Identification of fullerene-like CdSe nanoparticles from optical spectroscopy calculations

Semiconducting nanoparticles are the building blocks of optical nanodevices as their electronic states, and therefore light absorption and emission, can be controlled by modifying their size and shape. CdSe is perhaps the most studied of these nanoparticles, due to the efficiency of its synthesis, the high quality of the resulting samples, and the fact that the optical gap is in the visible range. In this article, we study light absorption of CdSe nanostructures with sizes up to 1.5 nm within density functional theory. We study both bulk fragments with wurtzite symmetry and novel fullerene-like core-cage structures. The comparison with recent experimental optical spectra allows us to confirm the synthesis of these fullerene-like CdSe clusters

Generalized scalar field models with the same energy density and linear stability

We study how the properties of a Lagrangian density for a single real scalar field in flat spacetime change with inclusion of an overall factor depending only on the field. The focus of the paper is to obtain analytical results. So, we show that even though it is possible to perform a field redefinition to get an equivalent canonical model, it is not always feasible to write the canonical model in terms of elementary functions. Also, we investigate the behavior of the energy density and the linear stability of the solutions. Finally, we show that one can find a class of models that present the same energy density and the same stability potential.Comment: 6 pages, 4 figure

Time and energy-resolved two photon-photoemission of the Cu(100) and Cu(111) metal surfaces

We present calculations on energy- and time-resolved two-photon photoemission spectra of images states in Cu(100) and Cu(111) surfaces. The surface is modeled by a 1D effective potential and the states are propagated within a real-space, real-time method. To obtain the energy resolved spectra we employ a geometrical approach based on a subdivision of space into two regions. We treat electronic inelastic effects by taking into account the scattering rates calculated within a GW scheme. To get further insight into the decaying mechanism we have also studied the effect of the variation of the classical Hartree potential during the excitation. This effect turns out to be small.Comment: 11 pages, 7 figure

Analytic vortex solutions in generalized models of the Maxwell-Higgs type

This work deals with the presence of analytical vortex configurations in generalized models of the Maxwell-Higgs type in the three-dimensional spacetime. We implement a procedure that allows to decouple the first order equations, which we use to solve the model analytically. The approach is exemplified with three distinct models that show the robustness of the construction. In the third model, one finds analytical solutions that exhibit interesting compact vortex behavior.Comment: 9 pages, 10 figures. To appear in PL

Compact Structures in Standard Field Theory

We investigate the presence of static solutions in models described by real scalar field in two-dimensional spacetime. After taking advantage of a procedure introduced sometime ago, we solve intricate nonlinear ordinary differential equations and illustrate how to find compact structures in models engendering standard kinematics. In particular, we study linear stability and show that all the static solutions we have found are linearly stable.Comment: 6 pages, 11 figures; version published in EP

From Kinks to Compactons

This work deals with the presence of localized structures in relativistic systems described by a single real scalar field in two-dimensional spacetime. We concentrate on kinks and compactons in models with standard kinematics, and we develop a procedure that help us to smoothly go from kinks to compactons in the suggested scenario. We also show how the procedure works in the braneworld scenario, for flat brane in the five-dimensional spacetime with a single extra dimension of infinite extent. The brane unveils a hybrid profile when the kink becomes a compacton, behaving as a thick or thin brane, depending on the extra dimension being inside or outside a compact space.Comment: 7 pages, 7 figures; new version, to appear in PL

Vortices in a generalized Maxwell-Higgs model with visible and hidden sectors

We investigate the presence of vortices in generalized Maxwell-Higgs models with a hidden sector. The model engenders $U(1)\times U(1)$ symmetry, in a manner that the sectors are coupled via the visible magnetic permeability depending only on the hidden scalar field. We develop a first order framework in which the hidden sector decouples from the visible one. We illustrate the results with two specific examples, that give rise to the presence of vortices with internal structure.Comment: 9 two-column pages, 4 figures; version to appear in AHE

Excitonic effects in the optical properties of CdSe nanowires

Using a first-principle approach beyond density functional theory we calculate the electronic and optical properties of small diameter CdSe nanowires.Our results demonstrate how some approximations commonly used in bulk systems fail at this nano-scale level and how indispensable it is to include crystal local fields and excitonic effects to predict the unique optical properties of nanowires. From our results, we then construct a simple model that describes the optical gap as a function of the diameter of the wire, that turns out to be in excellent agreement with experiments for intermediate and large diameters.Comment: submitte