with the first hydrostatic core candidates Barnard 1b-N and 1b-S
In the theory of star formation, the first hydrostatic core (FHSC) phase is a
critical step in which a condensed object emerges from a prestellar core. This
step lasts about one thousand years, a very short time compared with the
lifetime of prestellar cores, and therefore is hard to detect unambiguously.
We present IRAM Plateau de Bure observations of the Barnard 1b dense
molecular core, combining detections of H2CO and CH3OH spectral lines and dust
continuum at 2.3" resolution (~ 500 AU). The two compact cores B1b-N and B1b-S
are detected in the dust continuum at 2mm, with fluxes that agree with their
spectral energy distribution. Molecular outflows associated with both cores are
detected. They are inclined relative to the direction of the magnetic field, in
agreement with predictions of collapse in turbulent and magnetized gas with a
ratio of mass to magnetic flux somewhat higher than the critical value, \mu ~ 2
- 7. The outflow associated with B1b-S presents sharp spatial structures, with
ejection velocities of up to ~ 7 kms from the mean velocity. Its dynamical age
is estimated to be ~2000 yrs. The B1b-N outflow is smaller and slower, with a
short dynamical age of ~1000 yrs. The B1b-N outflow mass, mass-loss rate, and
mechanical luminosity agree well with theoretical predictions of FHSC. These
observations confirm the early evolutionary stage of B1b-N and the slightly
more evolved stage of B1b-S.Comment: 6 pages, 3 figure
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