Photocatalytic Activity and Mechanical Properties of Cements Modified with TiO2/N

In this paper, studies of the mechanical properties and photocatalytic activity of new photoactive cement mortars are presented. The new building materials were obtained by the addition of 1, 3, and 5 wt % (based on the cement content) of nitrogen-modified titanium dioxide (TiO2/N) to the cement matrix. Photocatalytic active cement mortars were characterized by measuring the flexural and the compressive strength, the hydration heat, the zeta potential of the fresh state, and the initial and final setting time. Their photocatalytic activity was tested during NOx decomposition. The studies showed that TiO2/N gives the photoactivity of cement mortars during air purification with an additional positive effect on the mechanical properties of the hardened mortars. The addition of TiO2/N into the cement shortened the initial and final setting time, which was distinctly observed using 5 wt % of the photocatalyst in the cement matrix

Manipulacja: pedagogiczno-społeczne aspekty. Cz. 1, Interdyscyplinarne aspekty manipulacji

Praca recenzowana / peer-reviewed pape

Chemical Composition and Related Properties of Lime (Tilia cordata Mill.) Bark and Wood as Affected by Tree Growth Conditions

Tilia cordata Mill. is a favourite tree used in urban spaces. For this reason, it is important to know its sensitivity to environmental stress, which is particularly burdensome for vegetation in urban spaces. The aim of the study was to investigate the properties necessary to control the growth of these trees and their subsequent use, i.e., chemical properties (percentage contents of cellulose, holocellulose, lignin, pentosans and substances soluble in NaOH and EtOH) as well as the chemical elements (K, Na, Mg, Ca and Fe, Zn, Cu, Pb, Cd, B, Ni, Cr, Al, As and Hg) and selected hygroscopic properties (hysteresis and sorption isotherms). Trees of Tilia cordata Mill. growing in environments exposed to environmental stress of varying severity were examined. Regardless of the growth conditions, in terms of its chemical composition, bark differs significantly from wood, showing twice the contents of soluble substances in NaOH and lignin and half the content of polysaccharides. Growth conditions clearly affect the range of selected chemical components in bark, e.g., substances soluble in ethanol, cellulose, or lignin. The main inorganic elements in bark and wood are Na, K, Ca, Mg and Zn. In bark, a relationship was found between the content of most chemical elements and differing environmental growth conditions. It was shown that environmental stress influenced the hygroscopic properties of wood and bark, which are a consequence of the percentage of chemical components

Study of Nitrogen-Modified Titanium Dioxide as an Adsorbent for Azo Dyes

The removal of two azo dyes from aqueous solution was investigated using a highly active nitrogen-modified titanium dioxide (TiO 2 /N). This photocatalyst was prepared by pressure modification of a commercial sample of anatase, TiO 2 (supplied by Zaklady Chemiczne Police SA, Poland). The adsorption of two azo dyes (Reactive Red 198 — a monoazo dye and Direct Green 99 — a polyazo dye) onto the unmodified and nitrogen-modified TiO 2 surface was determined. Adsorption onto unmodified TiO 2 led to an isotherm which could be described by the Freundlich model, whereas that onto the nitrogen-modified TiO 2 surface was best described by the Langmuir model. The adsorption isotherms of Direct Green 99 onto TiO 2 /N from aqueous solutions at various pH values were compared with those onto unmodified TiO 2 during dye removal under UV irradiation. Such a comparison is important since it provides information as to how solutes interact with adsorbents. Zeta potential measurements of TiO 2 provided an explanation for the observed behaviour in terms of the surface charge. The IR spectrum of the photocatalyst obtained exhibited new absorption bands at 1430–1440 cm −1 which were attributed to the bending vibrations of NH + 4 and at 1535 cm −1 associated with NH 2 groups or NO 2 and NO groups

A New Preparation Method of Cement with Photocatalytic Activity

The studies of some mechanical properties and photocatalytic activity of new cements with photocatalytic activity are presented. The new building materials were obtained by addition of semi-product from titanium white production. Semi-product was calcined at 300 and 600 °C for one, three, and five hours and then this material was added to cement matrix in an amount of 1 and 3 wt.%. New materials were characterized by measuring the flexural and compressive strength and the initial and the final setting time. The photocatalytic activity was tested during NOx photooxidation. The cement with photocatalytic activity was also characterized by sulphur content measurements. The measurement of reflectance percentage of TiO2-loaded cements in comparison with pristine cement and TiO2 photocatalyst calcined at 600 °C were also performed. It should be emphasized that although in some cases, the addition of photocatalyst reduced the flexural and the compressive strength of the modified cements, these values were still within the norm PN-EN 197-1:2012. It was also found that the initial and the final setting time is connected with the crystal size of anatase, and the presence of larger crystals significantly delays of the setting time. This was probably caused by a water adsorption on the surface of anatase crystals

Transcriptional response of Cu-deficient barley (Hordeum vulgare L.) to foliar-applied nano-Cu: Molecular crosstalk between Cu loading into plants and changes in Cu homeostasis genes

International audienc

Evaluation of Environmental Impact on Selected Properties of Lime (Tilia Cordata Mill.) Wood

The external and internal factors in the tree development process affect wooden structures and properties. They depend on, for example, a plant species, its age, part and growth conditions. The present study investigated the chemical structure and physical properties of the common urban tree species: small-leaved lime (Tilia cordata Mill.). The properties of trees growing in an urban agglomeration, by a roadside and in a forest, i.e., areas varying in degrees of an environmental stress impact, were compared. Tree-ring width and density, selected hygroscopic properties (sorption hysteresis and isotherms), wood chemical content (percentage content of: holocellulose, cellulose, pentosanes, lignin and substances soluble in 1% NaOH and EtOH) as well as the content of selected chemical elements (Fe, Zn, Cu, Pb, Cd, K, Na, Mg and Ca) were studied. The analysis of the case shows no impact of the environmental stress on the growth patterns characterized by ring width index (RWI). Two-factor analysis of variance (ANOVA) revealed impact significance of growth environment and cambial age on the content of each of the investigated components and chemical elements. There was a relationship demonstrated that for a tree growing in an agglomeration with the highest environmental stress the content of cellulose and lignin was the lowest, whereas the content of substances soluble in NaOH and EtOH was the highest. For mature wood growing under the same conditions, the results corresponded to the highest Zn, Cu, K, Na, Mg and Ca content. It was also shown that the environmental stress affected hygroscopicity which was the consequence of chemical component percentage content. The research proved that Tilia cordata Mill. responded to environmental stress with alternations in its chemical or/and physical properties

NOx photocatalytic degradation on gypsum plates modified by TiO2-N,C photocatalysts

In presented studies the photocatalytic decomposition of NOx on gypsum plates modified by TiO2-N,Cphotocatalysts were presented. The gypsum plates were obtained by addition of 10 or 20 wt.% of different types of titanium dioxide, such as: pure TiO2 and carbon and nitrogen co-modified TiO2 (TiO2-N,C) to gypsum. TiO2-N,C photocatalysts were obtained by heating up the starting TiO2 (Grupa Azoty Zakłady Chemiczne Police S.A) in the atmosphere of ammonia and carbon at the temperature: 100, 300 i 600ºC. Photocatalyst were characterized by FTIR/DRS, UVVis/DR, BET and XRD methods. Moreover the compressive strength tests of modified gypsum were also done. Photocatalytic activity of gypsum plates was done during NOx decomposition. The highest photocatalytic activity has gypsum with 20 wt.% addition of TiO2-N,C obtained at 300ºC