1,178 research outputs found

    A study of the nanostructure and hardness of electron beam evaporated TiAlBN coatings

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    TiAlBN coatings have been deposited by electron beam (EB) evaporation from a single TiAlBN material source onto AISI 316 stainless steel substrates at a temperature of 450 °C and substrate bias of − 100 V. The stoichiometry and nanostructure have been studied by X-ray photoelectron spectroscopy, X-ray diffraction and transmission electron microscopy. The hardness and elastic modulus were determined by nanoindentation. Five coatings have been deposited, three from hot-pressed TiAlBN material and two from hot isostatically pressed (HIPped) material. The coatings deposited from the hot-pressed material exhibited a nanocomposite nc-(Ti,Al)N/a-BN/a-(Ti,Al)B2 structure, the relative phase fraction being consistent with that predicted by the equilibrium Ti–B–N phase diagram. Nanoindentation hardness values were in the range of 22 to 32 GPa. Using the HIPped material, coating (Ti,Al)B0.29N0.46 was found to have a phase composition of 72–79 mol.% nc-(Ti,Al)(N,B)1 − x+ 21–28 mol.% amorphous titanium boride and a hardness of 32 GPa. The second coating, (Ti,Al)B0.66N0.25, was X-ray amorphous with a nitride+boride multiphase composition and a hardness of 26 GPa. The nanostructure and structure–property relationships of all coatings are discussed in detail. Comparisons are made between the single-EB coatings deposited in this work and previously deposited twin-EB coatings. Twin-EB deposition gives rise to lower adatom mobilities, leading to (111) (Ti,Al)N preferential orientation, smaller grain sizes, less dense coatings and lower hardnesses

    Collective dynamics of internal states in a Bose gas

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    Theory for the Rabi and internal Josephson effects in an interacting Bose gas in the cold collision regime is presented. By using microscopic transport equation for the density matrix the problem is mapped onto a problem of precession of two coupled classical spins. In the absence of an external excitation field our results agree with the theory for the density induced frequency shifts in atomic clocks. In the presence of the external field, the internal Josephson effect takes place in a condensed Bose gas as well as in a non-condensed gas. The crossover from Rabi oscillations to the Josephson oscillations as a function of interaction strength is studied in detail.Comment: 18 pages, 2 figure

    An epitaxial model for heterogeneous nucleation on potent substrates

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    © The Minerals, Metals & Materials Society and ASM International 2012In this article, we present an epitaxial model for heterogeneous nucleation on potent substrates. It is proposed that heterogeneous nucleation of the solid phase (S) on a potent substrate (N) occurs by epitaxial growth of a pseudomorphic solid (PS) layer on the substrate surface under a critical undercooling (ΔT ). The PS layer with a coherent PS/N interface mimics the atomic arrangement of the substrate, giving rise to a linear increase of misfit strain energy with layer thickness. At a critical thickness (h ), elastic strain energy reaches a critical level, at which point, misfit dislocations are created to release the elastic strain energy in the PS layer. This converts the strained PS layer to a strainless solid (S), and changes the initial coherent PS/N interface into a semicoherent S/N interface. Beyond this critical thickness, further growth will be strainless, and solidification enters the growth stage. It is shown analytically that the lattice misfit (f) between the solid and the substrate has a strong influence on both h and ΔT ; h decreases; and ΔT increases with increasing lattice misfit. This epitaxial nucleation model will be used to explain qualitatively the generally accepted experimental findings on grain refinement in the literature and to analyze the general approaches to effective grain refinement.EPSRC Centre for Innovative Manufacturing in Liquid Metal Engineerin

    No V-Fe-Zn isotopic variation in basalts from the 2021 Fagradalsfjall eruption

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    The Earth’s mantle is chemically heterogeneous in space and time, which is often reflected by variable isotopic compositions of mantle derived basalts. Basalts from the first 40 days of the 2021 Fagradalsfjall eruption, Reykjanes Peninsula, Iceland, display systematic temporal variations in the ratios of incompatible elements alongside resolvable variations in Sr, Nd and Pb radiogenic isotopes. These variations reflect progressive influx of magma derived from melting of a deeper, more enriched and potentially lithologically distinct source. We use this eruptive time series to conduct the first combined V-Fe-Zn isotope study, exploring the sensitivity of the combined isotopic approach, with particular focus on fingerprinting source lithological heterogeneity. We find no analytically resolvable change in V (δ51VAA between −0.95 ± 0.09 ‰ 2 s.d. and −0.86 ± 0.07 ‰ 2 s.d.), Fe (δ56FeIRMM-524 between +0.047 ± 0.042 ‰ 2 s.d. and +0.094 ± 0.049 ‰ 2 s.d.) and Zn (δ66ZnAA-ETH between −0.042 ± 0.003 ‰ 2 s.d. and +0.013 ± 0.027 ‰ 2 s.d.) isotopic compositions. The lack of variability in V-Fe-Zn isotopes, despite the evolving trace element and radiogenic isotope ratios, suggests there is no significant contribution of melts from a lithologically distinct (pyroxenite) mantle component under the Reykjanes Peninsula

    Measurement of Stresses in Fixed-Bridge Restorations Using a Brittle Coating Technique

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    Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/67230/2/10.1177_00220345650440042201.pd

    Elastic Scattering of Pions From the Three-nucleon System

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    We examine the scattering of charged pions from the trinucleon system at a pion energy of 180 MeV. The motivation for this study is the structure seen in the experimental angular distribution of back-angle scattering for pi+ 3He and pi- 3H but for neither pi- 3He nor pi+ 3H. We consider the addition of a double spin flip term to an optical model treatment and find that, though the contribution of this term is non-negligible at large angles for pi+ 3He and pi- 3H, it does not reproduce the structure seen in the experiment.Comment: 15 pages + 5 figure

    Moment of Inertia and Quadrupole Response Function of a Trapped Superfluid

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    We derive an explicit relationship between the moment of inertia and the quadrupole response function of an interacting gas confined in a harmonic trap. The relationship holds for both Bose and Fermi systems and is well suited to reveal the effects of irrotationality of the superfluid motion. Recent experimental results on the scissors mode are used to extract the value of the moment of inertia of a trapped Bose gas and to point out the deviations from the rigid value due to superfluidity.Comment: 6 page

    Experimental analysis of gas to water two phase closed thermosyphon based heat exchanger

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    Paper presented to the 10th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Florida, 14-16 July 2014.Wickless heat pipes have been attracting increased attention in the last two decades due to their reliability and high heat transfer potential per unit area. Their most common application is in the process industry, when coupled to waste heat recovery devices. Heat pipe based heat exchangers offer many advantages when compared with conventional waste heat recovery systems; advantages that are detailed in the current work. The design of such devices, however, is not a straightforward process due to the complex modes of heat transfer mechanisms involved. In this paper, the characterisation of a cross-flow heat pipe based heat exchanger is studied experimentally, using correlations currently available in literature. A design tool with the purpose of predicting the performance of the test unit was also developed and validated through comparison with the experimental results. The design tool was validated with the use of a purpose-built experimental facility.cf201
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