31,503 research outputs found

    Possible applications of soaring technology to drag reduction in powered general aviation aircraft

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    A brief examination of the performance figures achieved by modern soaring machines and a little reflection on the often huge disparity in L/D values between sailplanes and GA aircraft indicates that careful attention to lessons learned in sailplane design and manufacture hold realistic promise for substantial gains in the aerodynamic efficiency of several GA types

    A route generator concept for aircraft onboard fault monitoring

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    Because of the increasingly complex environments in which the flight crews of commercial aviation aircraft must operate, a research effort is currently underway at NASA Langley Research Center to investigate the potential benefits of intelligent cockpit aids, and to establish guidelines for the application of artificial intelligence techniques to advanced flight management concepts. The segment of this research area that concentrates on automated fault monitoring and diagnosis requires that a reference frame exist, against which the current state of the aircraft may be compared to determine the existence of a fault. This paper describes a computer program which generates the position of that reference frame that specifies the horizontal flight route

    Outer-Sphere Effects on Reduction Potentials of Copper Sites in Proteins: The Curious Case of High Potential Type 2 C112D/M121E Pseudomonas aeruginosa Azurin

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    Redox and spectroscopic (electronic absorption, multifrequency electron paramagnetic resonance (EPR), and X-ray absorption) properties together with X-ray crystal structures are reported for the type 2 Cu^(II) C112D/M121E variant of Pseudomonas aeruginosa azurin. The results suggest that Cu^(II) is constrained from interaction with the proximal glutamate; this structural frustration implies a “rack” mechanism for the 290 mV (vs NHE) reduction potential measured at neutral pH. At high pH (~9), hydrogen bonding in the outer coordination sphere is perturbed to allow axial glutamate ligation to Cu^(II), with a decrease in potential to 119 mV. These results highlight the role played by outer-sphere interactions, and the structural constraints they impose, in determining the redox behavior of transition metal protein cofactors

    Structures and Reactivity Patterns of Group 9 Metallocorroles

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    Group 9 metallocorroles 1-M(PPh_3) and 1-M(py)_2 [M = Co(III), Rh(III), Ir(III); 1 denotes the trianion of 5,10,15-tris-pentafluorophenylcorrole] have been fully characterized by structural, spectroscopic, and electrochemical methods. Crystal structure analyses reveal that average metal−N(pyrrole) bond lengths of the bis-pyridine metal(III) complexes increase from Co (1.886 Å) to Rh (1.957 Å)/Ir (1.963 Å); and the average metal−N(pyridine) bond lengths also increase from Co (1.995 Å) to Rh (2.065 Å)/Ir (2.059 Å). Ligand affinities for 1-M(PPh_3) axial coordination sites increase dramatically in the order 1-Co(PPh_3) < 1-Rh(PPh_3) < 1-Ir(PPh_3). There is a surprising invariance in the M(+/0) reduction potentials within the five- and six-coordinate corrole series, and even between them; the average M(+/0) potential of 1-M(PPh_3) is 0.78 V vs Ag/AgCl in CH_2Cl_2 solution, whereas that of 1-M(py)_2 is 0.70 V under the same conditions. Electronic structures of one-electron-oxidized 1-M(py)_2 complexes have been assigned by analysis of electron paramagnetic resonance spectroscopic measurements: oxidation is corrole-centered for 1-Co(py)_2 (g = 2.008) and 1-Rh(py)_2 (g = 2.003), and metal-centered for 1-Ir(tma)_2 (g_(zz) = 2.489, g_(yy) = 2.010, g_(xx) = 1.884, g_(av) = 2.128) and 1-Ir(py)_2 (g_(zz) = 2.401, g_(yy) = 2.000, g_(xx) = 1.937, g_(av) = 2.113)

    Sustaining Collection Value: Managing Collection/Item Metadata Relationships

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    Many aspects of managing collection/item metadata relationships are critical to sustaining collection value over time. Metadata at the collection-level not only provides context for finding, understanding, and using the items in the collection, but is often essential to the particular research and scholarly activities the collection is designed to support. Contemporary retrieval systems, which search across collections, usually ignore collection level metadata. Alternative approaches, informed by collection-level information, will require an understanding of the various kinds of relationships that can obtain between collection-level and item-level metadata. This paper outlines the problem and describes a project that is developing a logic-based framework for classifying collection-level/item-level metadata relationships. This framework will support (i) metadata specification developers defining metadata elements, (ii) metadata librarians describing objects, and (iii) system designers implementing systems that help users take advantage of collection-level metadata.Institute for Museum and Libary Services (Grant #LG06070020)published or submitted for publicationis peer reviewe

    Developmental design, fabrication, and test of acoustic suppressors for fans of high bypass turbofan engines

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    An analysis procedure was developed for design of acoustically treated nacelles for high bypass turbofan engines. The plan was applied to the conceptual design of a nacelle for the quiet engine typical of a 707/DC-8 airplane installation. The resultant design was modified to a test nacelle design for the NASA Lewis quiet fan. The acoustic design goal was a 10 db reduction in effective perceived fan noise levels during takoff and approach. Detailed nacelle designs were subsequently developed for both the quiet engine and the quiet fan. The acoustic design goal for each nacelle was 15 db reductions in perceived fan noise levels from the inlet and fan duct. Acoustically treated nacelles were fabricated for the quiet engine and quiet fan for testing. Performance of selected inlet and fan duct lining configurations was experimentally evaluated in a flow duct. Results of the tests show that the linings perform as designed

    Resolving The ISM Surrounding GRBs with Afterglow Spectroscopy

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    We review current research related to spectroscopy of gamma-ray burst (GRB) afterglows with particular emphasis on the interstellar medium (ISM) of the galaxies hosting these high redshift events. These studies reveal the physical conditions of star-forming galaxies and yield clues to the nature of the GRB progenitor. We offer a pedagogical review of the experimental design and review current results. The majority of sightlines are characterized by large HI column densities, negligible molecular fraction, the ubiquitous detection of UV pumped fine-structure transitions, and metallicities ranging from 1/100 to nearly solar abundance.Comment: Conference procedings for Gamma Ray Bursts 2007 November 5-9, 2007 Santa Fe, New Mexico (8 pages, 4 figures

    Kissing Bonds in Diffusion Bonded Parts

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    The widespread application of diffusion bonding has been hindered, in part, by concerns over kissing bonds. Kissing bonds are generally considered to be conditions where a bond has little or no strength and the concern is that such conditions might escape detection. At Rohr we differentiate between an intimate contact disbond (which has no bond between the surfaces but is detectable by careful ultrasonic testing) and a kissing bond (which also has no bond between the surfaces but is not detectable using current ultrasonic technology). These definitions will be used throughout

    Properties of the solvation force of a two-dimensional Ising strip in scaling regimes

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    We consider d=2 Ising strip with surface fields acting on boundary spins. Using the properties of the transfer matrix spectrum we identify two pseudotransition temperatures and show that they satisfy similar scaling relations as expected for real transition temperatures in strips with d>2. The solvation force between the boundaries of the strip is analysed as a function of temperature, surface fields and the width of the strip. For large widths the solvation force can be described by scaling functions in three different regimes: in the vicinity of the critical wetting temperature of 2D semi-infinite system, in the vicinity of the bulk critical temperature, and in the regime of weak surface fields where the critical wetting temperature tends towards the bulk critical temperature. The properties of the relevant scaling functions are discussed
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