"Single-cycle" ionization effects in laser-matter interaction

We investigate numerically effects related to ``single-cycle'' ionization of dense matter by an ultra-short laser pulse. The strongly non-adiabatic response of electrons leads to generation of a megagauss steady magnetic field in laser-solid interaction. By using two-beam interference, it is possible to create periodic density structures able to trap light and to generate relativistic ionization frontsComment: 12 pages, 6 figures, to be published in Laser and Particle Beam

CAESAR: SEWGS integration into an IGCC plant

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THERMODYNAMIC ORC CYCLE DESIGN OPTIMIZATION FOR MEDIUM-LOW TEMPERATURE ENERGY SOURCES

In the large spectrum of organic fluids suitable for Rankine cycles, a fluid that is already wellknown and available on industrial scale but currently excluded from this kind of application has been selected. This choice is due to the remarkable characteristics of the fluid, such as its high molecular weight, good thermal stability, non-flammability, and atoxicity. Compared to those fluids nowadays common in the ORC market, its thermodynamic properties and fluid dynamic behavior lead to a peculiar configuration of the cycle: • Supercritical cycle, when heat input is at medium-high temperature; • Massive regeneration, to obtain higher efficiency; • Low specific work of the turbine; • Relatively high volumetric expansion ratio and relatively low absolute inlet volumetric flow; Accordingly, an innovative cycle design has been developed, including a once-through Hairpin primary heat exchanger and a multi-stage radial outflow expander. This last innovative component has been designed to get the best performance with the chosen fluid: • The high inlet/outlet volumetric flow ratio is well combined with the change in cross section across the radius; • Compared to an axial turbine, the lower inlet volumetric flow is compensated by higher blades at the first stage. It is feasible thanks to the change in section available along the radius, so that there is no need for partial admission; • The prismatic blade leads to constant velocity diagrams across the blade span; • It minimizes tip leakages and disk friction losses, due to the single disk / multi-stage configuration; • The intrinsical limit of a radial outflow expander to develop high enthalpy drop is not relevant for this cycle, presenting itself a very low enthalpy drop. Moreover the tip speed is limited by the low speed of sound and consequently this kind of expander suits well with this cycle arrangement. The results of this study, conducted through thermodynamic simulations, CFD, stress analysis and economic optimization show an ORC system that reaches high efficiencies, comparable to those typical of existing system

CAPSULAR DEVICES FOR ORAL MODIFIED RELEASE OF DRUGS PREPARED BY INJECTION MOLDING

The research project was focused on the development of a pulsatile capsular-shaped drug delivery system (DDS) named Chronocap\u2122. It consists of a capsule shell, made of hydroxypropyl cellulose (HPC), prepared by injection molding (IM); it is intended to be filled with different types of drug preparations and to delay their liberation after oral administration. Such devices prepared by means of a prototype mold were demonstrated able to convey drug preparations giving rise to the expected pulsatile release performance, confirmed by in vivo data. The PhD project was undertaken aiming at improving the robustness and versatility of the Chronocap\u2122 device as well as enhancing the industrial scalability of its manufacturing process. For this purpose, two different tasks were pointed out: the improvement of the manufacturing process and of the technological characteristics of capsules on the one side, and the upgrade of applications of the device on the other. In this respect, the modulation of the lag phase of the capsular device and its possible exploitation in the design of a colon DDS were approached

Application of Hydrogen Selective Membranes to IGCC

AbstractThis study considers the integration of Pd-based H2-selective membranes in integrated gasifier combined cycles (IGCC) from both technical and economical point of view. The selected gasification system is based on Shell technology. Two different dry feeding systems are investigated: the first is a state-of-the- art nitrogen-based lock hopper charger while the second uses CO2 as pressurization gas. The net electric efficiency of the two plants is evaluated as a function of the hydrogen recovery factor (HRF) and the membrane feed pressure in order to minimize the membrane surface area. 90% HRF and 54bar feed pressure are the best operating parameters which correspond to a net electric efficiency of 39% both for N2 and CO2 feeding system. The cost of CO2 avoided is calculated as a function of a parameter named MI which represents the membrane development in terms of performances and costs. Results show that an improvement of membrane technology is necessary to match the state-of-the-art CO2 capture plant, even though membranes show good potentiality for cost abatement

Economic and environmental impact assessment through system dynamics of technology-enhanced maintenance services

This work presents an economic and environmental impact assessment of maintenance services in order to evaluate how they contribute to sustainable value creation through field service delivery supported by advanced technologies. To this end, systems dynamics is used to assist the prediction of economic and environmental impacts of maintenance services supported by the use of an e-maintenance platform implementing prognosis and health management. A special concern is given to the energy use and related carbon footprint as environmental impacts

Mean-Field Interacting Boson Random Point Fields in Weak Harmonic Traps

A model of the mean-field interacting boson gas trapped by a weak harmonic potential is considered by the \textit{boson random point fields} methods. We prove that in the Weak Harmonic Trap (WHT) limit there are two phases distinguished by the boson condensation and by a different behaviour of the local particle density. For chemical potentials less than a certain critical value, the resulting Random Point Field (RPF) coincides with the usual boson RPF, which corresponds to a non-interacting (ideal) boson gas. For the chemical potentials greater than the critical value, the boson RPF describes a divergent (local) density, which is due to \textit{localization} of the macroscopic number of condensed particles. Notice that it is this kind of transition that observed in experiments producing the Bose-Einstein Condensation in traps

The design of CO2-based working fluids for high-temperature heat source power cycles

The application of CO2power cycles is advantageous to exploit high-temperature sources (500-800°C) in the case of available low-temperature heat sinks (15-25°C). However, their efficiency is strongly reduced for higher heat sink temperatures. At these temperatures, due to the low-critical temperature of CO2(about 31°C), CO2is in fact compressed in the supercritical vapor phase rather than in the liquid phase, thus increasing energetic demand for compression. One of the solutions envisaged to overcome this problem is the addition of one or more chemicals that allow having a mixture with a higher critical temperature than the one of pure CO2. This preserve the working fluid compression in its liquid phase, even in the case of heat sinks with temperatures greater than 25°C. This research shows that the addition to CO2of a properly selected chemical component enables to increase the critical temperature up to 45°C with relevant improvements of cycle efficiency with respect to pure-CO2power cycles. In particular, it summarizes the most relevant criteria to be accounted for when selecting CO2-additives. Moreover, the paper warns of the thermodynamic effects deriving from adding to CO2a second characterized by a much more high critical temperature, such as the occurrence of infinite-pressure critical points and multiple-phase liquid-liquid and vapor-liquid critical points. Finally, the paper analyses the thermodynamic properties of a high-critical temperature CO2-based mixture, suitable for these applications, that presents multiple phase critical points. In this regard, it is specified that the paper also aims at filling a knowledge gap in the study of thermodynamic properties of mixtures presenting how do enthalpy and specific volume change in response to pressure variations in the event of liquid-liquid and vapour-liquid critical points. Finally, we present the comparison between performances of power cycles which use, as working fluid, either pure CO2or the novel designed higher temperature CO2-based mixture