936 research outputs found

    Ab initio molecular dynamics study of manganese porphine hydration and interaction with nitric oxide

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    The authors use ab initio molecular dynamics and the density functional theory+U (DFT+U) method to compute the hydration environment of the manganese ion in manganese (II) and manganese (III) porphines (MnP) dispersed in liquid water. These are intended as simple models for more complex water soluble porphyrins, which have important physiological and electrochemical applications. The manganese ion in Mn(II)P exhibits significant out-of-porphine plane displacement and binds strongly to a single H2O molecule in liquid water. The Mn in Mn(III)P is on average coplanar with the porphine plane and forms a stable complex with two H2O molecules. The residence times of these water molecules exceed 15 ps. The DFT+U method correctly predicts that water displaces NO from Mn(III)P-NO, but yields an ambiguous spin state for the MnP(II)-NO complex.Comment: 10 pages, 6 figure

    Impulse Response with Correlation Study of a Broadband Bended Wearable Monopole Antenna

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    In this paper, the impulse response of a wide band flexible circular monopole antenna is presented. The antenna is fabricated on liquid crystalline polymer flexible substrate with a compact geometry that makes it suitable for wearable applications under different bending conditions. The antenna is fed by coplanar waveguide transmission line and has a compact total size of 40 × 22 mm2. The presented antenna has a good performance over the operating frequency range for straight and bent configurations. The design principals, simulation and experimental results are presented in this work

    Evaluation of the Scope, Organization, Effectiveness and Approach of the Work of the United Nations in Mine Action

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    The objectives of the present evaluation are: to provide member States with an independent perspective on the performance of the United Nations in this area, and to inform the development of a new United Nations Inter-Agency Mine Action Strategy for the period 2011-2015. In carrying out the evaluation, the Inspectors looked into the approach, efficiency, effectiveness and coherence of the work of the United Nations in mine action, as set out in the United Nations Inter-Agency Mine Action Strategy for the period 2006-2010 (the Strategy), identified best practices and lessons learned and formulated recommendations with a view to strengthening the work and coordination among United Nations mine action actors

    Generalized ψ

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    The aim of this work is to introduce ψ-operations on fuzzy topological spaces and to use them to study fuzzy generalized ψρ-closed sets and fuzzy generalized ψρ-open sets. Also, we introduce some characterizations and properties for these concepts. Finally we show that certain results of several publications on the concepts of weakness and strength of fuzzy generalized closed sets are considered as corollaries of the results of this research

    New Insights on Avoiding the Causes of Projects Delays: A Framework

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    In this paper, we study and analyze the reasons behind the delay of some projects. Our aim is shed light on how one reduces the effect of the different obstacles and improves achievement either in quality or time. Different challenges play the main reasons in the stalled project including planning, designing, construction, and weak leaders or poor administrative decisions. We focus on developing a framework that helps in improving the management of the projects and finishing the projects on time. This includes developing a contingency plan and coordination mechanism between internal and external stakeholders. Following the steps of the methodology will help project managers to avoid project delay and solve the problems of the staled ones. Finally, we represent some managerial insights and recommendations that related parties should follow with the projects

    Non-Tensile Tunica Albuginea Plication for the Correction of Penile Curvature

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    Objective: To evaluate the efficacy of non-tensile tunica albuginea plication (NTTAP) using nonabsorbable sutures for the correction of congenital and acquired penile curvature and to determine the key points for a successful outcome of this procedure. Patients and Methods: From June 2004 to July 2007, 43 patients with penile curvature (35 congenital and 8 secondary to Peyronie’s disease) underwent surgical correction by NTTAP. The indications were difficult or impossible vaginal penetration, and a cosmetically unacceptable penis. For tunica albuginea plication (TAP) we applied the 16 dot procedure using non-absorbable sutures (Tycron® 2/0 polyester fiber).Results: After a mean follow-up period of 18 months, successful results with respect to penile straightening, normal erection, penetration and sensation, confirmed both subjectively and objectively, were achieved in all patients. Post-operative penile shortening of less than 1.5 cmwas present in 50% of the cases, but did not affect intercourse. Post-operative complications were mild and reversible; they consisted of penile skin necrosis after circumcising incisions and post-operative pain upon nocturnal erection that subsided after a few weeks with the frequent use of ice compresses. The overall satisfaction rate was nearly 100% (35/43 very satisfied and 8/43 satisfied).Conclusion:NTTAP is a simple and effective method for the correction of congenital and acquired penile curvature. The key points for successful outcomes are: clear identification of the line of maximum curvature, adequate pre-operative evaluation, counseling of the patient to setappropriate expectations, and careful discussion of the location of the suture sites. There is no need for mobilization of the urethra or neurovascular bundle, which adds a great advantage to this easy and simple technique. Cutting through the tunica albuginea, which may prevent postoperative erectile dysfunction, is not necessary. A disadvantage of this procedure is that it cannot correct hour-glass deformity

    Strategi penyampaian pesan dakwah di Radio Sufada UIN Sunan Ampel Surabaya

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    Penelitian ini bertujuan menjawab pertanyaan yaitu bagaimana strategi penyampaian pesan dakwah di radio SUFADA UIN Sunan Ampel Surabaya. Metode penelitian yang digunakan yaitu penelitian kualitatif dengan pendekatan deskriptif. Data primer dalam penelitian yaitu wawancara dengan General Manager radio Sufada, sedangkan data sekunder berupa buku ilmu dakwah, penelitian terdahulu, jurnal. Teknik pengumpulan data yang digunakan ialah menggunakan teknik observasi, wawancara dan dokumentasi.Hasil penelitian ini menyimpulkan bahwa strategi yang digunakan dalam penyampaiaan pesan dakwah di radio SUFADA UIN Sunan Ampel Surabaya yaitu Strategi sentimentil, strategi rasional dan strategi indrawi . Dimana strategi adalah penyampaian dakwah dengan strategi . Salah satunya ialah aplikasi keagamaan, keteladanan, serta pentas drama. Dalam hal ini ditandai dari tema dakwah yang sesuai dengan khalayak pendengar yakni terdiri dari mahasiswa, selain itu karena hal tersebutlah maka dakwah tersebut dikemas dengan pesan yang sesuai dengan kondisi dan keadaan lingkungan mahasiswa. Rekomendasi dan saran penelitian selanjutnya supaya bisa mengembangkan lebih dalam mengenai Radio SUFADA
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