A study of rainfall in the Roman area in the years 1951--2000

The daily rainfall data collected in the second half of the last century at 31 climatic stations in Lazio, Italy, have been subjected to statistical analysis in order to describe the pluviometric regime of the whole area on a multi-decadal time scale. The stations, for their geographical distribution within the region under study, are apt to represent different climatic zones, namely, a coastal, a rural, a suburban and an urban zone. The data have been treated both as time series and as geographicalstatisticalv ariates with the double aim, first, to verify if in the area under study any changes in the yearly precipitation rate, frequency and its distribution over different classes of rain intensity, have occurred in the last 50 years; second, to evidence a possible correlation between the intensity of precipitation and any of some environmental variables such as altitude, distance from the coastline and distance from the urban site. As for the first issue, it can be concluded that the precipitations over the Roman area in the period 1951–2000 show no significant trend; in particular, no trend is visible in any of the single classes of rain intensity, both absolute and percentile-based, considering either their frequency or their percent contribution to the total. As for the second issue, significant correlations have been found in the spatial distribution of rainfall with any of the relevant environmental variables mentioned above. The results of the analysis also show that in the urban area a less amount of rain seem to fall than in the surroundings zones, a result that seems rather anomalous in consideration of the several known factors that favour the intensification of the rainfall in the city with respect to its surroundings. A detailed statistical characterization of all the single 31 stations over the whole period is also given via a separate study of the durations of droughts and of the statistics of rainy days, using best fits based on the Weibull probability distribution

Optical properties of the Ce and La di-telluride charge density wave compounds

The La and Ce di-tellurides LaTe$_2$ and CeTe$_2$ are deep in the charge-density-wave (CDW) ground state even at 300 K. We have collected their electrodynamic response over a broad spectral range from the far infrared up to the ultraviolet. We establish the energy scale of the single particle excitation across the CDW gap. Moreover, we find that the CDW collective state gaps a very large portion of the Fermi surface. Similarly to the related rare earth tri-tellurides, we envisage that interactions and Umklapp processes play a role in the onset of the CDW broken symmetry ground state

Verification of precipitation forecasts from two limited-area models over Italy and comparison with ECMWF forecasts using a resampling technique

This paper presents the first systematic limited area model (LAM) precipitation verification work over Italy. A resampling technique was used to provide skill score results along with confidence intervals. Two years of data were used, starting in October 2000. Two operational LAMs have been considered, the Limited Area Model Bologna (LAMBO) operating at the Agenzia Regionale Prevenzione e Ambiente- Servizio Meteorologico Regionale (ARPA-SMR) of the Emilia–Romagna region, and the QUADRICS Bologna Limited Area Model (QBOLAM) running at the Agenzia per la Protezione dell’Ambiente e per i Servizi Tecnici (APAT). A 24-h forecast skill score comparison was first performed on the native 0.1° high-resolution grids, using a Barnes scheme to produce the observed 24-h accumulated rainfall analysis. Two nonparametric skill scores were used: the equitable threat score (ETS) and the Hanssen and Kuipers score (HK). Frequency biases (BIA) were also calculated. LAM forecasts were also remapped on a lowerresolution grid (0.5°), using a nearest-neighbor average method; this remapping allowed for comparison with ECMWF model forecasts, and for LAM intercomparisons at lower resolution, with the advantage of reducing the skill score sensitivity to small displacements errors. LAM skill scores depend on the resolution of the verification grid, with an increase when they are verified on a lower-resolution grid. The selected LAMs have a higher BIA compared to ECMWF, showing a tendency to overforecast precipitation, especially along mountain ranges, possibly due to undesired effects from the large-scale and/or convective precipitation parameterizations. Lower ECMWF BIA accounts for skill score differences. LAMBO precipitation forecasts during winter (adjusted for BIA differences) have less misses than ECMWF over the islands of Sardinia and Sicily. Higher-resolution orography definitely adds value to LAM forecasts

Verification of Precipitation Forecasts from Two Limited-Area Models over Italy and Comparison with ECMWF Forecasts Using a Resampling Technique

Abstract This paper presents the first systematic limited area model (LAM) precipitation verification work over Italy. A resampling technique was used to provide skill score results along with confidence intervals. Two years of data were used, starting in October 2000. Two operational LAMs have been considered, the Limited Area Model Bologna (LAMBO) operating at the Agenzia Regionale Prevenzione e Ambiente-Servizio Meteorologico Regionale (ARPA-SMR) of the Emilia–Romagna region, and the QUADRICS Bologna Limited Area Model (QBOLAM) running at the Agenzia per la Protezione dell'Ambiente e per i Servizi Tecnici (APAT). A 24-h forecast skill score comparison was first performed on the native 0.1° high-resolution grids, using a Barnes scheme to produce the observed 24-h accumulated rainfall analysis. Two nonparametric skill scores were used: the equitable threat score (ETS) and the Hanssen and Kuipers score (HK). Frequency biases (BIA) were also calculated. LAM forecasts were also remapped on a lower-resolution grid (0.5°), using a nearest-neighbor average method; this remapping allowed for comparison with ECMWF model forecasts, and for LAM intercomparisons at lower resolution, with the advantage of reducing the skill score sensitivity to small displacements errors. LAM skill scores depend on the resolution of the verification grid, with an increase when they are verified on a lower-resolution grid. The selected LAMs have a higher BIA compared to ECMWF, showing a tendency to overforecast precipitation, especially along mountain ranges, possibly due to undesired effects from the large-scale and/or convective precipitation parameterizations. Lower ECMWF BIA accounts for skill score differences. LAMBO precipitation forecasts during winter (adjusted for BIA differences) have less misses than ECMWF over the islands of Sardinia and Sicily. Higher-resolution orography definitely adds value to LAM forecasts

Raman scattering evidence for a cascade-like evolution of the charge-density-wave collective amplitude mode

The two-dimensional rare-earth tri-tellurides undergo a unidirectional charge-density-wave (CDW) transition at high temperature and, for the heaviest members of the series, a bidirectional one at low temperature. Raman scattering experiments as a function of temperature on DyTe$_3$ and on LaTe$_3$ at 6 GPa provide a clear-cut evidence for the emergence of the respective collective CDW amplitude excitations. In the unidirectional CDW phase, we surprisingly discover that the amplitude mode develops as a succession of two mean-field, BCS-like transitions in different temperature ranges

Pressure dependence of the single particle excitation in the charge-density-wave CeTe3_3 system

We present new data on the pressure dependence at 300 K of the optical reflectivity of CeTe$_3$, which undergoes a charge-density-wave (CDW) phase transition well above room temperature. The collected data cover an unprecedented broad spectral range from the infrared up to the ultraviolet, which allows a robust determination of the gap as well as of the fraction of the Fermi surface affected by the formation of the CDW condensate. Upon compressing the lattice there is a progressive closing of the gap inducing a transfer of spectral weight from the gap feature into the Drude component. At frequencies above the CDW gap we also identify a power-law behavior, consistent with findings along the $R$Te$_3$ series (i.e., chemical pressure) and suggestive of a Tomonaga-Luttinger liquid scenario at high energy scales. This newest set of data is placed in the context of our previous investigations of this class of materials and allows us to revisit important concepts for the physics of CDW state in layered-like two-dimensional systems

Microstructural evolution of 3YSZ flash sintered with current ramp control

Ceramics sintered by Flash Sintering (FS), sometimes have heterogeneity in their microstructure. Among the possible causes of this problem, the formation of hotspots is probably the principal issue observed in flash sintering. The hotspots are formed due to the heterogeneity of the resistance of current passing in the green sample. In this way, in the flash phenomenon, the current finds preferential paths, carrying on non-uniform thermal runaway. In this work, we observed that one way of reversing this problem was gradually increasing the electric current density at FS. For this, 3YSZ was shaped in cylindrical form (5 mm height and 6 mm diameter) and flash sintered, at a tubular setup proposed before1, under the application of an AC electric field of 120 V/cm (RMS basis) applied from the beginning of the furnace heating. Three different electric current density ramps were studied: 0.012, 0.024 and 0.048 A.s-1, named as Z1, Z2 and Z3 respectively, until they reached the maximum value of 100 mA.mm-2 (the moment the power supply was turned off). For comparison purposes, conventional FS (Z0) was performed using the same electrical parameters. The electric source, in this case, remained on after reaching 100 mA.mm-2 for 142 s (time calculated to reach the same total energy supplied by the electrical source of samples Z1). After sintering, the apparent densities of the samples were measured according to the Archimedes principle. For analysis of the microstructure, the samples were cut radially and three regions of each sample were observed in SEM: center, right and left surfaces. The grain size distribution was made for each region using ImageJ software. The apparent density of samples sintered by FS was 94 % (Z0) and samples with electrical current ramp were 93 %, 92 % and 87 % for Z1, Z2 and Z3, respectively. The apparent density is proportional to the total energy supplied to the sample (energy provided by the power supply and thermal energy provided by the furnace). Thus, the density of Z0 was expected to be close to the density of Z1. As samples Z2 and Z3 had more abrupt ramps, the energy supplied was lower, which resulted in lower apparent density. The grain size distribution indicates that the mean grain size between the three different regions did not present statistically significant differences (ANOVA test) for the same sample. Please click Additional Files below to see the full abstract

Alternative route to charge density wave formation in multiband systems

Charge and spin density waves, periodic modulations of the electron and magnetization densities, respectively, are among the most abundant and non-trivial low-temperature ordered phases in condensed matter. The ordering direction is widely believed to result from the Fermi surface topology. However, several recent studies indicate that this common view needs to be supplemented. Here, we show how an enhanced electron-lattice interaction can contribute to or even determine the selection of the ordering vector in the model charge density wave system ErTe3. Our joint experimental and theoretical study allows us to establish a relation between the selection rules of the electronic light scattering spectra and the enhanced electron-phonon coupling in the vicinity of band degeneracy points. This alternative proposal for charge density wave formation may be of general relevance for driving phase transitions into other broken-symmetry ground states, particularly in multiband systems such as the iron based superconductors

Role of charge doping and lattice distortions in codoped Mg_{1-x}(AlLi)_{x}B_2 compounds

We prepared a series of Mg_{1-x}(AlLi)_{x}B_2 samples with 0≤x≤0.45 in order to compensate with Li the electron doping induced by Al. Structural characterization by means of neutron and X-ray diffraction confirms that Li enters the MgB2 structure even though in an amount less than nominal one. We performed susceptibility, resistivity and specific heat measurements. Vibrational properties were also investigated by means of Raman spectroscopy. We compare these results with those obtained on a homologous series of Mg_{1-x}Al_{x}B_2 samples. The systematic success of scaling the relevant properties with the Al content rather than with the electron doping suggests that lattice deformation plays an important role in tuning the superconducting properties.Comment: 15 pages, 13 figures; changes: "codoped" instead of "co-doped"; added comments in the Fig. 11 caption Comments 31/1/2006: 16 figures ; new revised version of the manuscrip