305 research outputs found
Isotherm equation of sorption of electrolyte solutions on solids: how to do heterogeneous surface from homogeneous one?
It is a rather common phenomenon in the literature, that the surface accumulation processes are treated by different isotherm equations without taking into account the mechanism of the sorption processes. In this paper, a model calculation is presented for homovalent ion exchange process on energetically homogeneous surface. It reveals all incorrect conclusions which can be drawn in this way
Structural curiosities of lanthanide (Ln)-modified bentonites analyzed by radioanalytical methods
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Continued fraction representation of the Coulomb Green's operator and unified description of bound, resonant and scattering states
If a quantum mechanical Hamiltonian has an infinite symmetric tridiagonal
(Jacobi) matrix form in some discrete Hilbert-space basis representation, then
its Green's operator can be constructed in terms of a continued fraction. As an
illustrative example we discuss the Coulomb Green's operator in
Coulomb-Sturmian basis representation. Based on this representation, a quantum
mechanical approximation method for solving Lippmann-Schwinger integral
equations can be established, which is equally applicable for bound-, resonant-
and scattering-state problems with free and Coulombic asymptotics as well. The
performance of this technique is illustrated with a detailed investigation of a
nuclear potential describing the interaction of two particles.Comment: 7 pages, 4 ps figures, revised versio
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