1,146 research outputs found
First-principles investigation of Li intercalation kinetics in phospho-olivines
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2013.Cataloged from PDF version of thesis.Includes bibliographical references (p. 141-150).This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO₄ and Li(Fe,Mn)PO₄, using first-principles calculations. Currently Li-ion battery technology is critically relied upon for the operation of electrified vehicles, but further improvements mainly in cathode performance are required to ensure widespread adoption, which in itself requires learning from existing commercial cathode chemistries. LiFePO₄ is presently used in commercial Li-ion batteries, known for its rapid charge and discharge capability but with underwhelming energy density. This motivates the three central research efforts presented herein. First, we investigate the modified phase diagram and electrochemical properties of mixed olivines, such as Li(Fe,Mn)PO₄, which offer improved theoretical energy density over LiFePO₄ (due to the higher redox voltage associated with Mn²+/Mn³+). The Lix(FelyMny)PO₄ phase diagram is constructed by Monte Carlo simulation on a cluster expansion Hamiltonian parametrized by first-principles determined energies. Deviations from the equilibrium phase behavior and voltages of pure LiFePO₄ and LiMnPO₄ are analyzed and discussed to good agreement with experimental observations. Second, we address why LiFePO₄ exhibits superior rate performance strictly when the active particle size is brought down to the nano-scale. By considering the presence of immobile point defects residing in the 1D Li diffusion path, specifically by calculating from first principles both defect formation energies and Li migration barriers in the vicinity of likely defects, the Li diffusivity is recalculated and is found to strongly vary with particle size. At small particle sizes, the contribution from defects is small, and fast 1D Li diffusion is accessible. However, at larger particle sizes (pm scale and above) the contribution from defects is much larger. Not only is Li transport impeded, but it is also less anisotropic in agreement with experiments on large LiFePO₄ single crystals. Third, we investigate why LiFePO₄ can be charged and discharged rapidly despite having to undergo a first-order phase transition. Conventional wisdom dictates that a system with strong equilibrium Li segregation behavior requires both nucleation and growth in the charge and discharge process, which should impede the overall kinetics. Rather, through first-principles calculations, we determine the minimal energy required to access a non-equilibrium transformation path entirely through the solid solution. Not only does this transformation mechanism require little driving force, but it also rationalizes how a kinetically favorable but nonequilibrium path is responsible for the extremely high rate performance associated with this material. The consequences of a rapid non-equilibrium single-particle transformation mechanism on (dis)charging a multi-particle assembly, as is the case in porous electrodes, are discussed and compared to experimental observations.by Rahul Malik.Ph.D
CRIMINAL DISPOSAL OF THE DEAD AFTER HOMICIDAL STRANGULATION: AUTOPSY DEFYING PUTREFACTION AND EVIL MOTIVES ONCE AGAIN
Homicide with concealment of the corpse is a rarely encountered phenomenon in routine forensic work. Such cases represent a challenge by the fact that the bodies or parts thereof are unknown, without any relevant history, and usually depict well-established changes of putrefaction at autopsy. However, a proper scrutiny of the circumstances along with discovery of significant injuries at autopsy may bring a breakthrough to the case. A case of putrefied and unidentified male dead body is hereby described that was killed by ligature strangulation followed by dumping into a deep water channel which was, however, preceded by tying-up of extremities with a strong metallic chain. The postmortem findings along with the ancillary investigations and case circumstances helped in concluding the cause and manner of death which was subsequently followed by the arrest of the perpetrators who submitted and explained the whole story of the crime. Various possible means of suicide, including a self-application of restraint, were excluded from the study
Understanding the Initial Stages of Reversible Mg Deposition and Stripping in Inorganic Non-Aqueous Electrolytes
Multi-valent (MV) battery architectures based on pairing a Mg metal anode
with a high-voltage ( 3 V) intercalation cathode offer a realistic design
pathway toward significantly surpassing the energy storage performance of
traditional Li-ion based batteries, but there are currently only few
electrolyte systems that support reversible Mg deposition. Using both static
first-principles calculations and molecular dynamics, we perform
a comprehensive adsorption study of several salt and solvent species at the
interface of Mg metal with an electrolyte of Mg and Cl dissolved in
liquid tetrahydrofuran (THF). Our findings not only provide a picture of the
stable species at the interface, but also explain how this system can support
reversible Mg deposition and as such we provide insights in how to design other
electrolytes for Mg plating and stripping. The active depositing species are
identified to be (MgCl) monomers coordinated by THF, which exhibit
preferential adsorption on Mg compared to possible passivating species (such as
THF solvent or neutral MgCl complexes). Upon deposition, the energy to
desolvate these adsorbed complexes and facilitate charge-transfer is shown to
be small ( 61 46.2 kJ mol to remove 3 THF from the strongest
adsorbing complex), and the stable orientations of the adsorbed but desolvated
(MgCl) complexes appear favorable for charge-transfer. Finally,
observations of Mg-Cl dissociation at the Mg surface at very low THF
coordinations (0 and 1) suggest that deleterious Cl incorporation in the anode
may occur upon plating. In the stripping process, this is beneficial by further
facilitating the Mg removal reaction
HFRAS : design of a high-density feature representation model for effective augmentation of satellite images
Efficiently extracting features from satellite images is crucial for classification and post-processing activities. Many feature representation models have been created for this purpose. However, most of them either increase computational complexity or decrease classification efficiency. The proposed model in this paper initially collects a set of available satellite images and represents them via a hybrid of long short-term memory (LSTM) and gated recurrent unit (GRU) features. These features are processed via an iterative genetic algorithm, identifying optimal augmentation methods for the extracted feature sets. To analyse the efficiency of this optimization process, we model an iterative fitness function that assists in incrementally improving the classification process. The fitness function uses an accuracy & precision-based feedback mechanism, which helps in tuning the hyperparameters of the proposed LSTM & GRU feature extraction process. The suggested model used 100 k images, 60% allocated for training and 20% each designated for validation and testing purposes. The proposed model can increase classification precision by 16.1% and accuracy by 17.1% compared to conventional augmentation strategies. The model also showcased incremental accuracy enhancements for an increasing number of training image sets.© The Author(s) 2023. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.fi=vertaisarvioitu|en=peerReviewed
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