157 research outputs found
Validity of the scaling functional approach for polymer interfaces as a variational theory
We discuss the soundness of the scaling functional (SF) approach proposed by
Aubouy Guiselin and Raphael (Macromolecules 29, 7261 (1996)) to describe
polymeric interfaces. In particular, we demonstrate that this approach is a
variational theory. We emphasis the role of SF theory as an important link
between ground-state theories suitable to describe adsorbed layers, and
"classical" theories for polymer brushes.Comment: 8 pages, 1 figure, to be published in Phys. Rev.
Effective interactions and phase behaviour for a model clay suspension in an electrolyte
Since the early observation of nematic phases of disc-like clay colloids by
Langmuir in 1938, the phase behaviour of such systems has resisted theoretical
understanding. The main reason is that there is no satisfactory generalization
for charged discs of the isotropic DLVO potential describing the effective
interactions between a pair of spherical colloids in an electrolyte. In this
contribution, we show how to construct such a pair potential, incorporating
approximately both the non-linear effects of counter-ion condensation (charge
renormalization) and the anisotropy of the charged platelets. The consequences
on the phase behaviour of Laponite dispersions (thin discs of 30 nm diameter
and 1 nm thickness) are discussed, and investigation into the mesostructure via
Monte Carlo simulations are presented.Comment: LaTeX, 12 pages, 11 figure
Effective interactions in the colloidal suspensions from HNC theory
The HNC Ornstein-Zernike integral equations are used to determine the
properties of simple models of colloidal solutions where the colloids and ions
are immersed in a solvent considered as a dielectric continuum and have a size
ratio equal to 80 and a charge ratio varying between 1 and 4000. At an infinite
dilution of colloids, the effective interactions between colloids and ions are
determined for ionic concentrations ranging from 0.001 to 0.1 mol/l and
compared to those derived from the Poisson-Boltzmann theory. At finite
concentrations, we discuss on the basis of the HNC results the possibility of
an unambiguous definition of the effective interactions between the colloidal
molecules.Comment: 26 pages, 15 figure
Exact asymptotic expansions for the cylindrical Poisson-Boltzmann equation
The mathematical theory of integrable Painleve/Toda type systems sheds new
light on the behavior of solutions to the Poisson-Boltzmann equation for the
potential due to a long rod-like macroion. We investigate here the case of
symmetric electrolytes together with that of 1:2 and 2:1 salts. Short and large
scale features are analyzed, with a particular emphasis on the low salinity
regime. Analytical expansions are derived for several quantities relevant for
polyelectrolytes theory, such as the Manning radius. In addition, accurate and
practical expressions are worked out for the electrostatic potential, which
improve upon previous work and cover the full range of radial distances
Evidence of environmental strains on charge injection in silole based organic light emitting diodes
Using d. functional theory (DFT) computations, the authors demonstrated a
substantial skeletal relaxation when the structure of
2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole (BAS) is
optimized in the gas-phase comparing with the mol. structure detd. from
monocrystal x-ray diffraction. The origin of such a relaxation is explained by
a strong environmental strains induced by the presence of anthracene entities.
Also, the estn. of the frontier orbital levels showed that this structural
relaxation affects mainly the LUMO that is lowered of 190 meV in the gas phase.
To check if these theor. findings would be confirmed for thin films of BAS, the
authors turned to UV photoemission spectroscopy and/or inverse photoemission
spectroscopy and electrooptical measurements. The study of the c.d. or voltage
and luminance or voltage characteristics of an ITO/PEDOT/BAS/Au device clearly
demonstrated a very unusual temp.-dependent behavior. Using a thermally
assisted tunnel transfer model, this behavior likely originated from the
variation of the electronic affinity of the silole deriv. with the temp. The
thermal agitation relaxes the mol. strains in thin films as it is shown when
passing from the cryst. to the gas phase. The relaxation of the intramol. thus
induces an increase of the electronic affinity and, as a consequence, the more
efficient electron injection in org. light-emitting diodes
Nanofiber-based filters as novel barrier systems for nanomaterial exposure scenarios
In this article our latest advances in the development of efficient barrier systems against micro- and nano-particulate materials are presented. Nanofibrous polyamide 6 (PA6) mats were fabricated by electrospinning onto a nonwoven viscose substrate. The influence of electrospinning parameters including solution concentration, viscosity, and conductivity, were studied for the production of nonwovens with different fiber size distribution ranging from 74 to 261 nm in diameters. Moreover, the formation of nanowebs (30-40 nm) which are widely distributed among fibers was observed. By varying several process parameters, membranes with different thickness of the nanofiber layer and therefore air permeability and nanoparticle filtration efficiency were obtained.The financial support of this work was provided by MICINN (Spanish Ministry of Science and
Innovation) and ERDF (European Regional Development Fund) (ref: PSE-420000-2008-003)
Superparamagnetic iron oxide nanoparticle-loaded polyacrylonitrile nanofibers with enhanced arsenate removal performance
Novel nanocomposite sorbents of superparamagnetic iron oxide nanoparticles (SPION) supported onto electrospun polyacrylonitrile nanofibers were synthesized by a simple and scalable method. The influence of both nanofiber size and SPION loading on As(V) adsorption capacity was studied and optimization was conducted. A maximum uptake capacity of 32.5 mmol As(V) per gram SPION in batch mode tests using an extremely low loading of only 2.9 mg of SPION per gram of adsorbent was achieved. This represents a remarkable improvement of 36 times compared with SPION in suspension. The optimal material was tested in continuous flow operation mode, reaching an adsorption capacity of 851.7 mg As(V) per gram of adsorbent at pH 3.8. It is also demonstrated that the new adsorbents can retain high performance when tested under real conditions using polluted wastewater from a lixiviation dump containing a large amount of competing anions (Cl- and F- ) and interfering cations (K+, Na+, Mg2+, and Ca2+). Furthermore, there was no release of nanoparticles observed during the operation and the spent porous material can be compressed, generating a small amount of solid waste that can be easily treated or stored
Arsenate removal with 3-mercaptopropanoic acid-coated superparamagnetic iron oxide nanoparticles
In the present work, superparamagnetic iron oxide nanoparticles (SPION) surface-coated with 3-mercaptopropanoic acid (3-MPA) were prepared and their feasibility for the removal of arsenate from dilute aqueous solutions was demonstrated. The synthesized 3-MPA-coated SPION was characterized using transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and Fourier transform infra-red spectrometry (FTIR). Separation efficiency of the coated nanoparticles and the equilibrium isotherm of arsenate adsorption were investigated. The obtained results reveal the arsenate adsorption to be highly pH-dependent, and the maximum adsorption was attained in less than 60 min. The resulting increase of 3-MPA-coated SPION adsorption capacity to twice the adsorption capacity of SPION alone under the same conditions is attributed to the increase of active adsorption sites. An adsorption reaction is proposed. On the other hand, efficient recovery of arsenate from the loaded nanoparticles was achieved using nitric acid (HNO3) solution, which also provides a concentration over the original arsenate solutio
Inverse lift: a signature of the elasticity of complex fluids?
To understand the mechanics of a complex fluid such as a foam we propose a
model experiment (a bidimensional flow around an obstacle) for which an
external sollicitation is applied, and a local response is measured,
simultaneously. We observe that an asymmetric obstacle (cambered airfoil
profile) experiences a downards lift, opposite to the lift usually known (in a
different context) in aerodynamics. Correlations of velocity, deformations and
pressure fields yield a clear explanation of this inverse lift, involving the
elasticity of the foam. We argue that such an inverse lift is likely common to
complex fluids with elasticity.Comment: 4 pages, 4 figures, revised version, submitted to PR
- …