Rough triggerfish, Canthidermis maculata from Gujarat coast

A specimen of the Rough triggerfish, Canthidermis maculata (Bloch, 1786) was landed by a multiday trawler on 25th November 2015 at Mangrol Fisheries Harbour, Gujarat. The specimen was brownish grey in colour with characteristic white spots all over the body including the head. It measured 309 mm and 256 mm in Total length and Standard length respectively with a weight of 580 g (Fig. 1). The fish is usually found in areas having sandy, muddy or rocky bottoms at a depth range of 50-100 m and is reported from the Western Indian Ocean

Dynamics of vegetative morphomatrix, productivity and economics of NA 7 aonla (Emblica officinalis) in different planting systems under rainfed conditions

A field experiment was conducted to determine the effects of different planting systems and densities on plant growth and their relation to yield and quality attributes of NA 7 aonla (Emblica officinalis Gaertn) during the years 2011-2013 under rainfed hot semi- arid ecosystem of western India. The present study contained 5 planting systems as treatments namely, square, hedgerow, double hedge row, cluster and paired system. Different planting systems significantly influenced the vegetative growth, yield and quality of fruits during both the years of experimentation. The highest plant height was noted in double hedgerow system (7.80 m) and the lowest in paired system (7.08 m). Consequently, the rootstock (59.82cm), scion girth (58.38 cm) and plant spread (6.99 cm) was measured maximum in square system of planting. However, these parameters were measured the lowest in double hedgerow followed by hedgerow and cluster planting systems. Result of study revealed that the mean yield/plant (110.24 kg) was recorded the highest in square but the yield/ha were recorded maximum in double hedgerow (225.90 q) followed by hedgerow (202.65 q) and cluster (170.37 q). During the experimentation, a considerable difference in yield over previous year was observed among the different planting systems. An increase in yield over square system by the rest of the system ranged between 83.8% - 132.39% being highest in double hedgerow and lowest in paired system, whereas per cent increase in yield in double hedgerow over other systems ranged between 26.44-132.39 being the maximum and minimum upon square and hedgerow systems of planting, respectively. There were significant differences amongst different planting system with regards to fruit physical and quality attributes. Among the different planting systems, the square system exhibited better values for physical qualities, whereas chemical attributes like TSS, total sugar, vitamin C and total phenols were observed maximum in double hedgerow planting system. The net economic return was computed with double hedgerow (₹192 270.00 and ₹ 243 035.00) followed by hedgerow (₹ 150 800.00 and ₹195 650) and it was minimum in square (₹ 83 950.00 and ₹ 107 605.00) system of planting

Measurement of (n,γ) reaction cross section of 186W-isotope at neutron energy of 20.02±0.58 MeV

The cross-section of 186W(n,γ)187W reaction has been measured at an average neutron energy of 20.02±0.58 MeV by using activation technique. The 27Al(n,α)24Na and 115In(n,n´)115mIn reactions have been used for absolute neutron flux measurement. Theoretically the reaction cross-sections have been calculated by using the TALYS-1.9 code. The results from the present work and the EXFOR based literature data have been compared with the evaluated data and calculated data from TALYS-1.9 code

Measurement of (n,γ) reaction cross section of 186W-isotope at neutron energy of 20.02±0.58 MeV

392-396The cross-section of 186W(n,γ)187W reaction has been measured at an average neutron energy of 20.02±0.58 MeV by using activation technique. The 27Al(n,α)24Na and 115In(n,n´)115mIn reactions have been used for absolute neutron flux measurement. Theoretically the reaction cross-sections have been calculated by using the TALYS-1.9 code. The results from the present work and the EXFOR based literature data have been compared with the evaluated data and calculated data from TALYS-1.9 code

Measurements of 181Ta(n,2n)180Ta reaction cross-section at the neutron energy of 14.78 MeV

The cross-section of the 181Ta(n,2n)180Ta reaction has been measured with respect to the 197Au(n,2n)196Au monitor reaction at the incident neutron energy of 14.78± 0.20 MeV, using neutron activation analysis and off-line γ-ray spectrometric technique. The present measurement has been done at the energy where discrepant measured results are available in the EXFOR data library. The result has been compared with evaluated data libraries JEFF-3.3 and ENDF/B-VII.1. The present result has also been supported by theoretical predictions of nuclear model code TALYS1.8 and TALYS-1.9. The uncertainty and the correlations among the measured cross-section has been studied using co-variance analysis

Oxy-functionalization of olefins with neat and heterogenized binuclear V(IV)O and Fe(II) complexes: effect of steric hindrance on product selectivity and output in homogeneous and heterogeneous phase

Neat {[VO(sal2bz)]2; [Fe(sal2bz)(H2O)2]2·2H2O} and zeolite-Y immobilized {[VO(sal2bz)]2-Y; [Fe(sal2bz)(H2O)2]2-Y} binuclear complexes have been prepared and characterized by spectroscopic techniques (IR, UV–vis), elemental analyses (CHN, ICP-OES), thermal study (TGA), scanning electron micrograph (SEM), adsorption study (BET) and X-ray diffraction (XRD) patterns. Neat (homogeneous) and immobilized (heterogeneous) complexes were employed as catalysts in the oxidation of olefins, namely, cyclohexene, limonene and α-pinene in the presence of 30% hydrogen peroxide. 100% conversion of cyclohexene and α-pinene was obtained while limonene was oxidized up to 90%. Homogeneous catalysts showed highly selective result as neat [VO(sal2bz)]2 complex has provided 87% cyclohexane-1,2-diol and neat [Fe(sal2bz)(H2O)2]2·2H2O complex has provided 79% verbenone in oxidation of cyclohexene and α-pinene, respectively. We have observed that due to steric hindrance, formation of olefinic oxidation products increases on moving from α-pinene to limonene and limonene to cyclohexene. Additionally. recovered heterogeneous catalysts showed intact results up to two consecutive runs. Probable catalytic mechanism has been proposed for oxidation of cyclohexene

High serum levels of transforming growth factor β1 are associated with increased cortical thickness in cingulate and right frontal areas in healthy subjects

ABSTRACT

Aptamer-based radiopharmaceuticals for diagnostic imaging and targeted radiotherapy of epithelial tumors

In the continuous search for earlier diagnosis and improved therapeutic modalities against cancer, based on our constantly increasing knowledge of cancer biology, aptamers hold the promise to expand on current antibody success, but overcoming some of the problems faced with antibodies as therapeutic or delivery agents in cancer. However, as the first aptamer reached the market as an inhibitor against angiogenesis for the treatment of macular degeneration, aptamers have found only limited applications or interest in oncology, and even less as radiopharmaceuticals for diagnostic imaging and targeted radiotherapy of tumours. Yet, the chemistry for the labelling of aptamers and the options to alter their pharmacokinetic properties, to make them suitable for use as radiopharmaceuticals is now available and recent advances in their development can demonstrate that these molecules would make them ideal delivery vehicles for the development of targeted radiopharmaceuticals that could deliver their radiation load with accuracy to the tumour site, offering improved therapeutic properties and reduced side effects

Oxidation of benzoin catalyzed by oxovanadium (IV) schiff base complexes

BACKGROUND: The oxidative transformation of benzoin to benzil has been accomplished by the use of a wide variety of reagents or catalysts and different reaction procedures. The conventional oxidizing agents yielded mainly benzaldehyde or/and benzoic acid and only a trace amount of benzil. The limits of practical utilization of these reagents involves the use of stoichiometric amounts of corrosive acids or toxic metallic reagents, which in turn produce undesirable waste materials and required high reaction temperatures. In recent years, vanadium complexes have attracted much attention for their potential utility as catalysts for various types of reactions. RESULTS: Active and selective catalytic systems of new unsymmetrical oxovanadium(IV) Schiff base complexes for the oxidation of benzoin is reported. The Schiff base ligands are derived between 2-aminoethanol and 2-hydroxy-1- naphthaldehyde (H2L1) or 3-ethoxy salicylaldehyde (H2L3); and 2-aminophenol and 3-ethoxysalicylaldehyde (H2L2) or 2-hydroxy-1-naphthaldehyde (H2L4). The unsymmetrical Schiff bases behave as tridentate dibasic ONO donor ligands. Reaction of these Schiff base ligands with oxovanadyl sulphate afforded the mononuclear oxovanadium(IV) complexes (VIVOLx.H2O), which are characterized by various physico-chemical techniques. The catalytic oxidation activities of these complexes for benzoin were evaluated using H2O2 as an oxidant. The best reaction conditions are obtained by considering the effect of solvent, reaction time and temperature. Under the optimized reaction conditions, VOL4 catalyst showed high conversion (>99%) with excellent selectivity to benzil (~100%) in a shorter reaction time compared to the other catalysts considered. CONCLUSION: Four tridentate ONO type Schiff base ligands were synthesized. Complexation of these ligands with vanadyl(IV) sulphate leads to the formation of new oxovanadium(IV) complexes of type VIVOL.H2O. Elemental analyses and spectral data of the free ligands and their oxovanadium(IV) complexes were found to be in good agreement with their structures, indicating high purity of all the compounds. Oxovanadium complexes were screened for the oxidation of benzoin to benzil using H2O2 as oxidant. The effect of time, solvent and temperature were optimized to obtain maximum yield. The catalytic activity results demonstrate that these catalytic systems are both highly active and selective for the oxidation of benzoin under mild reaction conditions.Web of Scienc