Preparation of proton exchange membrane by radiation-induced grafting method : Grafting of styrene onto poly(ethylene tetrafluoroethylene) copolymer films

Radiation induced grafting of styrene onto poly(ethylene-tetrafluoroethylene) (ETFE) copolymer film was carried out to prepare graft copolymer (ETFE-g-polystyrene) that can host sulfonic acid groups and form proton exchange membrane for polymer electrolyte fuel cell (PEFC). The effect of monomer concentration and type of solvent on the degree of grafting was investigated. The formation of graft copolymer film was confirmed by FTIR spectrum analysis

Optimization of locations of diffusion spots in indoor optical wireless local area networks

In this paper, we present a novel optimization of the locations of the diffusion spots in indoor optical wireless local area networks, based on the central force optimization (CFO) scheme. The users’ performance uniformity is addressed by using the CFO algorithm, and adopting different objective function’s configurations, while considering maximization and minimization of the signal to noise ratio and the delay spread, respectively. We also investigate the effect of varying the objective function’s weights on the system and the users’ performance as part of the adaptation process. The results show that the proposed objective function configuration-based optimization procedure offers an improvement of 65% in the standard deviation of individual receivers’ performance

An approximate dynamic programming approach to food security of communities following hazards

Food security can be threatened by extreme natural hazard events for households of all social classes within a community. To address food security issues following a natural disaster, the recovery of several elements of the built environment within a community, including its building portfolio, must be considered. Building portfolio restoration is one of the most challenging elements of recovery owing to the complexity and dimensionality of the problem. This study introduces a stochastic scheduling algorithm for the identification of optimal building portfolio recovery strategies. The proposed approach provides a computationally tractable formulation to manage multi-state, large-scale infrastructure systems. A testbed community modeled after Gilroy, California, is used to illustrate how the proposed approach can be implemented efficiently and accurately to find the near-optimal decisions related to building recovery following a severe earthquake.Comment: As opposed to the preemptive scheduling problem, which was addressed in multiple works by us, we deal with a non-preemptive stochastic scheduling problem in this work. Submitted to 13th International Conference on Applications of Statistics and Probability in Civil Engineering, ICASP13 Seoul, South Korea, May 26-30, 201

High-pressure behavior of superconducting boron-doped diamond

This work investigates the high-pressure structure of freestanding superconducting ($T_{c}$ = 4.3\,K) boron doped diamond (BDD) and how it affects the electronic and vibrational properties using Raman spectroscopy and x-ray diffraction in the 0-30\,GPa range. High-pressure Raman scattering experiments revealed an abrupt change in the linear pressure coefficients and the grain boundary components undergo an irreversible phase change at 14\,GPa. We show that the blue shift in the pressure-dependent vibrational modes correlates with the negative pressure coefficient of $T_{c}$ in BDD. The analysis of x-ray diffraction data determines the equation of state of the BDD film, revealing a high bulk modulus of $B_{0}$=510$\pm$28\,GPa. The comparative analysis of high-pressure data clarified that the sp$^{2}$ carbons in the grain boundaries transform into hexagonal diamond.Comment: 7 pages, 4 figure

Long and short paths in uniform random recursive dags

In a uniform random recursive k-dag, there is a root, 0, and each node in turn, from 1 to n, chooses k uniform random parents from among the nodes of smaller index. If S_n is the shortest path distance from node n to the root, then we determine the constant \sigma such that S_n/log(n) tends to \sigma in probability as n tends to infinity. We also show that max_{1 \le i \le n} S_i/log(n) tends to \sigma in probability.Comment: 16 page

Effects of contact resistance and metal additives in finned-tube adsorbent beds on the performance of silica gel/water adsorption chiller

Recently interest in adsorption cooling systems has increased due to their capability to utilise low grade heat sources and environmentally friendly refrigerants. Currently, most of the commercially available adsorption cooling systems utilise granular packed adsorbent beds. Enhancing the heat transfer process inside the adsorbent bed will improve the overall efficiency of the adsorption system. Using recently developed empirical lumped analytical simulation model for a 450 kW two-bed silica gel/water adsorption chiller, this paper theoretically investigates the effects of various adsorbent bed heat transfer enhancement techniques on the adsorption system cooling capacity. Firstly, coating the first adsorbent layer to the metal part and packing the rest of adsorbent granules to eliminate the thermal contact resistance between heat exchanger metal and granules while keeping the same level of permeability. Secondly, adding metal particles to the adsorbent in order to enhance the granules thermal conductivity. The effective thermal conductivity of adsorbent/metal mixtures were determined and validated by comparing it with published experimental data. Also, the combined effect of using both techniques simultaneously was investigated. All these investigations were carried out at various adsorption bed fin spacing. Results of the combined techniques showed that the enhancement in the cooling capacity and system coefficient of performance (COP) increased with increasing the fin spacing ratio to reach maximum of 25% and 10% respectively at fin spacing ratio of 2

Performance of multi junction photovoltaic cells with high concentration ratio

AbstractConcentrating solar radiation on Photovoltaic (PV) has the potential to replace the expensive PV material with cheaper optical elements which also enhance the overall electrical output. The use of high solar concentration ratios with the triple junction III-V solar cells offers potential of high solar cell efficiency and power output. However, using high concentration ratios will increase the solar cell surface temperature which is inversely proportional to the PV electrical efficiency. This work investigates the effect of active cooling on the performance of triple junction PV cells with high solar concentration (up to 500X) in the harsh environment of Saudi Arabia where ambient temperatures can reach to 50o C in summer time, but with good clearance index of 0.6 and high yearly solar radiation of up to 2200 kWh/m2. Simulation results showed that as the concentration ratio increases, the effect of cooling on the PV efficiency increases

Thermal analysis of stirling engine to power automotive alternator using heat from exhaust gases

AbstractThis paper investigates the development of small scale beta type Stirling engine to recover the exhaust heat from the main engine and to drive the alternator (decouple it from the main engine), thus providing the required electrical power for onboard devices. The ideal adiabatic model was used to predict the thermodynamic performance of the engine. CFD investigation was also carried out to optimise the heater and the cooler geometry of the Stirling engine. The results showed that it is possible to generate a power output of 1.5-2kWe at an ideal thermal efficiency of 40% and engine overall weight of 11-14kg