Assessment and enhancement of MERRA land surface hydrology estimates

The Modern-Era Retrospective Analysis for Research and Applications (MERRA) is a state-of-the-art reanalysis that provides, in addition to atmospheric fields, global estimates of soil moisture, latent heat flux, snow, and runoff for 1979 present. This study introduces a supplemental and improved set of land surface hydrological fields ("MERRA-Land") generated by rerunning a revised version of the land component of the MERRA system. Specifically, the MERRA-Land estimates benefit from corrections to the precipitation forcing with the Global Precipitation Climatology Project pentad product (version 2.1) and from revised parameter values in the rainfall interception model, changes that effectively correct for known limitations in the MERRA surface meteorological forcings. The skill (defined as the correlation coefficient of the anomaly time series) in land surface hydrological fields from MERRA and MERRA-Land is assessed here against observations and compared to the skill of the state-of-the-art ECMWF Re-Analysis-Interim (ERA-I). MERRA-Land and ERA-I root zone soil moisture skills (against in situ observations at 85 U.S. stations) are comparable and significantly greater than that of MERRA. Throughout the Northern Hemisphere, MERRA and MERRA-Land agree reasonably well with in situ snow depth measurements (from 583 stations) and with snow water equivalent from an independent analysis. Runoff skill (against naturalized stream flow observations from 18 U.S. basins) of MERRA and MERRA-Land is typically higher than that of ERA-I. With a few exceptions, the MERRA-Land data appear more accurate than the original MERRA estimates and are thus recommended for those interested in using MERRA output for land surface hydrological studies

Mechanisms Associated with Daytime and Nighttime Heat Waves over the United States

Heat waves are extreme climate events that have the potential to cause immense stress on human health, agriculture and energy systems, so understanding the processes leading to their onset is crucial. There is no single accepted definition for heat waves, but they are generally described as a sustained amount of time where temperature exceeds a local threshold. Multiple different temperature variables are potentially relevant, as high values of daily maximum (T(max)) and minimum (T(min)) temperatures can both be detrimental to human health. Previous studies have concluded that the frequency of global heat waves has increased over recent decades, with greater increases in T(min)- than T(max)-heat waves in several regions. In this study, we focus explicitly on the different mechanisms associated with heatwaves manifest during daytime versus nighttime hours over the United States. Heat waves are examined using the National Aeronautics and Space Administration (NASA) Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2). A daytime (nighttime) heat wave is defined as average daytime (nighttime) temperature exceeding its calendar day 90th percentile for at least 3 days. Over 1980-2018, the number of heat wave days per summer has increased over much of the United States. Trends are stronger for nighttime versus daytime heat wave frequency over the Northeast, Midwest and Southwest United States. Local and remote processes linked with daytime and nighttime heat waves are identified through composite analysis of clouds, precipitation, soil moisture, and fluxes of heat and moisture. Finally, we characterize the large-scale atmospheric circulation associated with daytime and nighttime heat waves over different regions of the United States

CONSTRUCTION OF A LOW COST AIR SAMPLER AND IT'S APPLICATION IN SAMPLING VOLATILE CARBONYL COMPOUNDS

lntcrcxt is expanding in measuring. concentrations of volatile organic compounds inbuildings since it is rccogniscd that many peoples' exposure to these compounds occur inthe indoor environment. However. such data are not available in Sri Lanka primarily dueto lack 01"proper equipment for quantitation and their high maintenance cost. This paperdcxcribcx the construction of a low cost air sampler (Rs. 40()/=) using commonly availablematerials.The air sampler contains a muffler fan to pull .unhient air though a filrcrts) and/or a bed ofsorhcnt material. which are housed in a variable length pye tube. Battery poweredmuffler fan and lightweight are two of the convenient features of this air sampler thatminimisc operational and transportation difficulties to the user.Vularilc carbonyl compounds such as formaldehyde acetaldehyde and acetone arecommonly found in indoors ambient air due to the combustion sources and emissions fromsvnthcric household products. Since formaldehyde is a known carcinogen andacetaldehyde is a suspected carcinogen compound. they were selected as the modelcompounds for the evaluation of constructed sampler. A filter paper spiked with 2. 4-dinitrophcnylhydruzcnc is used to collect the airborne carbonyl compounds at a flow rate ofI.X Cill'/SCC. Filters were sonicated in methanol and extracts were separated using a C,xcolumn for qu.uuitation at lSO mm wavelength. Quanutaiion limits estimates thats.unpling of I () dm ' ambient air enables minimum quantitauon of O.S formaldehyde. 1.0acetaldehyde and 1.2 acetone accurately. The paper also reports quantified levels ofairborne carbonyls from different indoor environments.

INVESTIGATION OF SULFUR COMPOUNDS IN SELECTED STAGNANT WATER BODIES

Sulfur compounds, primarily in the form of sulfides (S2.), sulfites (50)'") andsulfates (50t) have been neglected but has a strong effect upon water quality.The dark colour sediments and strong unpleasant ordours often indicate the 52.contamination in aquatic bodies. To the best of our knowledge, no attempt hasbeen made to investigate these compounds and to asses their contribution to thedegradation of water quality. Both the bacteria and dissolved oxygen (DO) areplaying leading roles in determining the fate of 5 containing compounds inaquatic systems.In this investigation it was intended to study the possible relationships betweensulfur species and DO. Four urban stagnant water bodies effected by impropersewage disposal, industrial waste, wet and dry deposition of atmospheric 50/'were investigated along with a prawn farm and two coconut husk soaking pitsinherited with S compounds. These water bodies indicated the emission ofvolatile 5 compounds. These water bodies indicated the emission of volatile 5compounds From their characteristic rotten egg smell.Under this study 52., SO)·2 and 50t levels were monitored along with DO, pHand temperature to investigate the possible correlation method introduced byPawlak and Pawlak (1999) was employed in determination of 52. levels while allother parameters were measured by employing standard methods.Based on the results obtained, only S2. shows a significant correlation with DOunder ambient conditions. Finally, measured dissolved 52. levels were utilized todetermine the possible H25 emission levels. Calculations have shown that each ofthe water body is emitting gaseous H25 and in most cases, emission levels aregreater than the ordour thresholds accounting for the unpleasant smell near thesestagnant water bodies.*Correspondence author

Toxic Volatile Organic Compounds in Environmental Tobacco Smoke:Emission Factors for Modeling Exposures of California Populations

The primary objective of this study was to measure emission factors for selected toxic air in environmental tobacco smoke (ETS) using a room-sized environmental chamber. The emissions of 23 volatile organic compounds (VOCs), including 1,3-butadiene, three aldehydes and two vapor-phase N-nitrosarnines were determined for six commercial brands of cigarettes and reference cigarette 1R4F. The commercial brands were selected to represent 62.5% of the cigarettes smoked in California. For each brand, three cigarettes were machine smoked in the chamber. The experiments were conducted over four hours to investigate the effects of aging. Emission factors of the target compounds were also determined for sidestream smoke (SS). For almost all target compounds, the ETS emission factors were significantly higher than the corresponding SS values probably due to less favorable combustion conditions and wall losses in the SS apparatus. Where valid comparisons could be made, the ETS emission factors were generally in good agreement with the literature. Therefore, the ETS emission factors, rather than the SS values, are recommended for use in models to estimate population exposures from this source. The variabilities in the emission factors (pgkigarette) of the selected toxic air contaminants among brands, expressed as coefficients of variation, were 16 to 29%. Therefore, emissions among brands were generally similar. Differences among brands were related to the smoked lengths of the cigarettes and the masses of consumed tobacco. Mentholation and whether a cigarette was classified as light or regular did not significantly affect emissions. Aging was determined not to be a significant factor for the target compounds. There were, however, deposition losses of the less volatile compounds to chamber surfaces

Contribution of dissolved sulfates and sulfites in hydrogen sulfide emission from stagnant water bodies in Sri Lanka

Abstract Accumulation of sulfur-containing compounds and their bacterial mediated reductions have led to the emission of pungent odors from stagnant water bodies. This study is focused on the contribution of inorganic sulfur compounds in the emission of hydrogen sulfide. The measured dissolved oxygen levels have demonstrated good negative correlations with the dissolved sulfide levels implying the oxygen deficiency is the key for the reduction of sulfate ion and sulfite ion to sulfide ion. Particularly, the dissolved molar fractions of sulfide from the total dissolved sulfur compounds (sulfates, sulfites and sulfides) have a very good correlation with the dissolved oxygen for the stagnant water bodies except the artificially aerated prawn farms. For the stagnant water bodies with significant correlations, linear regressions are reported for them to be utilized in estimating one component of the regression from the measurement of the other. The measured data were further utilized to estimate the levels of hydrogen sulfide gas. The pH of the water bodies has confined much of the dissolved sulfides in the form of bisulfide ion and they can be easily escaped to the atmosphere upon acidification due to industrial discharges and/or acidic precipitations. The estimated levels of hydrogen sulfide just above the water surface were plotted for the most polluted stagnant water body in Sri Lanka for the pH range of 5-10 and temperature range of 25-35°C

Assessment and Enhancement of MERRA Land Surface Hydrology Estimates

The Modern-Era Retrospective analysis for Research and Applications (MERRA) is a state-ofthe-art reanalysis that provides, in addition to atmospheric fields, global estimates of soil moisture, latent heat flux, snow, and runoff for 1979-present. This study introduces a supplemental and improved set of land surface hydrological fields ("MERRA-Land") generated by re-running a revised version of the land component of the MERRA system. Specifically, the MERRA-Land estimates benefit from corrections to the precipitation forcing with the Global Precipitation Climatology Project pentad product (version 2.1) and from revised parameter values in the rainfall interception model, changes that effectively correct for known limitations in the MERRA surface meteorological forcings. The skill (defined as the correlation coefficient of the anomaly time series) in land surface hydrological fields from MERRA and MERRA-Land is assessed here against observations and compared to the skill of the state-of-the-art ERA-Interim (ERA-I) reanalysis. MERRA-Land and ERA-I root zone soil moisture skills (against in situ observations at 85 US stations) are comparable and significantly greater than that of MERRA. Throughout the northern hemisphere, MERRA and MERRA-Land agree reasonably well with in situ snow depth measurements (from 583 stations) and with snow water equivalent from an independent analysis. Runoff skill (against naturalized stream flow observations from 18 US basins) of MERRA and MERRA-Land is typically higher than that of ERA-I. With a few exceptions, the MERRA-Land data appear more accurate than the original MERRA estimates and are thus recommended for those interested in using MERRA output for land surface hydrological studies

What do We Know the Snow Darkening Effect Over Himalayan Glaciers?

The atmospheric absorbing aerosols such as dust, black carbon (BC), organic carbon (OC) are now well known warming factors in the atmosphere. However, when these aerosols deposit onto the snow surface, it causes darkening of snow and thereby absorbing more energy at the snow surface leading to the accelerated melting of snow. If this happens over Himalayan glacier surface, the glacier meltings are expected and may contribute the mass balance changes though the mass balance itself is more complicated issue. Glacier has mainly two parts: ablation and accumulation zones. Those are separated by the Equilibrium Line Altitude (ELA). Above and below ELA, snow accumulation and melting are dominant, respectively. The change of ELA will influence the glacier disappearance in future. In the Himalayan region, many glacier are debris covered glacier at the terminus (i.e., in the ablation zone). Debris is pieces of rock from local land and the debris covered parts are probably not affected by any deposition of the absorbing aerosols because the snow surface is already covered by debris (the debris covered parts have different mechanism of melting). Hence, the contribution of the snow darkening effect is considered to be most important "over non debris covered part" of the Himalayan glacier (i.e., over the snow or ice surface area). To discuss the whole glacier retreat, mass balance of each glacier is most important including the discussion on glacier flow, vertical compaction of glacier, melting amount, etc. The contribution of the snow darkening is mostly associated with "the snow/ice surface melting". Note that the surface melting itself is not always directly related to glacier retreats because sometimes melt water refreezes inside of the glacier. We should discuss glacier retreats in terms of not only the snow darkening but also other contributions to the mass balance

Use of Volatile Tracers to Determine the Contribution ofEnvironment Tobacco Smoke to Concentrations of Volatile Organic Compoundsin Smoking Environments

Three volatile nitrogen-containing compounds, 3-ethenylpyridine (3-EP), pyridine and pyrrole, were investigated as potential tracers for determining the contribution of environmental tobacco smoke (ETS) to concentrations of volatile organic compounds (VOCs) in indoor environments with smoking. The source emission rates of the three tracers and ten selected VOCs in ETS were first measured in a room-size environmental chamber for a market-weighted selection of six commercial cigarettes. The ratios of the emission rates of the tracers to the emission rates of the selected VOCs were calculated and compared among the six brands. The utility of the tracers was then evaluated in a field study conducted in five office buildings. Samples for VOCs were collected in designated smoking areas and adjoining non-smoking areas, air change rates were measured, and smoking rates were documented. Concentrations of the three tracers in the smoking areas were calculated using a mass-balance model and compared to their measured concentrations. Based on this comparison, 3-EP was selected as the most suitable tracer for the volatile components of ETS, although pyrrole is also potentially useful. Using 3-EP as the tracer, the contributions of ETS to the measured concentrations of the selected VOCs in the smoking areas were estimated by apportionment. ETS was estimated to contribute 57 to 84 percent (4.1 to 26 pg m{sup -3}) of the formaldehyde concentrations, 44 to 69 percent (0.9 to 5.8 pg m{sup -3}) of the 2-butanone concentrations, 37 to 58 percent (1.3 to 8.2 pg m{sup -3}) of the benzene concentrations, and 20 to 69 percent (0.5 to 3.0 pg m{sup -3}) of the styrene concentrations. The fractional contributions of ETS to the concentrations of acetone, toluene, ethylbenzene, xylene isomers and d-limonene were all less than 50 percent