Photoinduced Doughnut-Shaped Nanostructures

We show that an incoherent unpolarized single-beam illumination is able to photoinduce nano-doughnuts on the surface of azopolymer thin films. We demonstrate that individual doughnut-shaped nano-objects as well as clusters of several adjacent nano-doughnuts can be formed and tailored with wide range of typical sizes, thus providing a rich field for applications in nanophotonics and photochemistry.Comment: 13 pages, 3 figures, first version to chem. phys. lett. 201

Asymmetry Effects on Nuclear Fragmentation

We show the possibility of extracting important information on the symmetry term of the Equation of State ($EOS$) directly from multifragmentation reactions using stable isotopes with different charge asymmetries. We study n-rich and n-poor $Sn + Sn$ collisions at $50AMeV$ using a new stochastic transport approach with all isospin effects suitably accounted for. For central collisions a chemical component in the spinodal instabilities is clearly seen. This effect is reduced in the neck fragmentation observed for semiperipheral collisions, pointing to a different nature of the instability. In spite of the low asymmetry tested with stable isotopes the results are showing an interesting and promising dependence on the stiffness of the symmetry term, with an indication towards an increase of the repulsion above normal density.Comment: 8 pages (Latex), 7 Postscript figures, CRIS2000 Conference, Acicastello, Italy, May 22-26, (2000), Nucl. Phys. A (in press

Investigation of Low-Density Symmetry Energy via Nucleon and Fragment Observables

With stochastic transport simulations we study in detail central and peripheral collisions at Fermi energies and suggest new observables, sensitive to the symmetry energy below normal density. As such we identify on one hand the isospin imbalance ratio, i.e. the relative amount of isospin equilibration in binary, peripheral reactions of nuclei with different isospin, as a function of the energy loss, which is sensitive to isospin diffusion; on the other hand the isospin asymmetry of an intermediate mass fragment (IMF) in symmetric collisions in ternary reactions, or more particularly, the ratio of the IMF to the residue asymmetry, which is sensitive to isospin migration.Comment: 6 pages, 6 figures; Contrib. to Int. Symp. on Exotic States of Nuclear Matter (EXOCT2007), Catania, Italy, June 2007, World Scientifc styl

Nighttime air quality under desert conditions

Nighttime concentrations of the gas phase nitrate radical (NO3) were successfully measured during a four week field campaign in an arid urban location, Reno Nevada, using long-path Differential Optical Absorbance Spectrometry (DOAS). While typical concentrations of NO3 ranged from 5 to 20ppt, elevated concentrations were observed during a wildfire event. Horizontal mixing in the free troposphere was considerable because the sampling site was above the stable nocturnal boundary layer every night and this justified a box modeling approach. Process analysis of box model simulations showed NO3 accounted for approximately half of the loss of internal olefins, 60% of the isoprene loss, and 85% of the α-pinene loss during the nighttime hours during a typical night of the field study. The NO3+aldehyde reactions were not as important as anticipated. On a polluted night impacted by wildfires upwind of the sampling location, NO3 reactions were more important. Model simulations overpredicted NO2 concentrations for both case studies and inorganic chemistry was the biggest influence on NO3 concentrations and on nitric acid formation. The overprediction may be due to additional NO2 loss processes that were not included in the box model, as deposition and N2O5 uptake had no significant effect on NO2 levels

The scenario of two-dimensional instabilities of the cylinder wake under EHD forcing: A linear stability analysis

We propose to study the stability properties of an air flow wake forced by a dielectric barrier discharge (DBD) actuator, which is a type of electrohydrodynamic (EHD) actuator. These actuators add momentum to the flow around a cylinder in regions close to the wall and, in our case, are symmetrically disposed near the boundary layer separation point. Since the forcing frequencies, typical of DBD, are much higher than the natural shedding frequency of the flow, we will be considering the forcing actuation as stationary. In the first part, the flow around a circular cylinder modified by EHD actuators will be experimentally studied by means of particle image velocimetry (PIV). In the second part, the EHD actuators have been numerically implemented as a boundary condition on the cylinder surface. Using this boundary condition, the computationally obtained base flow is then compared with the experimental one in order to relate the control parameters from both methodologies. After validating the obtained agreement, we study the Hopf bifurcation that appears once the flow starts the vortex shedding through experimental and computational approaches. For the base flow derived from experimentally obtained snapshots, we monitor the evolution of the velocity amplitude oscillations. As to the computationally obtained base flow, its stability is analyzed by solving a global eigenvalue problem obtained from the linearized Navier–Stokes equations. Finally, the critical parameters obtained from both approaches are compared

Smart nanogels at the air/water interface: structural studies by neutron reflectivity

STFC for provision of consumables and subsistence and access to the ILL facility through the STFC managed UK contribution to the facility (EXP: 9-13-530, 9-11-1721 and 9-11-17446). The European Commission (FP7 Marie Curie Actions, NANOLEM, PIEF-GA-2013-627146 to KZ) and the Chinese Scholarship Council (studentship to HS) are gratefully acknowledged for financial support

Cannabidiol in neurological and neoplastic diseases: Latest developments on the molecular mechanism of action

As the major nonpsychotropic constituent of Cannabis sativa, cannabidiol (CBD) is regarded as one of the most promising therapeutic agents due to its proven effectiveness in clinical trials for many human diseases. Due to the urgent need for more efficient pharmacological treatments for several chronic diseases, in this review, we discuss the potential beneficial effects of CBD for Alzheimers disease, epilepsy, multiple sclerosis, and neurological cancers. Due to its wide range of pharmacological activities (e.g., antioxidant, anti-inflammatory, and neuroprotective properties), CBD is considered a multimodal drug for the treatment of a range of neurodegenerative disorders, and various cancer types, including neoplasms of the neural system. The different mechanisms of action of CBD are here disclosed, together with recent progress in the use of this cannabis-derived constituent as a new therapeutic approach. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.Institute of Human Genetics, Polish Academy of Sciences by the internal grant for the implementation of a single scientific activity and by the National Centre for Research and Development by the grant ONKOKAN, INNOMED/I/11/NCBR/2014info:eu-repo/semantics/publishedVersio