Rhenium(I)-based Double-heterostranded Helicates

Rhenium(I)-based supramolecular coordination complexes were obtained using Re2(CO)10, (2-hydroxyphenyl)benzimidazole-derived bis-chelating N?O donors and a benzimidazolyl-derived ditopic monodentate N-donor possessing Troger's base spacer in a one-pot approach

Furan-decorated neutral Re(I)-based 2D rectangle and 3D trigonal prism

Neutral, stable and luminescent metallacycles decorated with furan units, a 2D rectangle with four furans and a 3D trigonal prism with six furans, were synthesized from readily accessible starting materials through a fac- Re(CO)3-directed approach

4,4′-Bipyridine–3-(thio­phen-3-yl)acrylic acid (1/2)

In the title 1/2 adduct, C10H8N2·2C7H6O2S, the dihedral angle between the pyridine rings is 18.41 (11)°. In the thio­phene­acrylic acid mol­ecules, the dihedral angles between the respective thio­phene and acrylic acid units are 5.52 (17)° and 23.92 (9)°. In the crystal, the components are linked via O—H⋯N hydrogen-bonding inter­actions, forming units of two 3-thio­phene­acrylic acid mol­ecules and one 4,4′-bipyridine mol­ecule

Organometallic Calixarenes: Syceelike Tetrarhenium(I) Cavitands with Tunable Size, Color, Functionality, and Coin-Slot Complexation

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