Chirality and the origin of atmospheric humic-like substances

Aerosol water extracts and atmospheric humic-like substances (HULIS) obtained from PM2.5-fraction aerosol samples collected in a rural/continental background environment and in an urban environment in spring and summer, and at a tropical site that was heavily impacted by biomass burning were studied. HULIS was obtained as the water-soluble, methanol-elutable material isolated from a solid-phase extraction procedure. The mean organic matter-to-organic carbon mass conversion factor and the standard deviation of 2.04 +/- 0.06 were derived for HULIS from biomass burning. Mean atmospheric concentrations of HULIS for the rural and urban environments and for the biomass burning during daylight periods and nights, were 1.65, 2.2, 43, and 60 mu gm(-3), respectively. This and other abundances indicate that intense emission sources and/or formation mechanisms of HULIS operate in biomass burning. Mean contributions of C in HULIS (HULIS-C) to water-soluble organic carbon (WSOC) were 35, 48, 63, and 76%, respectively, for the sample set listed. HULIS-C is the major component of the WSOC in tropical biomass burning. The data also suggest that HULIS most likely do not share common origin in the three environments studied. Differentiation among the possible formation processes was attempted by investigating the optical activity of HULIS through their (electronic and vibrational) circular dichroism properties. The urban HULIS did not show optical activity, which is in line with the concept of their major airborne formation from anthropogenic aromatics. The rural HULIS revealed weak optical activity, which may be associated with one of their important formation pathways by photo-oxidation and oligomerisation, i.e., with the formation from chiral biogenic precursors with one of the enantiomers slightly enriched. The The biomass burning of HULIS exhibited a strong effect in the vibrational circular dichroism as a clear distinction from the other two types. This was related to the contribution of the thermal degradation products of lignins and cellulose. The biomass burning of HULIS resemble Suwannee River Fulvic Acid standard more closely in some aspects than the urban and rural types of HULIS, which may be related to their common origin from plant material

Voltage rectification in two dimensional Josephson junction arrays

We study numerically the directed motion of vortices (antivortices) under an applied ac bias in two-dimensional Josephson junction arrays (JJA) with an asymmetrically modulated periodic vortex pinning potential. We find that the ratchet effect in large 2D JJA can be obtained using the RSJ model for the overdamped vortex dynamics. The rectification effect shows a strong dependence on vortex density as well as an inversion of the vortex flow direction with the ac amplitude, for a wide range of high magnetic field around f=1/2 (f being the vortex density). Our results are in good agreement with very recent experiments by D.E. Shalom and H. Pastoriza [Phys. Rev. Lett. 94, 177001, (2005)].Comment: 4 pages, 4 figures, Proceedings Vortex IV Conference, September 3-9, 2005, Crete, Greece. To appear in Physica

Experimental and numerical study of local mean age of air

This paper presents the results from the experimental and numerical study of a room with mixing ventilation, focused on the local mean age of air (LMA). The measurements were performed using the tracer gas concentration decay method. The numerical predictions were obtained from the computational fluid dynamics (CFD) module of the latest version of the ESP-r software

Quantum phase estimation algorithm in presence of static imperfections

We study numerically the effects of static imperfections and residual couplings between qubits for the quantum phase estimation algorithm with two qubits. We show that the success probability of the algorithm is affected significantly more by static imperfections than by random noise errors in quantum gates. An improvement of the algorithm accuracy can be reached by application of the Pauli-random-error-correction method (PAREC).Comment: 5 pages, 5 figures. Research avilable at http://www.quantware.ups-tlse.fr

Approaching Unit Visibility for Control of a Superconducting Qubit with Dispersive Readout

In a Rabi oscillation experiment with a superconducting qubit we show that a visibility in the qubit excited state population of more than 90 % can be attained. We perform a dispersive measurement of the qubit state by coupling the qubit non-resonantly to a transmission line resonator and probing the resonator transmission spectrum. The measurement process is well characterized and quantitatively understood. The qubit coherence time is determined to be larger than 500 ns in a measurement of Ramsey fringes.Comment: 4 pages, 5 figures, version with high resolution figures available at http://www.eng.yale.edu/rslab/Andreas/content/science/PubsPapers.htm

VH + jet production in hadron-hadron collisions up to order α3s in perturbative QCD

We present precise predictions for the hadronic production of an on-shell Higgs boson in association with a leptonically decaying gauge boson and a jet up to order α3s. We include the complete set of NNLO QCD corrections to both charged- and neutral-current Drell-Yan type contributions, as well as the previously known leading heavy quark loop induced contributions which involve a direct Higgs-quark coupling. As an application, we study a range of differential observables in proton-proton collisions at s√ = 13 TeV for both the charged- and neutral-current production modes. For each Higgs production process, we assess the improvement in the theoretical uncertainty for both the exclusive (njet = 1) and inclusive (njet ≥ 1) jet categories. We find that the inclusion of the NNLO corrections to the Drell-Yan type contributions is essential in stabilising the predictions and in reducing the theoretical uncertainty for both inclusive and exclusive jet production for all three modes. This is particularly true in the kinematical regimes associated with low to medium values of the transverse momentum of the produced vector boson and where the differential cross sections are the largest. For the neutral-current process, we find that the heavy quark loop induced contributions have their largest phenomenological impact (an increase in the size of the NNLO corrections, a distortion of the distribution shape and an enlargement of the left over remaining uncertainties) in kinematical regions associated to large values of pT,Z (typically above 150 GeV) where the cross sections are smaller

Predictions for Z-Boson Production in Association with a b-Jet at O(αs3)

Precise predictions are provided for the production of a Z boson and a b-jet in hadron-hadron collisions within the framework of perturbative QCD, at O(α3s). To obtain these predictions, we perform the first calculation of a hadronic scattering process involving the direct production of a flavored jet at next-to-next-to-leading-order accuracy in massless QCD and extend techniques to also account for the impact of finite heavy-quark mass effects. The predictions are compared to CMS data obtained in pp collisions at a center-of-mass energy of 8 TeV, which are the most precise data from run I of the LHC for this process, where a good description of the data is achieved. To allow this comparison, we have performed an unfolding of the data, which overcomes the long-standing issue that the experimental and theoretical definitions of jet flavor are incompatible

Qubit-photon interactions in a cavity: Measurement induced dephasing and number splitting

We theoretically study measurement induced-dephasing of a superconducting qubit in the circuit QED architecture and compare the results to those obtained experimentally by Schuster {\it et al.}, [Phys. Rev. Lett. 94, 123602 (2005)]. Strong coupling of the qubit to the resonator leads to a significant ac-Stark shift of the qubit transition frequency. As a result, quantum fluctuations in the photon number populating the resonator cause dephasing of the qubit. We find good agreement between the predicted line shape of the qubit spectrum and the experimental results. Furthermore, in the strong dispersive limit, where the Stark shift per photon is large compared to the cavity decay rate and the qubit linewidth, we predict that the qubit spectrum will be split into multiple peaks, with each peak corresponding to a different number of photons in the cavity.Comment: 15 pages and 10 figures. Section IV revised. Author and references added. Version with high resolution figures available at available at http://www.physique.usherbrooke.ca/~ablais/publications.ht