117 research outputs found
First evidence for charge ordering in NaVO from Raman spectroscopy
We argue on the basis of symmetry selection rules and Raman scattering
spectra that NaVO undergoes a charge ordering phase transition at
T=34 K. Such a transition is characterized by the redistribution of the
charges at the phase transition and corresponds to the change of the vanadium
ions, from uniform V to two different V and V states. In
the low temperature phase the V ions are forming a "zig-zag" ladder
structure along the {\bf b}-axis, consistent with the symmetry of the P2/b
space group.Comment: to be published in solid state communication
Optical properties of NaxV2O5
The optical properties of sodium-deficient NaxV2O5 (0.85 < x <1) single
crystals are analyzed in the wide energy range, from 0.012 to 4.5 eV, using
ellipsometry, infrared reflectivity, and Raman scattering techniques. The
material remains insulating up to the maximal achieved hole concentration of
about 15%. In sodium deficient samples the optical absorption peak associated
to the fundamental electronic gap develops at about 0.44 eV. It corresponds to
the transition between vanadium dxy and the impurity band, which forms in the
middle of the pure NaV2O5 gap. Raman spectra measured with incident photon
energy larger then 2 eV show strong resonant behavior, due to the presence of
the hole-doping activated optical transitions, peaked at 2.8 eV.Comment: 7 pages, 4 fugures, to be published in PR
The in-plane electrodynamics of the superconductivity in Bi2Sr2CaCu2O8+d: energy scales and spectral weight distribution
The in-plane infrared and visible (3 meV-3 eV) reflectivity of
Bi2Sr2CaCu2O8+d (Bi-2212) thin films is measured between 300 K and 10 K for
different doping levels with unprecedented accuracy. The optical conductivity
is derived through an accurate fitting procedure. We study the transfer of
spectral weight from finite energy into the superfluid as the system becomes
superconducting. In the over-doped regime, the superfluid develops at the
expense of states lying below 60 meV, a conventional energy of the order of a
few times the superconducting gap. In the underdoped regime, spectral weight is
removed from up to 2 eV, far beyond any conventional scale. The intraband
spectral weight change between the normal and superconducting state, if
analyzed in terms of a change of kinetic energy is ~1 meV. Compared to the
condensation energy, this figure addresses the issue of a kinetic energy driven
mechanism.Comment: 13 pages with 9 figures include
The change of Fermi surface topology in Bi2Sr2CaCu2O8 with doping
We report the observation of a change in Fermi surface topology of
Bi2Sr2CaCu2O8 with doping. By collecting high statistics ARPES data from
moderately and highly overdoped samples and dividing the data by the Fermi
function, we answer a long standing question about the Fermi surface shape of
Bi2Sr2CaCu2O8 close to the (pi,0) point. For moderately overdoped samples
(Tc=80K) we find that both the bonding and antibonding sheets of the Fermi
surface are hole-like. However for a doping level corresponding to Tc=55K we
find that the antibonding sheet becomes electron-like. This change does not
directly affect the critical temperature and therefore the superconductivity.
However, since similar observations of the change of the topology of the Fermi
surface were observed in LSCO and Bi2Sr2Cu2O6, it appears to be a generic
feature of hole-doped superconductors. Because of bilayer splitting, though,
this doping value is considerably lower than that for the single layer
materials, which again argues that it is unrelated to Tc
Optical properties, electron-phonon coupling, and Raman scattering of vanadium ladder compounds
The electronic structure of two V-based ladder compounds, the quarter-filled
NaVO in the symmetric phase and the iso-structural half-filled
CaVO is investigated by ab initio calculations. Based on the
bandstructure we determine the dielectric tensor of these
systems in a wide energy range. The frequencies and eigenvectors of the fully
symmetric A phonon modes and the corresponding electron-phonon and
spin-phonon coupling parameters are also calculated from first-principles. We
determine the Raman scattering intensities of the A phonon modes as a
function of polarization and frequency of the exciting light.
All results, i.e. shape and magnitude of the dielectric function, phonon
frequencies and Raman intensities show very good agreement with available
experimental data.Comment: 11 pages, 10 figure
Absence of a pseudogap in the in-plane infrared response of Bi2Sr2CaCu2O(8+d)
The ab-plane reflectance of Bi2Sr2CaCu2O(8+d) thin films was measured in the
30-25000 cm^(-1) range for one underdoped (Tc = 70 K), and one overdoped sample
(Tc = 63 K) as a function of temperature (10-300 K). We find qualitatively
similar behaviors in the temperature dependence of the normal-state infrared
response of both samples. Above Tc, the effective spectral weight, obtained
from the integrated conductivity, does not decrease when T decreases, so that
no opening of an optical pseudogap is seen. We suggest that these are
consequences of the pseudogap opening first in the k=(0, pi) direction,
according to ARPES, and of the in-plane infrared conductivity being mostly
sensitive to the k=(pi, pi) direction.Comment: 11 pages, 3 figure
Anomalous electronic susceptibility in Bi2Sr2CuO6+d and comparison with other overdoped cuprates
We report magnetic susceptibility performed on overdoped Bi2Sr2CuO6+d powders
as a function of oxygen doping d and temperature T. The decrease of the spin
susceptibility with increasing T is confirmed. At sufficient high temperature,
the spin susceptibility Chi_s presents an unusual linear temperature dependence
Chi_s ~ Chi_s0 -Chi_1 T. Moreover, a linear correlation between Chi_1 and
Chi_s0 for increasing hole concentration is displayed. A temperature Tchi,
independent of hole doping characterizes this scaling. Comparison with other
cuprates of the literature(LSCO, Tl-2201 and Bi-2212), over the same overdoped
range, shows similarities with above results. These non conventional metal
features will be discussed in terms of a singular narrow-band structure.Comment: 16 pages, 4 figure
Electronic Spectra and Their Relation to the (pi,pi) Collective Mode in High-Tc Superconductors
Photoemission spectra of Bi2Sr2CaCu2O8 reveal that the high energy feature
near (pi,0), the "hump", scales with the superconducting gap and persists above
Tc in the pseudogap phase. As the doping decreases, the dispersion of the hump
increasingly reflects the wavevector (pi,pi) characteristic of the undoped
insulator, despite the presence of a large Fermi surface. This can be
understood from the interaction of the electrons with a collective mode,
supported by our observation that the doping dependence of the resonance
observed by neutron scattering is the same as that inferred from our data.Comment: 4 pages (revtex), 5 figures (eps
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