Moisture effects on the bending fatigue of laminated composites

This paper investigated the effect of moisture ingress on the bending fatigue of laminated composites. An accelerated testing method was developed to investigate the correlation between composite fatigue and moisture diffusion effects. Unidirectional and cross-ply laminated CFRP composites were manufactured in autoclave, and then submerged in both fresh and seawater for various periods until moisture saturation. Quasi-static and cyclic tests were carried out in both air and wet environment, and the failure mechanisms were investigated using visual and microscopic methods. Additionally, a robust 2D Finite Element model (FEA) was developed to simulate the fatigue crack propagation based on virtual crack closure technique (VCCT), while a 3D FEA model was developed to investigate the edge effect on fatigue crack propagation. The experimental observations gave a good agreement with the FEA models. The study showed that the bending fatigue failure was due to the so-called buckling-driven delamination, and the fatigue life was reduced significantly owing to the combination of edge effect and capillary effect. The fatigue test indicated that the fatigue resistance was degraded one stress level due to the water ingress, e.g. from 80% ultimate flexural strength (UFS) to 65% UFS. Therefore, a 4-step fatigue failure theory was proposed to explain the moisture effects on the crack propagation under bending fatigue

Use of a porous membrane for gas bubble removal in microfluidic channels: physical mechanisms and design criteria

We demonstrate and explain a simple and efficient way to remove gas bubbles from liquid-filled microchannels, by integrating a hydrophobic porous membrane on top of the microchannel. A prototype chip is manufactured in hard, transparent polymer with the ability to completely filter gas plugs out of a segmented flow at rates up to 7.4 microliter/s per mm2 of membrane area. The device involves a bubble generation section and a gas removal section. In the bubble generation section, a T-junction is used to generate a train of gas plugs into a water stream. These gas plugs are then transported towards the gas removal section, where they slide along a hydrophobic membrane until complete removal. The system has been successfully modeled and four necessary operating criteria have been determined to achieve a complete separation of the gas from the liquid. The first criterion is that the bubble length needs to be larger than the channel diameter. The second criterion is that the gas plug should stay on the membrane for a time sufficient to transport all the gas through the membrane. The third criterion is that the gas plug travel speed should be lower than a critical value: otherwise a stable liquid film between the bubble and the membrane prevents mass transfer. The fourth criterion is that the pressure difference across the membrane should not be larger than the Laplace pressure to prevent water from leaking through the membrane

Giant energy storage density in PVDF with internal stress engineered polar nanostructures

High power dielectric capacitors with high energy density are needed in order to develop modern electronic and electrical systems, including hybrid vehicles, telecommunication infrastructures and portable electronic devices. Relaxor ferroelectric polymers (RFP) are considered to be the most promising candidates for the next generation of capacitors owing to their relatively high energy storage density. However, the commercialization of RFP capacitors in power systems is hindered by their high cost and low dielectric breakdown strength. In this study, inexpensive, free-standing nano-crystalline (~3.3 nm) poly (vinylidene fluoride) (PVDF) films with high β phase content (~98%), “relaxor-like” ferroelectric behaviour and high breakdown strength (880 kV/mm) were fabricated using the facile Press & Folding (P&F) technique. An internal stress dominated polarization switching model is proposed to explain the origin of the relaxor-like ferroelectric behaviour. The internal stress generated during pressing alters the intermolecular chain distance of the (200) plane of β-PVDF from 4.24 Å in internal stress free films to 4.54 Å in P&F films, corresponding to a tensile strain and residual stress of 7.11% and 142 MPa, respectively. The internal stress acts to partially reverse the polarization on reversal of the applied electric field. This, combined with preferred in-plane orientation of the crystallites, results in a polar nanostructure with high polarization reversibility at high electric fields. A giant discharged energy storage density of 39.8 J/cm3 at 880 kV/mm was achieved for P&F films, which surpasses all previously reported polymer-based materials

Second best toll and capacity optimisation in network: solution algorithm and policy implications

This paper looks at the first and second-best jointly optimal toll and road capacity investment problems from both policy and technical oriented perspectives. On the technical side, the paper investigates the applicability of the constraint cutting algorithm for solving the second-best problem under elastic demand which is formulated as a bilevel programming problem. The approach is shown to perform well despite several problems encountered by our previous work in Shepherd and Sumalee (2004). The paper then applies the algorithm to a small sized network to investigate the policy implications of the first and second-best cases. This policy analysis demonstrates that the joint first best structure is to invest in the most direct routes while reducing capacities elsewhere. Whilst unrealistic this acts as a useful benchmark. The results also show that certain second best policies can achieve a high proportion of the first best benefits while in general generating a revenue surplus. We also show that unless costs of capacity are known to be low then second best tolls will be affected and so should be analysed in conjunction with investments in the network

Nanoscale interfacial electroactivity in PVDF/PVDF-TrFE blended films with enhanced dielectric and ferroelectric properties

The existing interactions substantially affect the structure of PVDF/PVDF-TrFE blends as well as their electric properties.</p

Moisture effects on the bending fatigue of laminated composites

This paper investigated the effect of moisture ingress on the bending fatigue of laminated composites. An accelerated testing method was developed to investigate the correlation between composite fatigue and moisture diffusion effects. Unidirectional and cross-ply laminated CFRP composites were manufactured in autoclave, and then submerged in both fresh and seawater for various periods until moisture saturation. Quasi-static and cyclic tests were carried out in both air and wet environment, and the failure mechanisms were investigated using visual and microscopic methods. Additionally, a robust 2D Finite Element model (FEA) was developed to simulate the fatigue crack propagation based on virtual crack closure technique (VCCT), while a 3D FEA model was developed to investigate the edge effect on fatigue crack propagation. The experimental observations gave a good agreement with the FEA models. The study showed that the bending fatigue failure was due to the so-called buckling-driven delamination, and the fatigue life was reduced significantly owing to the combination of edge effect and capillary effect. The fatigue test indicated that the fatigue resistance was degraded one stress level due to the water ingress, e.g. from 80% ultimate flexural strength (UFS) to 65% UFS. Therefore, a 4-step fatigue failure theory was proposed to explain the moisture effects on the crack propagation under bending fatigue

Structural and functional characterization of Pseudomonas aeruginosa CupB chaperones

Pseudomonas aeruginosa, an important human pathogen, is estimated to be responsible for,10% of nosocomial infections worldwide. The pathogenesis of P. aeruginosa starts from its colonization in the damaged tissue or medical devices (e. g. catheters, prothesis and implanted heart valve etc.) facilitated by several extracellular adhesive factors including fimbrial pili. Several clusters containing fimbrial genes have been previously identified on the P. aeruginosa chromosome and named cup [1]. The assembly of the CupB pili is thought to be coordinated by two chaperones, CupB2 and CupB4. However, due to the lack of structural and biochemical data, their chaperone activities remain speculative. In this study, we report the 2.5 A crystal structure of P. aeruginosa CupB2. Based on the structure, we further tested the binding specificity of CupB2 and CupB4 towards CupB1 (the presumed major pilus subunit) and CupB6 (the putative adhesin) using limited trypsin digestion and strep-tactin pull-down assay. The structural and biochemical data suggest that CupB2 and CupB4 might play different, but not redundant, roles in CupB secretion. CupB2 is likely to be the chaperone of CupB1, and CupB4 could be the chaperone of CupB4:CupB5:CupB6, in which the interaction of CupB4 and CupB6 might be mediated via CupB5

Crystallization kinetics and enhanced dielectric properties of free standing lead-free PVDF based composite films

Ferroelectric composites, integrating dielectric ceramic fillers with mechanically flexible polymers, are promising materials for flexible electronic applications. Plenty of research has demonstrated the enhanced dielectric and ferroelectric properties of composite materials. However, the mechanisms responsible for these enhancements are not completely understood. Herein, we used typical dielectric materials, poly(vinylidene fluoride) (PVDF) and BaTiO3 (BTO), to study the effect of a dielectric filler on the crystallization, phase transformation and dielectric properties of PVDF. The crystallization of β-PVDF was not affected by the presence of BTO particles, but small amounts of BTO (<3 vol %) made PVDF crystallize into larger spherulites. This is linked to crystallization kinetic studies, which showed that BTO acted as a nucleation agent for large full ring banded spherulites when its content was less than 1 vol %. Furthermore, solid state drawing in the presence of BTO particles promoted the formation of β-PVDF with more pronounced preferred crystalline orientation at high drawing temperatures (120 °C). The dielectric and ferroelectric properties were enhanced with BTO filling. The 100 °C oriented drawn PVDF tape exhibited a dielectric permittivity of 14 (100 Hz) and remnant polarization of 0.080 C/m2 (10 Hz), which increased to 23 and 0.095 C/m2, respectively, after filling with 5 vol % BTO; neither resulting in high dielectric loss tangent (∼0.02) nor obvious current leakage. Moreover, the coercive field decreased from 80 to 50 kV/mm with increasing BTO content from 0 to 5 vol %