economic feasibility of methanol synthesis as a method for co2 reduction and energy storage

Abstract In this paper, a thermo-economic analysis concerning a methanol production plant is performed. In particular, this study was developed with the aim of evaluating the opportunity and viability of obtaining methanol from the chemical reaction between recycled CO2, emitted from a fossil-fuel power station, and hydrogen produced by water electrolysis. This solution can represent an interesting carbon dioxide reduction method and methanol as a product can be considered an energy storage means. As a first step, a thermodynamic analysis is performed in order to determine the mass and energy flows of the plant; then, a feasibility analysis concerning a large size methanol production plant is performed taking into account three different economic scenarios (Germany, Italy, and China). In order to evaluate the economic viability, the total investment cost and payback period are calculated in all the scenarios. Different methanol and electrical energy prices are considered, to take into proper account the influence of these parameters on mid-term future scenarios. Moreover, a sensitivity analysis, considering different oxygen selling prices and PEM electrolyzer capital costs, were performed

Turbocharged Solid Oxide Fuel Cell System: Design and Emulation

This paper presents a design model of a turbocharged solid oxide fuel cell system fueled by biogas. The aim of this plant layout is the development of a low-cost solution considering the coupling of the solid oxide fuel cell (SOFC) with a low-cost machine such as a turbocharger (instead of a microturbine). The whole system model calculates the operational conditions and realizes the coupling between the turbocharger, the recuperator and the solid oxide fuel cell system (comprising SOFC, air preheater, fuel compressor and pre-heater, reformer, off-gas burner and anodic ejector). This model also supports the design of an emulator test rig in which a burner, located inside a thermal insulated vessel, replaces the solid oxide fuel cell system. The emulator test rig will be useful to study the matching between the turbocharger and the fuel cell to validate simulation models, design innovative solutions and test the control system of the whole plant

Techno-economic analysis for the integration of a power to fuel system with a CCS coal power plant

In this paper, an analysis of the integration of a carbon capture unit and a power to fuel system for methanol synthesis with a coal power plant is presented from the energetic, environmental and economic standpoints. The study is carried out in three different sections. In the first part, the impact of the integration of a carbon capture system (CCS ) and of a power to fuel plant (PtF) for methanol production is investigated in terms of plant average efficiency, fuel consumption,CO2 emissions. In the second part, the annual fixed and variable costs of the power plant, and the annual cost of electricity (COE) are assessed for different plant configurations. Additionally, future scenarios are analyzed considering the impact of European policies on the CO2 emission\u2019s cost, defined by the European Emission Trading System (ETS). Finally, an economic feasibility analysis of the power to fuel plant is performed and the methanol production is evaluated. Moreover, a sensitivity analysis is carried out to evaluate the impact of the most affecting parameters (electrical energy cost, the methanol selling price and the capital cost of the electrolyzer) in terms of Internal Rate of Return (IRR)

A multi-criteria approach for comparing alternative fuels and energy systems for marine applications

This paper presents an algorithm to compare traditional and innovative energy systems for maritime applications, adopting a multi-criteria method. The algorithm includes a large and updated database of market solutions. Two case studies are investigated: (i) a sailing yacht (ii) and a large-size cruise ship. For case (i), Fuel Cells represent a competitive solution, in particular considering navigation in emission control areas; the installation of electrical batteries is also evaluated. For case study (ii) Internal Combustion Engines are the best solution: the evaluation of alternative fuels (LNG, ammonia, methanol) is performed, also in dual-fuel configuration

A multi-criteria approach for assessment of maritime sector energy systems

This paper describes a multi-criteria tool for the performance comparison of alternative and conventional on board energy systems for maritime sector, both for hotel and propulsion loads, depending on the mission taken into account. The tool, named HELM (Helper for Energy Layouts in Maritime applications), carries out this analysis based on an extended and up-to-date market database of many technologies in terms of power units and suitable fuel storage systems. A wide range of maps has been created, correlating costs, volumes, weights, emissions and fuel environmental hazards with the installed power and the operational hours, given by the user as input. In this work, different maritime vessels typologies are investigated and the choice of the best solution is performed for each one, considering the single evaluation parameters. It is worth noting that the multi-criteria analysis carried out has a general approach, allowing it to give preliminary information on the energy system, in order to respect new requirements (e.g. more and more stringent normative in terms of pollutant emissions in ports and restricted areas). HELM can be used for many design approaches, either for a new ship project or for already existing ships retrofit; furthermore, the database can be easily extended to other generation and storage technologies

From Listing to Recovery: A Review of Nutritional Status Assessment and Management in Liver Transplant Patients

Liver transplantation (LT) is a complex surgical procedure requiring thorough pre- and post-operative planning and care. The nutritional status of the patient before, during, and after LT is crucial to surgical success and long-term prognosis. This review aims to assess nutritional status assessment and management before, during, and after LT, with a focus on patients who have undergone bariatric surgery. We performed a comprehensive topic search on MEDLINE, Ovid, In-Process, Cochrane Library, EMBASE, and PubMed up to March 2023. It identifies key factors influencing the nutritional status of liver transplant patients, such as pre-existing malnutrition, the type and severity of liver disease, comorbidities, and immunosuppressive medications. The review highlights the importance of pre-operative nutritional assessment and intervention, close nutritional status monitoring, individualised nutrition care plans, and ongoing nutritional support and monitoring after LT. The review concludes by examining the effect of bariatric surgery on the nutritional status of liver transplant recipients. The review offers valuable insights into the challenges and opportunities for optimising nutritional status before, during, and after LT

Recommended vaccinations for asplenic and hyposplenic adult patients

Asplenic or hyposplenic (AH) individuals are particularly vulnerable to invasive infections caused by encapsulated bacteria. Such infections have often a sudden onset and a fulminant course. Infectious diseases (IDs) incidence in AH subjects can be reduced by preventive measures such as vaccination. The aim of our work is to provide updated recommendations on prevention of infectious diseases in AH adult patients, and to supply a useful and practical tool to healthcare workers for the management of these subjects, in hospital setting and in outpatients consultation. A systematic literature review on evidence based measures for the prevention of IDs in adult AH patients was performed in 2015. Updated recommendations on available vaccines were consequently provided. Vaccinations against S. pneumoniae, N. meningitidis, H. influenzae type b and influenza virus are strongly recommended and should be administered at least 2 weeks before surgery in elective cases or at least 2 weeks after the surgical intervention in emergency cases. In subjects without evidence of immunity, 2 doses of live attenuated vaccines against measles-mumps-rubella and varicella should be administered 4–8 weeks apart from each other; a booster dose of tetanus, diphtheria and pertussis vaccine should be administered also to subjects fully vaccinated, and a 3-dose primary vaccination series is recommended in AH subjects with unknown or incomplete vaccination series (as in healthy people). Evidence based prevention data support the above recommendations to reduce the risk of infection in AH individuals

Physician Attitudes and Perceptions of Complementary and Alternative Medicine (CAM): A Multicentre Italian Study

Purpose: Complementary and Alternative Medicine (CAM) interventions are widely used by patients with chronic disorders, including cancer, and may interact with cancer treatment. Physicians are often unaware of this, probably due to poor patient-physician communication on CAM. The purpose of this study was to evaluate physicians' knowledge, attitudes and practice patterns regarding CAM in a survey conducted in Italy. Methods: A questionnaire was administered to 438 physicians (11 Italian hospitals) who predominantly treat patients with chronic disease, to collect personal and professional data and information on attitudes toward CAM and its possible role in Conventional Medicine (CM). Results: Of the 438 participants, most were specialists in oncology (18%), internal medicine (17%), surgery (15%), and radiotherapy (11%). Most worked at university (44%) or research hospitals (31%). Forty-two percent of participants believed that CAM could have an integrative role within CM. Oncologists were the physicians who were best informed on CAM (58%). Physicians working at research institutes or university hospitals had a greater knowledge of CAM than those employed at general hospitals (p < 0.0001), and those who were also involved in research activity had a greater knowledge of CAM than those who were not (p < 0.003). Length of work experience was significantly related to CAM knowledge. Moreover, 55% of participants suggest CAM interventions to their patients and 44% discuss CAM with them. The best-known interventions were acupuncture, Aloe vera and high-dose vitamin C. Conclusion: CAM use by patients with chronic disease and/or cancer has become a topical issue for the scientific community and for physicians. Knowing the reasons that prompt these patients to use CAM and guiding them in their decisions would improve treatment and outcomes and also benefit healthcare systems. Our findings contribute to a greater understanding of CAM knowledge, attitudes, and practice among Italian physicians. Further research is needed to identify the more effective CAM treatments and to work toward an integrated healthcare model