A deep narrowband survey for planetary nebulae at the outskirts of M33

Context: Planetary nebulae (PNe) are excellent tracers of stellar populations with low surface brightness, and therefore provide a powerful method to detect and explore the rich system of substructures discovered around the main spiral galaxies of the Local Group. Aims: We searched the outskirts of the Local Group spiral galaxy M33 (the Triangulum) for PNe to gain new insights into the extended stellar substructure on the northern side of the disc and to study the existence of a faint classical halo. Methods: The search is based on wide field imaging covering a 4.5 square degree area out to a maximum projected distance of about 40 kpc from the centre of the galaxy. The PN candidates are detected by the combination of images obtained in narrowband filters selecting the [OIII]$\lambda5007\AA$ and H$\alpha$ + [NII] nebular lines and in the continuum g' and r' broadband filters. Results:Inside the bright optical disc of M33, eight new PN candidates were identified, three of which were spectroscopically confirmed. No PN candidates were found outside the limits of the disc. Fourteen additional sources showing [OIII] excess were also discovered. Conclusions:The absence of bright PN candidates in the area outside the galaxy disc covered by this survey sets an upper limit to the luminosity of the underlying population of $\mathrm{\sim1.6\cdot10^{7}L_{\odot}}$, suggesting the lack of a massive classical halo, which is in agreement with the results obtained using the RGB population.Comment: 13 pages, 18 figure

The throughput calibration of the VERITAS telescopes

Imaging atmospheric Cherenkov telescopes are continuously exposed to varying weather conditions that have short and long-term effects on their response to Cherenkov light from extensive air showers. This work presents the implementation of a throughput calibration method for the VERITAS telescopes taking into account changes in the optical response and detector performance over time. Different methods to measure the total throughput of the instrument, which depend on mirror reflectivites and PMT camera gain and efficiency, are discussed as well as the effect of its evolution on energy thresholds, effective collection areas, and energy reconstruction. The application of this calibration in the VERITAS data analysis chain is discussed, including the validation using Monte Carlo simulations and observations of the Crab Nebula.Comment: 7 pages, 4 figures, ICRC2021 Conference (Berlin, online

A simple and mild chemical oxidation route to high-purity nano-graphene oxide

Nano-graphene oxide (nGO) is used in a wide range of applications including cellular imaging, drug delivery, desalination and energy storage. Current preparation protocols are similar as for standard graphene oxide (GO) and typically rely on mixtures of sulfuric acid and potassium permanganate. We present a new route to nGO (∼30 nm diameter) using a quite defective arc-discharge carbon source and only 9 M nitric acid as the oxidising agent. The preparation can be scaled up proportionately with current GO protocols with 50 mL of half-concentrated nitric acid able to process one gram of arc-discharge material. The workup is straight forward and involves neutralization with sodium hydroxide which precipitates the sodium salt of nGO from solution. The only by-product of the new procedure is aqueous sodium nitrate which makes this protocol the cleanest route yet to nGO. The presence and quantities of functional groups in our nGO are determined and compared with standard GO. We anticipate that this new route to nGO will foster a range of new applications. The presence of highly reactive carboxylic anhydride groups on our nGO material in particular offers an excellent opportunity for purpose-specific chemical functionalization

Highly efficient heavy-metal extraction from water with carboxylated graphene nanoflakes

Heavy metals such a lead or cadmium have a wide range of detrimental and devastating effects on human health. It is therefore of paramount importance to efficiently remove heavy metals from industrial wastewater streams as well as drinking water. Carbon materials, including graphene and graphene oxide (GO), have recently been advocated as efficient sorption materials for heavy metals. We show that highly carboxylated graphene nanoflakes (cx-GNF) outperform nano-graphene oxide (nGO) as well as traditional GO with respect to extracting Fe 2+ , Cu 2+ , Fe 3+ , Cd 2+ and Pb 2+ cations from water. The sorption capacity for Pb 2+ , for example, is more than six times greater for the cx-GNF compared to GO which is attributed to the efficient formation of lead carboxylates as well as strong cation-π interactions. The large numbers of carboxylic acid groups as well as the intact graphenic regions of the cx-GNF are therefore responsible for the strong binding of the heavy metal cations. Remarkably, the performance of the as-made cx-GNF can easily compete with previously reported carbon materials that have undergone additional chemical-functionalisation procedures for the purpose of heavy-metal extraction. Furthermore, the recyclability of the cx-GNF material with respect to Pb 2+ loading is demonstrated as well as the outstanding performance for Pb 2+ extraction in the presence of excess Ca 2+ or Mg 2+ cations which are often present under environmental conditions. Out of all the graphene materials, the cx-GNF therefore show the greatest potential for future application in heavy-metal extraction processes

El aceite de oliva extra virgen y su fracción polifenólica previenen la respuesta inflamatoria y el daño articular en un modelo de artritis experimental en murino

The consumption of EVOO in Mediterranean countries has shown beneficial effects. A wide range of evidence indicates that the phenolic compounds present in EVOO are endowed with anti-inflammatory properties. In this work, we evaluated the effects of dietary EVOO and treatment with its phenolic extract (PE) in a model of RA, the collagen-induced arthritis (CIA) in mice. On day 0, DBA-1/J mice were immunized with bovine collagen type II (CII). On day 21, the mice received a booster injection. We have demonstrated that EVOO and its PE decreases joint edema, cell migration, cartilage degradation and bone erosion. Our data indicate that dietary EVOO and PE treatment inhibit JNK, p38 and signal transducer and STAT-3. In addition, both EVOO and PE decrease NF-κB translocation leading to the down-regulation of the arthritic process. These results support the interest of natural diet components in the development of therapeutic products for arthritic conditions.El consumo de Aceite de oliva virgen extra (AOVE) en los países mediterráneos ha demostrado tener efectos beneficiosos. Una amplia gama de pruebas indica que los compuestos fenólicos presentes en el AOVE tienen propiedades anti-inflamatorias. En este trabajo, se evaluaron los efectos de AOVE y el tratamiento en dieta de su fracción polifenólica (FP) en un modelo de la artritis reumatoide inducida por colágeno (CIA) en ratones. En el día 0, los ratones DBA-1/J se inmunizaron con colágeno bovino tipo II (CII). En el día 21, los ratones recibieron una inyección de refuerzo. Hemos demostrado que el AOVE y su FP disminuyen conjuntamente el edema, la migración celular, la degradación del cartílago y erosión ósea. Nuestros datos indican que la dieta con AOVE y el tratamiento con FP inhiben JNK, p38 y el transductor de señal y activador de la transcripción 3 (STAT-3). Además, tanto el AOVE como la FP disminuyen la translocación NF-κB que conduce a la mejora del proceso artrítico. Estos resultados apoyan el interés de una dieta con componentes naturales y el desarrollo de productos terapéuticos para desordenes artríticos

Non-uniform UE-spline quasi-interpolants and their application to the numerical solution of integral equations

A construction of Marsden’s identity for UE-splines is developed and a complete proof is given. With the help of this identity, a new non-uniform quasi-interpolant that repro-duces the spaces of polynomial, trigonometric and hyperbolic functions are defined. Effi-cient quadrature rules based on integrating these quasi-interpolation schemes are derived and analyzed. Then, a quadrature formula associated with non-uniform quasi-interpolation along with Nyström’s method is used to numericallysolve Hammerstein and Fredholm integral equations. Numerical results that illustrate the effectiveness of these rules are pre-sented.Universidad de Granada / CBU

Los retos de innovación a través de las tecnologías de información en las Smart Cities

Estamos viviendo una era denominada del cómputo móvil donde las Tecnologías de Información y de la Comunicación (TICs) están con una fuerte presencia en nuestra vida y actividades cotidianas. Este artículo presenta las tendencias mundiales sobre la evolución del concepto de Smart City en las últimas dos décadas. También se explican los modelos de gobernanza de estas ciudades como factor de cambio y la metodología formal. Así, se respaldan procesos para tomar decisiones que impacten en una mejora en la calidad de vida. Finalmente, se presenta una iniciativa mundial y se finaliza con una reflexión sobre las áreas de oportunidad, en particular para ciudades en América Latina.Facultad de Informátic

Electrochemical characterisation of graphene nanoflakes with functionalised edges

Graphene nanoflakes (GNF) of diameter ca. 30 nm and edge-terminated with carboxylic acid (COOH) or amide functionalities were characterised electrochemically after drop-coating onto a boron-doped diamond (BDD) electrode. In the presence of the outer-sphere redox probe ferrocenemethanol there was no discernible difference in electrochemical response between the clean BDD and GNF-modified electrodes. When ferricyanide or hydroquinone were used as redox probes there was a marked difference in response at the electrode modified with COOH-terminated GNF in comparison to the unmodified BDD and amide-terminated GNF electrode. The response of the COOH-terminated GNF electrode was highly pH dependent, with the most dramatic differences in response noted at pH < 8. This pH range coincides with partial protonation of the carboxylic acid groups as determined by titration. The acid edge groups occupy a range of bonding environments and are observed to undergo deprotonation over a pH range ca. 3.7 to 8.3. The protonation state of the GNF influences the oxidation mechanism of hydroquinone and in particular the number of solution protons involved in the reaction mechanism. The voltammetric response of ferricyanide is very inhibited by the presence of COOH-terminated GNF at pH < 8, especially in low ionic strength solution. While the protonation state of the GNF is clearly a major factor in the observed response, the exact role of the acid group in the redox process has not been firmly established. It may be that the ferricyanide species is unstable in the solution environment surrounding the GNF, where dynamic protonation equilibria are at play, perhaps through disruption to ion pairing

The influence of acidic edge groups on the electrochemical performance of graphene nanoflakes

Graphene nanoflakes (GNF) with lateral dimensions of ca. 30 nm and edge-terminated with carboxylic acid functionalities have been characterised and the influence of acidic functionalities on the [Fe(CN)6]3−/4− redox couple studied using cyclic voltammetry and spectroelectrochemical methods. The presence of the COOH-terminated GNF in solution as well as immobilised onto an electrode surface was found to inhibit the redox reaction, supporting the conclusion that GNF promote instability of [Fe(CN)6]3−/4− in solution. The redox reaction was also much less influenced by the presence of GNF in D2O, highlighting the role played by readily available protons in destabilising the [Fe(CN)6]3−/4− redox couple. In the presence of GNF in solution, an additional, very intense cyanide stretch IR band was observed that was attributed to the formation of a new, non-soluble species. When D2O was used as the solvent, the IR spectrum showed no evidence of a new cyano species