714 research outputs found
The electrorheology of suspensions consisting of Na-Fluorohectorite synthetic clay particles in silicon oil
Under application of an electric field greater than a triggering electric
field kV/mm, suspensions obtained by dispersing particles of the
synthetic clay fluoro-hectorite in a silicon oil, aggregate into chain- and/or
column-like structures parallel to the applied electric field. This
micro-structuring results in a transition in the suspensions' rheological
behavior, from a Newtonian-like behavior to a shear-thinning rheology with a
significant yield stress. This behavior is studied as a function of particle
volume fraction and strength of the applied electric field, . The steady
shear flow curves are observed to scale onto a master curve with respect to
, in a manner similar to what was recently found for suspensions of laponite
clay [42]. In the case of Na-fluorohectorite, the corresponding dynamic yield
stress is demonstrated to scale with respect to as a power law with an
exponent , while the static yield stress inferred from
constant shear stress tests exhibits a similar behavior with . The suspensions are also studied in the framework of thixotropic fluids:
the bifurcation in the rheology behavior when letting the system flow and
evolve under a constant applied shear stress is characterized, and a
bifurcation yield stress, estimated as the applied shear stress at which
viscosity bifurcation occurs, is measured to scale as with to 0.6. All measured yield stresses increase with the particle
fraction of the suspension. For the static yield stress, a scaling law
, with , is found. The results are found to be
reasonably consistent with each other. Their similarities with-, and
discrepancies to- results obtained on laponite-oil suspensions are discussed
Velocity Profiles in Slowly Sheared Bubble Rafts
Measurements of average velocity profiles in a bubble raft subjected to slow,
steady-shear demonstrate the coexistence between a flowing state and a jammed
state similar to that observed for three-dimensional foams and emulsions
[Coussot {\it et al,}, Phys. Rev. Lett. {\bf 88}, 218301 (2002)]. For
sufficiently slow shear, the flow is generated by nonlinear topological
rearrangements. We report on the connection between this short-time motion of
the bubbles and the long-time averages. We find that velocity profiles for
individual rearrangement events fluctuate, but a smooth, average velocity is
reached after averaging over only a relatively few events.Comment: typos corrected, figures revised for clarit
Motion-enhanced, differential interference contrast (MEDIC) microscopy of moving vesicles in live cells: VE-DIC updated
Video-enhanced DIC microscopy (VE-DIC) with background subtraction has made visible many structures and processes in living cells. In VE-DIC, the background image is stored manually by defocusing the microscope before images are acquired. We have updated and improved VE-DIC by adding automatic generation of the background image as a rolling average of the incoming image stream. Subtraction of this continuously updated 12-bit background image from the incoming 12-bit image stream provides a flat background which allows the contrast of moving objects, such as vesicles, to be strongly enhanced while suppressing stationary features such as the overall cell shape. We call our method MEDIC, for motion-enhanced DIC. By carrying out background subtraction with 12-bit images, the number of graylevels in the moving vesicles can be maximized and a single look-up table can be applied to the entire image, enhancing the contrast of all vesicles simultaneously. Contrast is increased by as much as a factor of 13. The method is illustrated with raw, background, and MEDIC images of moving vesicles within a neurite of a live PC12 cell and a live chick motorneuron
Vortex jamming in superconductors and granular rheology
We demonstrate that a highly frustrated anisotropic Josephson junction
array(JJA) on a square lattice exhibits a zero-temperature jamming transition,
which shares much in common with those in granular systems. Anisotropy of the
Josephson couplings along the horizontal and vertical directions plays roles
similar to normal load or density in granular systems. We studied numerically
static and dynamic response of the system against shear, i. e. injection of
external electric current at zero temperature. Current-voltage curves at
various strength of the anisotropy exhibit universal scaling features around
the jamming point much as do the flow curves in granular rheology, shear-stress
vs shear-rate. It turns out that at zero temperature the jamming transition
occurs right at the isotropic coupling and anisotropic JJA behaves as an exotic
fragile vortex matter : it behaves as superconductor (vortex glass) into one
direction while normal conductor (vortex liquid) into the other direction even
at zero temperature. Furthermore we find a variant of the theoretical model for
the anisotropic JJA quantitatively reproduces universal master flow-curves of
the granular systems. Our results suggest an unexpected common paradigm
stretching over seemingly unrelated fields - the rheology of soft materials and
superconductivity.Comment: 10 pages, 5 figures. To appear in New Journal of Physic
Describing and prescribing the constitutive response of yield stress fluids using large amplitude oscillatory shear stress (LAOStress)
Large amplitude oscillatory shear (LAOS) is used as a tool to probe the nonlinear rheological response of a model elasto-viscoplastic material (a Carbopol microgel). In contrast to most recent studies, these large amplitude measurements are carried out in a stress-controlled manner. We outline a descriptive framework of characterization measures for nonlinear rheology under stress-controlled LAOS, and this is contrasted experimentally to the strain-controlled framework that is more commonly used. We show that this stress-controlled methodology allows for a physically intuitive interpretation of the yielding behavior of elasto-viscoplastic materials. The insight gained into the material behavior through these nonlinear measures is then used to develop two constitutive models that prescribe the rheological response of the Carbopol microgel. We show that these two successively more sophisticated constitutive models, which are based on the idea of strain decomposition, capture in a compact manner the important features of the nonlinear rheology of the microgel. The second constitutive model, which incorporates the concept of kinematic hardening, embodies all of the essential behaviors exhibited by Carbopol. These include elasto-viscoplastic creep and time-dependent viscosity plateaus below a critical stress, a viscosity bifurcation at the critical stress, and HerschelâBulkley flow behavior at large stresses
Controllable adhesion using field-activated fluids
We demonstrate that field-responsive magnetorheological fluids can be used for variable-strength controllable adhesion. The adhesive performance is measured experimentally in tensile tests (a.k.a. probe-tack experiments) in which the magnetic field is provided by a cylindrical permanent magnet. Increasing the magnetic field strength induces higher peak adhesive forces. We hypothesize that the adhesion mechanism arises from the shear resistance of a yield stress fluid in a thin gap. This hypothesis is supported by comparing the experimentally measured adhesive performance to the response predicted by a lubrication model for a non-Newtonian fluid with a field-dependent yield stress. The model predictions are in agreement with experimental data up to moderate field strengths. Above a critical magnetic field strength the model over-predicts the experimentally measured values indicating non-ideal conditions such as local fluid dewetting from the surface.U.S. Army Research Laboratory (United States. Army Research Office Contract/Grant W911NF-08-C-0055
A fractional K-BKZ constitutive formulation for describing the nonlinear rheology of multiscale complex fluids
The relaxation processes of a wide variety of soft materials frequently contain one or more broad regions of power-law like or stretched exponential relaxation in time and frequency. Fractional constitutive equations have been shown to be excellent models for capturing the linear viscoelastic behavior of such materials, and their relaxation modulus can be quantitatively described very generally in terms of a MittagâLeffler function. However, these fractional constitutive models cannot describe the nonlinear behavior of such power-law materials. We use the example of Xanthan gum to show how predictions of nonlinear viscometric properties, such as shear-thinning in the viscosity and in the first normal stress coefficient, can be quantitatively described in terms a nonlinear fractional constitutive model. We adopt an integral K-BKZ framework and suitably modify it for power-law materials exhibiting MittagâLeffler type relaxation dynamics at small strains. Only one additional parameter is needed to predict nonlinear rheology, which is introduced through an experimentally measured damping function. Empirical rules such as the CoxâMerz rule and Gleissle mirror relations are frequently used to estimate the nonlinear response of complex fluids from linear rheological data. We use the fractional model framework to assess the performance of such heuristic rules and quantify the systematic offsets, or shift factors, that can be observed between experimental data and the predicted nonlinear response. We also demonstrate how an appropriate choice of fractional constitutive model and damping function results in a nonlinear viscoelastic constitutive model that predicts a flow curve identical to the elastic Herschel-Bulkley model. This new constitutive equation satisfies the Rutgers-Delaware rule, which is appropriate for yielding materials. This K-BKZ framework can be used to generate canonical three-element mechanical models that provide nonlinear viscoelastic generalizations of other empirical inelastic models such as the Cross model. In addition to describing nonlinear viscometric responses, we are also able to provide accurate expressions for the linear viscoelastic behavior of complex materials that exhibit strongly shear-thinning Cross-type or Carreau-type flow curves. The findings in this work provide a coherent and quantitative way of translating between the linear and nonlinear rheology of multiscale materials, using a constitutive modeling approach that involves only a few material parameters
The Physics of the Colloidal Glass Transition
As one increases the concentration of a colloidal suspension, the system
exhibits a dramatic increase in viscosity. Structurally, the system resembles a
liquid, yet motions within the suspension are slow enough that it can be
considered essentially frozen. This kinetic arrest is the colloidal glass
transition. For several decades, colloids have served as a valuable model
system for understanding the glass transition in molecular systems. The spatial
and temporal scales involved allow these systems to be studied by a wide
variety of experimental techniques. The focus of this review is the current
state of understanding of the colloidal glass transition. A brief introduction
is given to important experimental techniques used to study the glass
transition in colloids. We describe features of colloidal systems near and in
glassy states, including tremendous increases in viscosity and relaxation
times, dynamical heterogeneity, and ageing, among others. We also compare and
contrast the glass transition in colloids to that in molecular liquids. Other
glassy systems are briefly discussed, as well as recently developed synthesis
techniques that will keep these systems rich with interesting physics for years
to come.Comment: 56 pages, 18 figures, Revie
A Rheometry Method to Assess The Evaporation-Induced Mechanical Strength Development of Polymer Solutions Used For Membrane Applications
Rotational and oscillatory shear rheometry were used to quantify the flow behavior under minimal and significant solvent evaporation conditions for polymer solutions used to fabricate isoporous asymmetric membranes by the self-assembly and non-solvent induced phase separation (SNIPS) method. Three different A-B-C triblock terpolymer chemistries of similar molar mass were evaluated: polyisoprene-^-polystyrene-6-poly(4-vinylpyridine) (ISV); polyisoprene-6- polystyrene-6-poly(V,A-dimethylacrylamide) (ISD); and polyisoprene-Z\u3e-polystyrene-h-poly(fer/- butyl methacrylate) (ISB). Solvent evaporation resulted in the formation of a viscoelastic film typical of asymmetric membranes. Solution viscosity and film viscoelasticity were strongly dependent on the chemical structure of the triblock terpolymer molecules. A hierarchical magnitude (ISV\u3eISB\u3eISD) was observed for both properties, with ISV solutions displaying the greatest solution viscosity, fastest film strength development, and greatest strength magnitude
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