2 research outputs found
Application of the Metal–Organic Framework [Eu(BTC)] as a Luminescent Marker for Gunshot Residues: A Synthesis, Characterization, and Toxicity Study
The
3D metal–organic framework (MOF) [Eu(BTC)] (where BTC
= trimesic acid) was synthesized in 20 min by a microwave-assisted
hydrothermal method with a yield of 89%. A structural and spectroscopic
study, performed by X-ray diffraction, thermogravimetry, and photoluminescence
spectroscopy, showed that this framework has high crystallinity, thermal
stability, and luminescence. This MOF had a red-orange luminescence
when excited with ultraviolet (UV) radiation (λ = 254 nm) and
a high potential for use as a luminescent marker for gunshot residues
(GSR). When added to 9 mm nontoxic ammunition, it greatly improved
quality of the crime scene investigation, allowing for direct visualization
of the luminescent GSR on the shooter’s hand and firearm and
at the firing range using only a portable UV lamp. The marked luminescent
GSR was easily collected and characterized by nondestructive techniques,
including with a Video Spectral Comparator and scanning electron microscopy/energy-dispersive
spectroscopy, wherein the presence of Eu<sup>3+</sup> ions was confirmed.
Furthermore, the oral acute toxicity of this MOF was assessed in adult
female Wistar rats using the Organisation for Economic Cooperation
and Development 423 guidelines. This study classified the MOF [Eu(BTC)]
in a less toxic Globally Harmonized System category (category 5),
with a LD<sub>50</sub> (lethal dose) of 5000 mg/kg, ensuring a wide
security range for its application
Inkjet Printing of Lanthanide–Organic Frameworks for Anti-Counterfeiting Applications
Photoluminescent lanthanide–organic
frameworks (Ln-MOFs)
were printed onto plastic and paper foils with a conventional inkjet
printer. Ln-MOF inks were used to reproduce color images that can
only be observed under UV light irradiation. This approach opens a
new window for exploring Ln-MOF materials in technological applications,
such as optical devices (e.g., lab-on-a-chip), as proof of authenticity
for official documents