Study of corrosion of 1100 aluminum

Corrosion of 1100 aluminum in oxygen-saturated water at 70 degrees C under experimental conditions was studied, emphasizing effects of exposure interruption, the number of specimens, and the refreshment rate. A logarithmic equation was derived to express the corrosion rate

Study of crevice-galvanic corrosion of aluminum

Corrosion effects of aluminum-copper and aluminum-nickel couples in oxygenated distilled water, and aluminum alloys in oxygenated copper sulfate solution were studied. One of each of the couples had a water tight seal, and showed no substantial corrosion, and of the unsealed couples, only the aluminum-copper developed corrosion

The planar spectrum in U(N)-invariant quantum mechanics by Fock space methods: I. The bosonic case

Prompted by recent results on Susy-U(N)-invariant quantum mechanics in the large N limit by Veneziano and Wosiek, we have examined the planar spectrum in the full Hilbert space of U(N)-invariant states built on the Fock vacuum by applying any U(N)-invariant combinations of creation-operators. We present results about 1) the supersymmetric model in the bosonic sector, 2) the standard quartic Hamiltonian. This latter is useful to check our techniques against the exact result of Brezin et al. The SuSy case is where Fock space methods prove to be the most efficient: it turns out that the problem is separable and the exact planar spectrum can be expressed in terms of the single-trace spectrum. In the case of the anharmonic oscillator, on the other hand, the Fock space analysis is quite cumbersome due to the presence of large off-diagonal O(N) terms coupling subspaces with different number of traces; these terms should be absorbed before taking the planar limit and recovering the known planar spectrum. We give analytical and numerical evidence that good qualitative information on the spectrum can be obtained this way.Comment: 17 pages, 4 figures, uses youngtab.sty. Final versio

A general framework for online audio source separation

We consider the problem of online audio source separation. Existing algorithms adopt either a sliding block approach or a stochastic gradient approach, which is faster but less accurate. Also, they rely either on spatial cues or on spectral cues and cannot separate certain mixtures. In this paper, we design a general online audio source separation framework that combines both approaches and both types of cues. The model parameters are estimated in the Maximum Likelihood (ML) sense using a Generalised Expectation Maximisation (GEM) algorithm with multiplicative updates. The separation performance is evaluated as a function of the block size and the step size and compared to that of an offline algorithm.Comment: International conference on Latente Variable Analysis and Signal Separation (2012

Nonlinear evolution of the plasma beatwave: Compressing the laser beatnotes via electromagnetic cascading

The near-resonant beatwave excitation of an electron plasma wave (EPW) can be employed for generating the trains of few-femtosecond electromagnetic (EM) pulses in rarefied plasmas. The EPW produces a co-moving index grating that induces a laser phase modulation at the difference frequency. The bandwidth of the phase-modulated laser is proportional to the product of the plasma length, laser wavelength, and amplitude of the electron density perturbation. The laser spectrum is composed of a cascade of red and blue sidebands shifted by integer multiples of the beat frequency. When the beat frequency is lower than the electron plasma frequency, the red-shifted spectral components are advanced in time with respect to the blue-shifted ones near the center of each laser beatnote. The group velocity dispersion of plasma compresses so chirped beatnotes to a few-laser-cycle duration thus creating a train of sharp EM spikes with the beat periodicity. Depending on the plasma and laser parameters, chirping and compression can be implemented either concurrently in the same, or sequentially in different plasmas. Evolution of the laser beatwave end electron density perturbations is described in time and one spatial dimension in a weakly relativistic approximation. Using the compression effect, we demonstrate that the relativistic bi-stability regime of the EPW excitation [G. Shvets, Phys. Rev. Lett. 93, 195004 (2004)] can be achieved with the initially sub-threshold beatwave pulse.Comment: 13 pages, 11 figures, submitted to Physical Review

Multi-Orbital Molecular Compound (TTM-TTP)I_3: Effective Model and Fragment Decomposition

The electronic structure of the molecular compound (TTM-TTP)I_3, which exhibits a peculiar intra-molecular charge ordering, has been studied using multi-configuration ab initio calculations. First we derive an effective Hubbard-type model based on the molecular orbitals (MOs) of TTM-TTP; we set up a two-orbital Hamiltonian for the two MOs near the Fermi energy and determine its full parameters: the transfer integrals, the Coulomb and exchange interactions. The tight-binding band structure obtained from these transfer integrals is consistent with the result of the direct band calculation based on density functional theory. Then, by decomposing the frontier MOs into two parts, i.e., fragments, we find that the stacked TTM-TTP molecules can be described by a two-leg ladder model, while the inter-fragment Coulomb energies are scaled to the inverse of their distances. This result indicates that the fragment picture that we proposed earlier [M.-L. Bonnet et al.: J. Chem. Phys. 132 (2010) 214705] successfully describes the low-energy properties of this compound.Comment: 5 pages, 4 figures, published versio

Chandra Observations of the Northeastern Rim of the Cygnus Loop

We present results from spatially resolved spectral analyses of the northeastern (NE) rim of the Cygnus Loop supernova remnant (SNR) based on two Chandra observations. One pointing includes northern outermost abundance-enhanced regions discovered by recent Suzaku observations, while the other pointing is located on regions with "normal" abundances in the NE rim of the Cygnus Loop. The superior spatial resolving power of Chandra allows us to reveal that the abundance-enhanced region is concentrated in an about 200"-thickness region behind the shock front. We confirm absolute metal abundances (i.e., relative to H) as well as abundance ratios between metals are consistent with those of the solar values within a factor of about 2. Also, we find that the emission measure in the region gradually decreases toward the shock front. These features are in contrast with those of the ejecta fragments around the Vela SNR, which leads us to believe that the abundance enhancements are not likely due to metal-rich ejecta. We suggest that the origin of the plasma in this region is the interstellar medium (ISM). In the "normal" abundance regions, we confirm that abundances are depleted to the solar values by a factor of about 5 that is not expected in the ISM around the Cygnus Loop. Introduction of non-thermal emission in our model fitting can not naturally resolve the abundance-depletion problem. The origin of the depletion still remains as an open question.Comment: 18 pages, 6 figure

Frustrated Spin System in theta-(BEDT-TTF)_2RbZn(SCN)_4

The origin of the spin gap behavior in the low-temperature dimerized phase of theta-(BEDT-TTF)_2RbZn(SCN)_4 has been theoretically studied based on the Hartree-Fock approximation for the on-site Coulomb interaction at absolute zero. Calculations show that, in the parameter region considered to be relevant to this compound, antiferromagnetic ordering is stabilized between dimers consisting of pairs of molecules coupled with the largest transfer integral. Based on this result an effective localized spin 1/2 model is constructed which indicates the existence of the frustration among spins. This frustration may result in the formation of spin gap.Comment: 4 pages, 5 figures, to be published in J. Phys. Soc. Jpn. 67 (1998) no.

Universal scaling behavior at the upper critical dimension of non-equilibrium continuous phase transitions

In this work we analyze the universal scaling functions and the critical exponents at the upper critical dimension of a continuous phase transition. The consideration of the universal scaling behavior yields a decisive check of the value of the upper critical dimension. We apply our method to a non-equilibrium continuous phase transition. But focusing on the equation of state of the phase transition it is easy to extend our analysis to all equilibrium and non-equilibrium phase transitions observed numerically or experimentally.Comment: 4 pages, 3 figure