Solvent Mediated Assembly of Nanoparticles Confined in Mesoporous Alumina

The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.Comment: 9 pages, 9 figures, appeared in Phys. Rev.

Lower critical field H_c1 and barriers for vortex entry in Bi_2Sr_2CaCu_2O_{8+delta} crystals

The penetration field H_p of Bi_2Sr_2CaCu_2O_{8+delta} crystals is determined from magnetization curves for different field sweep rates dH/dt and temperatures. The obtained results are consistent with theoretical reports in the literature about vortex creep over surface and geometrical barriers. The frequently observed low-temperature upturn of H_p is shown to be related to metastable configurations due to barriers for vortex entry. Data of the true lower critical field H_c1 are presented. The low-temperature dependence of H_c1 is consistent with a superconducting state with nodes in the gap function. [PACS numbers: 74.25.Bt, 74.60.Ec, 74.60.Ge, 74.72.Hs

Structure of Flux Line Lattices with Weak Disorder at Large Length Scales

Dislocation-free decoration images containing up to 80,000 vortices have been obtained on high quality Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+x}$ superconducting single crystals. The observed flux line lattices are in the random manifold regime with a roughening exponent of 0.44 for length scales up to 80-100 lattice constants. At larger length scales, the data exhibit nonequilibrium features that persist for different cooling rates and field histories.Comment: 4 pages, 3 gif images, to appear in PRB rapid communicatio

The Structure of the Vortex Liquid at the Surface of a Layered Superconductor

A density-functional approach is used to calculate the inhomogeneous vortex density distribution in the flux liquid phase at the planar surface of a layered superconductor, where the external magnetic field is perpendicular to the superconducting layers and parallel to the surface. The interactions with image vortices are treated within a mean field approximation as a functional of the vortex density. Near the freezing transition strong vortex density fluctuations are found to persist far into the bulk liquid. We also calculate the height of the Bean-Livingston surface barrier.Comment: 8 pages, RevTeX, 2 figure

No Ending Point in The Bragg-to-Vortex Glass Phase Transition Line at Low Temperatures

We have measured the magnetic hysteresis loops and the magnetic relaxation for $Bi_2Sr_2CaCu_2O_{8+\delta}$ (Bi-2212) single crystals which exhibit the second magnetization peak effect. Although no second peak effect is observed below 20 K in the measurement with fast field sweeping rate, it is found that the second peak effect will appear again after long time relaxation or in a measurement with very slow field sweeping rate at 16 K. It is anticipated that the peak effect will appear at very low temperatures (approaching zero K) when the relaxation time is long enough. We attribute this phenomenon to the profile of the interior magnetic field and conclude that the phase transition line of Bragg glass to vortex glass has no ending point at low temperatures.Comment: 4 pages, 5 figure

Cu2+-induced self-assembly and amyloid formation of a cyclic d,l-α-peptide: Structure and function

In a wide spectrum of neurodegenerative diseases, self-assembly of pathogenic proteins to cytotoxic intermediates is accelerated by the presence of metal ions such as Cu2+. Only low concentrations of these early transient oligomeric intermediates are present in a mixture of species during fibril formation, and hence information on the extent of structuring of these oligomers is still largely unknown. Here, we investigate dimers as the first intermediates in the Cu2+-driven aggregation of a cyclic D,L-alpha-peptide architecture. The unique structural and functional properties of this model system recapitulate the self-assembling properties of amyloidogenic proteins including beta-sheet conformation and cross-interaction with pathogenic amyloids. We show that a histidine-rich cyclic D,L-alpha-octapeptide binds Cu2+ with high affinity and selectivity to generate amyloid-like cross-beta-sheet structures. By taking advantage of backbone amide methylation to arrest the self-assembly at the dimeric stage, we obtain structural information and characterize the degree of local order for the dimer. We found that, while catalytic amounts of Cu2+ promote aggregation of the peptide to fibrillar structures, higher concentrations dose-dependently reduce fibrillization and lead to formation of spherical particles, showing self-assembly to different polymorphs. For the initial self-assembly step to the dimers, we found that Cu2+ is coordinated on average by two histidines, similar to self-assembled peptides, indicating that a similar binding interface is perpetuated during Cu2+-driven oligomerization. The dimer itself is found in heterogeneous conformations that undergo dynamic exchange, leading to the formation of different polymorphs at the initial stage of the aggregation process

Supercooling of the disordered vortex lattice in Bi_2Sr_2CaCu_2O_8+d

Time-resolved local induction measurements near to the vortex lattice order-disorder transition in optimally doped Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+\delta}$ single crystals shows that the high-field, disordered phase can be quenched to fields as low as half the transition field. Over an important range of fields, the electrodynamical behavior of the vortex system is governed by the co-existence of the two phases in the sample. We interpret the results in terms of supercooling of the high-field phase and the possible first order nature of the order-disorder transition at the ``second peak''.Comment: 4 pages, 3 figures. Submitted to Nature, July 10th, 1999; Rejected August 8th for lack of broad interest Submitted to Physical Review Letters September 10th, 199

Solid-State Microwave Electronics

Contains research objectives and reports on status of research projects.National Aeronautics and Space Administration (Grant NGR-22-009-163

Circuit Quantum Electrodynamics: Coherent Coupling of a Single Photon to a Cooper Pair Box

Under appropriate conditions, superconducting electronic circuits behave quantum mechanically, with properties that can be designed and controlled at will. We have realized an experiment in which a superconducting two-level system, playing the role of an artificial atom, is strongly coupled to a single photon stored in an on-chip cavity. We show that the atom-photon coupling in this circuit can be made strong enough for coherent effects to dominate over dissipation, even in a solid state environment. This new regime of matter light interaction in a circuit can be exploited for quantum information processing and quantum communication. It may also lead to new approaches for single photon generation and detection.Comment: 8 pages, 4 figures, accepted for publication in Nature, embargo does apply, version with high resolution figures available at: http://www.eng.yale.edu/rslab/Andreas/content/science/PubsPapers.htm

Pressure Dependence of the Irreversibility Line in Bi2_{2}Sr2_{2}CaCu2_{2}O8+δ_{8+\delta}:Role of Anisotropy in Flux-Line Formation

One of the important problems of high-temperature superconductivity is to understand and ultimately to control fluxoid motion. We present the results of a new technique for measuring the pressure dependence of the transition to superconductivity in a diamond anvil cell. By measuring the third harmonic of the {\it ac} susceptibility, we determine the onset of irreversible flux motion. This enables us to study the effects of pressure on flux motion. The application of pressure changes interplanar spacing, and hence the interplanar coupling, without significantly disturbing the intraplanar superconductivity. Thus we are able to separate the effects of coupling from other properties that might affect the flux motion. Our results directly show the relationship between lattice spacing, effective- mass anisotropy, and the irreversibility line in Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+\delta}$. Our results also demonstrate that an application of 2.5 GPa pressure causes a dramatic increase in interplanar coupling.Comment: 4 pages, 4 figure