Breaking down banners: analytical approaches to determining the materials of painted banners

Background: This paper investigates a range of analytical techniques to yield information about the materials and processes used in making painted banners. A textile conservator, technical art historian and paintings conservator, and materials scientist have joined forces to develop a greater understanding of the potential of analytical findings in the identification of materials. Results: Visual examination using low level magnification and microscopy proved to be a crucial starting point and for identification of areas for further analysis. High magnification microscopy of cross sections was invaluable to gather information regarding the build-up of the layers, their interaction and condition. Scanning electron microscopy (SEM) of ion-milled samples showed that different areas of the banner had been prepared in different ways. SEM-EDX (scanning electron microscopy energy-dispersive X-ray spectroscopy) confirmed the presence of the main elements of pigments. Raman enabled identification of specific pigments. Raman also provided confirmation of specific materials (such as the paint filler). Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) enabled the identification of oil and resin, confirmation of pigments and fibres. Thin layers made sampling and identification challenging. Presence of materials such as silk and lead white dominated some analysis making interpretation of other materials more difficult. Conclusions: Sample preparation had a significant bearing on the effectiveness of the analysis. Ion-milling provided high quality surface on the cross section samples that enabled material interfaces to be clearly seen. The challenges of finding effective wavelengths for analysis of samples using Raman were clearly evident in this study. Microscopy showed fibres blends, easily missed using FTIR, whereas FTIR was particularly effective in the identification of man-made fibres. While portable instrumentation may be useful, for in-depth understanding of the heterogeneous layered materials sample taking still remains crucial. Commercial makers used many typical grounds and pigments but these were used sparingly, in thin layers, in order to produce a flexible object and also perhaps to reduce costs. The textile was however of high quality, in this case silk. Unexpectedly, the preparation layers do not appear to be consistent across the banner; the reasons for this need further investigation

Solar Stereoscopy with STEREO/EUVI A and B spacecraft from small (6 deg) to large (170 deg) spacecraft separation angles

We performed for the first time stereoscopic triangulation of coronal loops in active regions over the entire range of spacecraft separation angles ($\alpha_{sep}\approx 6^\circ, 43^\circ, 89^\circ, 127^\circ$, and $170^\circ$). The accuracy of stereoscopic correlation depends mostly on the viewing angle with respect to the solar surface for each spacecraft, which affects the stereoscopic correspondence identification of loops in image pairs. From a simple theoretical model we predict an optimum range of $\alpha_{sep} \approx 22^\circ-125^\circ$, which is also experimentally confirmed. The best accuracy is generally obtained when an active region passes the central meridian (viewed from Earth), which yields a symmetric view for both STEREO spacecraft and causes minimum horizontal foreshortening. For the extended angular range of $\alpha_{sep}\approx 6^\circ-127^{\circ}$ we find a mean 3D misalignment angle of $\mu_{PF} \approx 21^\circ-39^\circ$ of stereoscopically triangulated loops with magnetic potential field models, and $\mu_{FFF} \approx 15^\circ-21^\circ$ for a force-free field model, which is partly caused by stereoscopic uncertainties $\mu_{SE} \approx 9^\circ$. We predict optimum conditions for solar stereoscopy during the time intervals of 2012--2014, 2016--2017, and 2021--2023.Comment: Solar Physics, (in press), 22 pages, 9 figure

Energy harvesting from train vibrations

In this paper, linear mechanical oscillators are designed to harvest energy from train-induced vibrations. The harvested energy could be used, for example, to charge sensors mounted on the rail track for structural health monitoring. The dominant frequencies due to a passing train are determined for a specific train and speed from a recorded acceleration time-history. Using a simple model of an oscillator, the total energy harvested for the passage of one train is calculated. The stiffness, and hence the tuning frequency of the device, is varied in simulations to determine the optimum frequency at which to tune the device for a constant value of mass and damping in the device. Further simulations are conducted to investigate the power that could be harvested from multiple oscillators tuned at several dominant frequencies, and their performances are analysed and compared. The constraint for maximum relative displacement is considered in the design of each harvester, and this is adopted to assure that the amplitude of the oscillation is finite and does not exceed the physical size of the device. The robustness of the harvester is also analysed for different train speeds

Precious Metals-Exchange Rate Volatility Transmissions and Hedging Strategies

This study examines the conditional volatility and correlation dependency and interdependency for the four major precious metals (that is, gold, silver, platinum and palladium), while accounting for geopolitics within a multivariate system. The implications of the estimated results for portfolio designs and hedging strategies are also analyzed. The results for the four metals system show significant short-run and long-run dependencies and interdependencies to news and past volatility. These results have become more pervasive when the exchange rate and FFR are included. Monetary policy also has a differential impact on the precious metals and the exchange rate volatilities. Finally, the applications of the results show the optimal weights in a two-asset portfolio and the hedging ratios for long positions.exchange rates;hedging;volatility;shocks;precious metals;correlation;dependency;interdependency;multivariate

The new Global Multiple Sclerosis Severity Score (MSSS) correlates with axonal but not glial biomarkers

This study investigated whether the new Global Multiple Sclerosis Severity Scale (MSSS) correlated with cerebrospinal fluid biomarkers for axonal and glial pathology. The MSSS correlated with the phosphorylated neurofilament heavy chain (NfH-SMI35, R=0.44, P=0.016). The degree of neurofilament phosphorylation (ratio NfH-SMI34 to NfH-SMI35) was 8-fold higher in severely (median MSSS 6.5) versus mildly (MSSS 3.2) disabled patients (7.3 versus 0.9, P=0.03). The MSSS may provide a statistically powerful tool for comparing overall disease severity and be useful for validating the biomarker concept in MS

Ion milling - the perfect cross-section of a painted textile

The successful study and conservation of historical objects is greatly enhanced by accurate materials analysis. Here embedded cross-sections from a processional marching banner were viewed by scanning electron microscopy (SEM) pre and post ion milling The application of ion-milling to the resin embedded cross-sections of the painted textile improved the sample surface resulting in greatly enhanced SEM images by producing clear distinctions between layers. It also enabled clear images which show the areas where ingress of the ground paint layer had seeped into the textile support in some areas and not on others. This perhaps indicates deliberate differences in the preparation layer depending on the type of final painting layer or it could simply be due to a lack of accuracy in its application prior to painting. The analysis of cross-section samples from painted textiles often includes the textile itself making sample preparation more complex due to the possibility of fraying of the textile during sample polishing; the ion-milling technique prevented this from occurring. To enhance findings further analysis on these ion milled cross-section samples by the use of mapping spectroscopic techniques such as Fourier transform infrared spectroscopy (FTIR) and Raman would facilitate material identification of the layers

A ‘healthy baby’: The double imperative of preimplantation genetic diagnosis

This is the author's accepted manuscript. The final published article is available from the link below. Copyright @ 2010 The Authors.This article reports from a study exploring the social processes, meanings and institutions that frame and produce ‘ethical problems’ and clinical dilemmas for practitioners, scientists and others working in the specialty of preimplantation genetic diagnosis (PGD). A major topic in the data was that, in contrast to IVF, the aim of PGD is to transfer to the woman’s womb only those embryos likely to be unaffected by serious genetic disorders; that is, to produce ‘healthy babies’. Staff described the complex processes through which embryos in each treatment cycle must meet a double imperative: they must be judged viable by embryologists and ‘unaffected’ by geneticists. In this article, we focus on some of the ethical, social and occupational issues for staff ensuing from PGD’s double imperative.The Wellcome Trus

Seismic analysis of the second ionization region of helium in the Sun - I. Sensitivity study and methodology

The region of the second ionization of helium in the Sun is a narrow layer near the surface. Ionization induces a local change in the adiabatic exponent Γ1, which produces a characteristic signature in the frequencies of p modes. By adapting the method developed by Monteiro, Christensen-Dalsgaard & Thompson, we propose a methodology for determining the properties of this region by studying such a signature in the frequencies of oscillation. Using solar data we illustrate how the signal from the helium ionization zone can be isolated. Using solar models which each use different physics — the theory of convection, equation of state and low-temperature opacities — we establish how the characteristics of the signal depend on the various physical processes contributing to the structure in the ionization layer. We further discuss how the method can be used to measure the solar helium abundance in the envelope and to constrain the physics affecting this region of the Sun. The potential usefulness of the method we propose is shown. It may complement other inversion methods developed to study the solar structure and to determine the envelope helium abundance

Effect of continuum couplings in fusion of halo 11^{11}Be on 208^{208}Pb around the Coulomb barrier

The effect of continuum couplings in the fusion of the halo nucleus $^{11}$Be on $^{208}$Pb around the Coulomb barrier is studied using a three-body model within a coupled discretised continuum channels (CDCC) formalism. We investigate in particular the role of continuum-continuum couplings. These are found to hinder total, complete and incomplete fusion processes. Couplings to the projectile $1p_{1/2}$ bound excited state redistribute the complete and incomplete fusion cross sections, but the total fusion cross section remains nearly constant. Results show that continuum-continuum couplings enhance the irreversibility of breakup and reduce the flux that penetrates the Coulomb barrier. Converged total fusion cross sections agree with the experimental ones for energies around the Coulomb barrier, but underestimate those for energies well above the Coulomb barrier.Comment: 15 pages, 7 figures, accepted in Phys. Rev.