874 research outputs found
(−)-Istanbulin A
The title compound (systematic name: 9a-hydroxy-3,4a,5-trimethyl-4a,6,7,8a,9,9a-hexahydro-4H,5H-naphtho[2,3-b]furan-2,8-dione), C15H20O4, is a sesquiterpene lactone showing the typical eremophilanolide skeleton, which has been isolated from the plant Senecio candidans collected in the Chilean Magallanes region. The present study confirms the atomic connectivity assigned on the basis of 1H and 13C NMR spectroscopy, as well as the relative stereochemistry of the 4α-methyl,5α-methyl,8β-hydroxy,10β-H unit. The crystal structure is stabilized by intermolecular O—H⋯O hydrogen bonds involving the hydroxy group as donor and the oxo group as acceptor, giving chains along the a axis. The absolute structure was not determined because of the lack of suitable anomalous scatters
Potential use of Sargassum muticum as source of plant biostimulants after three different drying methods
Seaweed derived biostimulants are gaining attention as an important tool in sustainable agriculture. This offers a unique opportunity to alleviate the environmental impact of Sargassum muticum (Ochrophyta, Phaeophyceae) as an invasive species by finding new applications for its biomass. In this sense, incorporating green extraction technologies is fundamental to ensure environmental-friendly goals. This research was initiated in an attempt to contribute to an integral valorization system of S. muticum biomass, exploring the biostimulant potential of the solubles obtained from pressed solids, through an autohydrolysis treatment. In addition, we compared the effect of three different liquid phase drying techniques (spray-drying, freeze-drying and convective air-drying). Low stress drying techniques as spray-drying showed better conservation of bioactive compounds and biostimulant potential. A bioassay with Nastrium officinale showed no phytotoxic effects despite high electric conductivity in most of the extracts and concentrations. Dried extracts showed mainly an amorphous structure but occasional crystal formation when spray-dried at low temperatures (T out = 50 ºC) and after convective air drying (T = 40 ºC). Significant increases in root development were achieved at a concentration of 5 mg L −1 of spray-dried extracts and 50 mg L −1 in case of freeze-dried extracts. Munoo-Liisa vitality index showed best results with 50 mg L −1 of freeze-dried extracts. This study provides important information about the influence of different drying techniques on the physicochemical properties and biostimulant potential of S. muticum aqueous extracts and contributes to the integral valorization of its biomass.Agencia Estatal de Investigación | Ref. RYC2018-024454-IXunta de Galicia | Ref. ED431F 2020/01Xunta de Galicia | Ref. ED481D-2022/018Universidade de Vigo/CISU
Herschel Far-IR counterparts of SDSS galaxies: Analysis of commonly used Star Formation Rate estimates
We study a hundred of galaxies from the spectroscopic Sloan Digital Sky
Survey with individual detections in the Far-Infrared Herschel PACS bands (100
or 160 m) and in the GALEX Far-UltraViolet band up to z0.4 in the
COSMOS and Lockman Hole fields. The galaxies are divided into 4 spectral and 4
morphological types. For the star forming and unclassifiable galaxies we
calculate dust extinctions from the UV slope, the H/H ratio and
the ratio. There is a tight correlation between the
dust extinction and both and metallicity. We calculate
SFR and compare it with other SFR estimates (H, UV, SDSS)
finding a very good agreement between them with smaller dispersions than
typical SFR uncertainties. We study the effect of mass and metallicity, finding
that it is only significant at high masses for SFR. For the AGN and
composite galaxies we find a tight correlation between SFR and L
(0.29), while the dispersion in the SFR - L relation is
larger (0.57). The galaxies follow the prescriptions of the
Fundamental Plane in the M-Z-SFR space.Comment: 24 pages, 23 figures, accepted for publication in MNRA
EFFECT OF SEASON ON SERUM COPPER AND ZINC CONCENTRATIONS IN CROSSBRED GOATS HAVING DIFFERENT REPRODUCTIVE STATUS UNDER SEMIARID RANGELAND CONDITIONS IN SOUTHERN MEXICO STATE
The effect of season (rainy: RS, and dry: DS) and reproductive status on copper (Cu) and zinc (Zn) concentrations in blood serum of crossbred goats (BW= 36.01 ± 1.59 kg) were studied under semiarid rangeland conditions in Southern Mexico State. Blood samples from 80 crossbred goats were taken each season (RS and DS). The goats were clustered into 10 different groups considering their reproductive status. Concentrations of Cu and Zn in serum were assayed using atomic absorption. Data were analyzed using a general linear model procedure for a completely randomized design and differences among means were examined using a Tukey test. Blood serum concentrations of Cu and Zn were affected by reproductive status and season (P<0.001). In relation to the season, Cu and Zn serum levels were lower in RS than DS (P<0.05). Overall, kidded goats had the highest values (P<0.01) for Cu than other animals in both seasons (RS or DS). Anestrous goats had the lowest concentrations (P<0.01) for Zn during RS, while all goats at their second or more kidding, rearing single or twins, showed the highest concentrations of Zn (P<0.001) in this season. Adult goats in Southern Mexico State showed a deficiency of Cu and Zn, especially during RS. As such, mineral supplements should be provided with respect to these elements in feeding systems for goats under semiarid rangeland conditions in order to evaluate their impact on health and reproduction
Active surveillance in prostate cancer: role of available biomarkers in daily practice
Prostate cancer (PCa) is the most commonly diagnosed cancer in men. The diagnosis is currently based on PSA levels, which are associated with overdiagnosis and overtreatment. Moreover, most PCas are localized tumours; hence, many patients with low-/very low-risk PCa could benefit from active surveillance (AS) programs instead of more aggressive, active treatments. Heterogeneity within inclusion criteria and follow-up strategies are the main controversial issues that AS presently faces. Many biomarkers are currently under investigation in this setting; however, none has yet demonstrated enough diagnostic ability as an independent predictor of pathological or clinical progression. This work aims to review the currently available literature on tissue, blood and urine biomarkers validated in clinical practice for the management of AS patients
Fano-Rashba effect in quantum dots
We consider the electronic transport through a Rashba quantum dot coupled to
ferromagnetic leads. We show that the interference of localized electron states
with resonant electron states leads to the appearance of the Fano-Rashba
effect. This effect occurs due to the interference of bound levels of
spin-polarized electrons with the continuum of electronic states with an
opposite spin polarization. We investigate this Fano-Rashba effect as a
function of the applied magnetic field and Rashba spin-orbit coupling.Comment: 8 pages, 6 figures. To appear in Nanotechnolog
Simulation Studies on the Stability of the Vortex-Glass Order
The stability of the three-dimensional vortex-glass order in random type-II
superconductors with point disorder is investigated by equilibrium Monte Carlo
simulations based on a lattice XY model with a uniform field threading the
system. It is found that the vortex-glass order, which stably exists in the
absence of screening, is destroyed by the screenng effect, corroborating the
previous finding based on the spatially isotropic gauge-glass model. Estimated
critical exponents, however, deviate considerably from the values reported for
the gauge-glass model.Comment: Minor modifications made, a few referenced added; to appear in J.
Phys. Soc. Jpn. Vol.69 No.1 (2000
Movement representation strategies as a tool for educational innovation in physiotherapy students: a randomized single-blind controlled-pilot trial
Physiotherapy has a strictly theoretical body of knowledge, but for the most part, the physiotherapist’s learning is practical. The practical part is fundamental to acquire clinical skills that the physiotherapist will later use in professional practice. The main aim of this study was to assess the effectiveness of movement representation strategies (MRS) in the improvement of manual skills of physiotherapy students as an educational innovation strategy. We randomly assigned 30 participants to an action observation practice (AOP), motor imagery practice (MIP), or sham observation (SO) group. A high velocity, low amplitude lumbar manipulation technique that is widely used in clinical physiotherapy practice was taught in one session. The primary outcomes were required time and test score. The secondary outcomes were perceived mental fatigue and perceived difficulty for learning. The outcomes were assessed preintervention and immediately after the intervention (postintervention). The main results showed that both AOP and MIP improved the total time required and the test score, as well as entailed less perceived difficulty for learning. However, both strategies showed a higher level of mental fatigue after the intervention, which was higher in the MIP group. Based on the results obtained, it seems that the application of MRS promotes greater learning of manual motor tasks in physiotherapy students and could be used as educational innovation strategies
Multiparticle Biased DLA with surface diffusion: a comprehensive model of electrodeposition
We present a complete study of the Multiparticle Biased Diffusion-Limited
Aggregation (MBDLA) model supplemented with surface difussion (SD), focusing on
the relevance and effects of the latter transport mechanism. By comparing
different algorithms, we show that MBDLA+SD is a very good qualitative model
for electrodeposition in practically all the range of current intensities {\em
provided} one introduces SD in the model in the proper fashion: We have found
that the correct procedure involves simultaneous bulk diffusion and SD,
introducing a time scale arising from the ratio of the rates of both processes.
We discuss in detail the different morphologies obtained and compare them to
the available experimental data with very satisfactory results. We also
characterize the aggregates thus obtained by means of the dynamic scaling
exponents of the interface height, allowing us to distinguish several regimes
in the mentioned interface growth. Our asymptotic scaling exponents are again
in good agreement with recent experiments. We conclude by discussing a global
picture of the influence and consequences of SD in electrodeposition.Comment: 15 pages, 20 figures, accepted for publication in Physical Review
- …