Bulk mineralogical characterisation of oilfield reservoir rocks and sandstones using DRIFTS and partial least squares analysis

The feasibility of applying Partial Least Squares (PLS) to the Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) spectra of mineral mixtures, quarry sandstones and oilfield reservoir rocks has been investigated and shown considerable potential for accurate and precise mineralogical analysis. Rapid spectrum acquisition and data processing together with small sample size requirements are key advantages of the PLS–DRIFTS method. A PLS model was created from the DRIFTS spectra of mixtures of seven mineral standards chosen to represent the most frequently encountered minerals in sandstone-type rocks; quartz, dolomite, montmorillonite, illite, kaolinite, chlorite and albite. The PLS–DRIFTS model was able to quantify the mineral components of independent mixtures with an absolute error of 1 wt.% for all the minerals (concentration range 0–30 wt.%) with the exception of quartz which exhibited an absolute error of 3 wt.% (concentration range 50–90 wt.%). The results provided by applying this PLS–DRIFTS model to several sandstone-type quarry rocks and a suite of oilfield reservoir rocks were considerably better than anticipated even though the model did not describe all the mineral components present in the samples nor the entire variance of constituent mineral components (e.g. crystallinity). The model was not able to differentiate between montmorillonite and illite probably due to the similarity of the DRIFTS spectra of these minerals, but it was able to quantify the combined (montmorillonite + illite) concentrations to within 1 wt.%. The model over-predicted the concentration of albite in the quarry rocks due to the presence of K-feldspar, which has a similar DRIFTS spectrum and was not included in the model. However, the model accurately predicted the total (albite and K-feldspar) concentration to within 4 wt.%. A separate PLS–DRIFTS model constructed using the DRIFTS spectra of the oilfield reservoir rocks showed that the carbonate components, calcite and dolomite could be differentiated and quantified to within 5.0 and 3.6 wt.%, respectively. This feasibility study confirmed the strong potential of combining DRIFTS with a multivariate statistical approach such as PLS and it is clear that more sophisticated models, that incorporates and describes a higher percentage of the variance in unknowns, would further improve the predictions

Reducing the environmental impact of surgery on a global scale: systematic review and co-prioritization with healthcare workers in 132 countries

Background Healthcare cannot achieve net-zero carbon without addressing operating theatres. The aim of this study was to prioritize feasible interventions to reduce the environmental impact of operating theatres. Methods This study adopted a four-phase Delphi consensus co-prioritization methodology. In phase 1, a systematic review of published interventions and global consultation of perioperative healthcare professionals were used to longlist interventions. In phase 2, iterative thematic analysis consolidated comparable interventions into a shortlist. In phase 3, the shortlist was co-prioritized based on patient and clinician views on acceptability, feasibility, and safety. In phase 4, ranked lists of interventions were presented by their relevance to high-income countries and low–middle-income countries. Results In phase 1, 43 interventions were identified, which had low uptake in practice according to 3042 professionals globally. In phase 2, a shortlist of 15 intervention domains was generated. In phase 3, interventions were deemed acceptable for more than 90 per cent of patients except for reducing general anaesthesia (84 per cent) and re-sterilization of ‘single-use’ consumables (86 per cent). In phase 4, the top three shortlisted interventions for high-income countries were: introducing recycling; reducing use of anaesthetic gases; and appropriate clinical waste processing. In phase 4, the top three shortlisted interventions for low–middle-income countries were: introducing reusable surgical devices; reducing use of consumables; and reducing the use of general anaesthesia. Conclusion This is a step toward environmentally sustainable operating environments with actionable interventions applicable to both high– and low–middle–income countries

A unique blueschist facies metapelite with Mg-rich chloritoid from the Badajoz-Córdoba Unit (SW Iberian Massif): correlation of Late Devonian high-pressure belts along the Variscan Orogen

The Badajoz-Córdoba Unit (BCU, SW Iberian Massif) is a Variscan high-P unit mainly constituted by metapelites, metagreywackes, orthogneisses, Grt-amphibolites, and retrogressed eclogites (high-P metamorphism at c. 377 Ma). Discovery of rare metapelites with well-preserved high-P mineral assemblages, including large garnets up to 1 cm in diameter with abundant inclusions, chloritoid (up to X = 0.32), kyanite, staurolite, chlorite, phengite (up to Si = 3.16 apfu), paragonite, margarite, and rutile, allows detailed determination of the tectonothermal evolution of the unit. Pseudosection modelling of representative samples indicates that this mineral assemblage formed in blueschist facies (near eclogite facies transition) at P conditions higher than 20 kbar at c. 525°C and that it underwent a subsequent severe exhumation and moderate heating. The lithological composition of the BCU, the age of high-P metamorphism and the characteristics of the high-P mineral assemblages are similar to those found in other high-P and low to intermediate-T units of the Variscan Orogen. All these units form part of a single blueschist-eclogite facies metamorphic belt formed during Late Devonian subduction of the external margin of Gondwana.Insightful revisions of the manuscript by Idael F. Blanco Quintero and Uwe Kroner are kindly acknowledged. Financial support has been provided by the Spanish project CGL2016-76438-P (Ministerio de Economía, Industria y Competitividad)

A unique blueschist facies metapelite with Mg-rich chloritoid from the Badajoz-Córdoba Unit (SW Iberian Massif): correlation of Late Devonian high-pressure belts along the Variscan Orogen

The Badajoz-Córdoba Unit (BCU, SW Iberian Massif) is a Variscan high-P unit mainly constituted by metapelites, metagreywackes, orthogneisses, Grt-amphibolites, and retrogressed eclogites (high-P metamorphism at c. 377 Ma). Discovery of rare metapelites with well-preserved high-P mineral assemblages, including large garnets up to 1 cm in diameter with abundant inclusions, chloritoid (up to XMg = 0.32), kyanite, staurolite, chlorite, phengite (up to Si = 3.16 apfu), paragonite, margarite, and rutile, allows detailed determination of the tectonothermal evolution of the unit. Pseudosection modelling of representative samples indicates that this mineral assemblage formed in blueschist facies (near eclogite facies transition) at P conditions higher than 20 kbar at c. 525°C and that it underwent a subsequent severe exhumation and moderate heating. The lithological composition of the BCU, the age of high-P metamorphism and the characteristics of the high-P mineral assemblages are similar to those found in other high-P and low to intermediate-T units of the Variscan Orogen. All these units form part of a single blueschist-eclogite facies metamorphic belt formed during Late Devonian subduction of the external margin of Gondwana