76 research outputs found
Observation of collisions between cold Li atoms and Yb ions
We report on the observation of cold collisions between Li atoms and
Yb ions. This combination of species has recently been proposed as the most
suitable for reaching the quantum limit in hybrid atom-ion systems, due to its
large mass ratio. For atoms and ions prepared in the ground state,
the charge transfer and association rate is found to be at least~10 times
smaller than the Langevin collision rate. These results confirm the excellent
prospects of Li--Yb for sympathetic cooling and quantum information
applications. For ions prepared in the excited electronic states ,
and , we find that the reaction rate is dominated by
charge transfer and does not depend on the ionic isotope nor the collision
energy in the range ~1--120~mK. The low charge transfer rate for ground
state collisions is corroborated by theory, but the shell in the Yb
ion prevents an accurate prediction for the charge transfer rate of the
, and states. Using \textit{ab initio}
methods of quantum chemistry we calculate the atom-ion interaction potentials
up to energies of 30~cm, and use these to give qualitative
explanations of the observed rates.Comment: 8 pages, 7 figures (including appendices
Comparisons of trace constituents from ground stations and the DC-8 aircraft during PEM-West B
Chemical data from ground stations in Asia and the North Pacific are compared with data from the DC-8 aircraft collected during the Pacific Exploratory Measurements in the Western Pacific Ocean (PEM-West B) mission. Ground station sampling took place on Hong Kong, Taiwan, Okinawa, and Cheju; and at three Pacific islands, Shemya, Midway, and Oahu. Aircraft samples were collected during 19 flights, most over the western North Pacific. Aluminum was used as an indicator of mineral aerosol, and even though the aircraft did sample Asian dust, strong dust storms were not encountered. The frequency distribution for non-sea-salt sulfate (nss SO4=) in the aircraft samples was bimodal: the higher concentration mode (∼1 μg m−3) evidently originated from pollution or, less likely, from volcanic sources, while the lower mode, with a peak at 0.040 μg m−3, probably was a product of biogenic emissions. In addition, the concentrations of aerosol sulfate varied strongly in the vertical: arithmetic mean SO4=concentrations above 5000 m ( = 0.21±0.69 μg m−3) were substantially lower than those below ( = 1.07±0.87 μg m−3), suggesting the predominance of the surface sources. Several samples collected in the stratosphere exhibited elevated SO4=, however, probably as a result of emissions from Mount Pinatubo. During some boundary layer legs on the DC-8, the concentrations of CO and O3 were comparable to those of clean marine air, but during other legs, several chemically distinct air masses were sampled, including polluted air in which O3was photochemically produced. In general, the continental outflow sampled from the aircraft was substantially diluted with respect to what was observed at the ground stations. Higher concentrations of aerosol species, O3, and CO at the Hong Kong ground station relative to the aircraft suggest that much of the continental outflow from southeastern Asia occurs in the lower troposphere, and extensive long-range transport out of this part of Asia is not expected. In comparison, materials emitted farther to the north apparently are more susceptible to long-range transport
Buffer gas cooling of a trapped ion to the quantum regime
Great advances in precision quantum measurement have been achieved with
trapped ions and atomic gases at the lowest possible temperatures. These
successes have inspired ideas to merge the two systems. In this way one can
study the unique properties of ionic impurities inside a quantum fluid or
explore buffer gas cooling of the trapped ion quantum computer. Remarkably, in
spite of its importance, experiments with atom-ion mixtures remained firmly
confined to the classical collision regime. We report a collision energy of
1.15(0.23) times the -wave energy (or 9.9(2.0)~K) for a trapped
ytterbium ion in an ultracold lithium gas. We observed a deviation from
classical Langevin theory by studying the spin-exchange dynamics, indicating
quantum behavior in the atom-ion collisions. Our results open up numerous
opportunities, such as the exploration of atom-ion Feshbach resonances, in
analogy to neutral systems.Comment: 8 pages, 6 figures including appendice
Femtosecond two-photon photoassociation of hot magnesium atoms: A quantum dynamical study using thermal random phase wavefunctions
Two-photon photoassociation of hot magnesium atoms by femtosecond laser
pulses, creating electronically excited magnesium dimer molecules, is studied
from first principles, combining \textit{ab initio} quantum chemistry and
molecular quantum dynamics. This theoretical framework allows for rationalizing
the generation of molecular rovibrational coherence from thermally hot atoms
[L. Rybak \textit{et al.}, Phys. Rev. Lett. {\bf 107}, 273001 (2011)]. Random
phase thermal wave functions are employed to model the thermal ensemble of hot
colliding atoms. Comparing two different choices of basis functions, random
phase wavefunctions built from eigenstates are found to have the fastest
convergence for the photoassociation yield. The interaction of the colliding
atoms with a femtosecond laser pulse is modeled non-perturbatively to account
for strong-field effects
Modern applications of machine learning in quantum sciences
In these Lecture Notes, we provide a comprehensive introduction to the most recent advances in the application of machine learning methods in quantum sciences. We cover the use of deep learning and kernel methods in supervised, unsupervised, and reinforcement learning algorithms for phase classification, representation of many-body quantum states, quantum feedback control, and quantum circuits optimization. Moreover, we introduce and discuss more specialized topics such as differentiable programming, generative models, statistical approach to machine learning, and quantum machine learning
Comparisons of trace constituents from ground stations and the DC‐8 aircraft during PEM‐West B
Chemical data from ground stations in Asia and the North Pacific are compared with data from the DC‐8 aircraft collected during the Pacific Exploratory Measurements in the Western Pacific Ocean (PEM‐West B) mission. Ground station sampling took place on Hong Kong, Taiwan, Okinawa, and Cheju; and at three Pacific islands, Shemya, Midway, and Oahu. Aircraft samples were collected during 19 flights, most over the western North Pacific. Aluminum was used as an indicator of mineral aerosol, and even though the aircraft did sample Asian dust, strong dust storms were not encountered. The frequency distribution for non‐sea‐salt sulfate (nss SO4=) in the aircraft samples was bimodal: the higher concentration mode (∼1 μg m−3) evidently originated from pollution or, less likely, from volcanic sources, while the lower mode, with a peak at 0.040 μg m−3, probably was a product of biogenic emissions. In addition, the concentrations of aerosol sulfate varied strongly in the vertical: arithmetic mean SO4= concentrations above 5000 m ( = 0.21±0.69 μg m−3) were substantially lower than those below ( = 1.07±0.87 μg m−3), suggesting the predominance of the surface sources. Several samples collected in the stratosphere exhibited elevated SO4=, however, probably as a result of emissions from Mount Pinatubo. During some boundary layer legs on the DC‐8, the concentrations of CO and O3 were comparable to those of clean marine air, but during other legs, several chemically distinct air masses were sampled, including polluted air in which O3 was photochemically produced. In general, the continental outflow sampled from the aircraft was substantially diluted with respect to what was observed at the ground stations. Higher concentrations of aerosol species, O3, and CO at the Hong Kong ground station relative to the aircraft suggest that much of the continental outflow from southeastern Asia occurs in the lower troposphere, and extensive long‐range transport out of this part of Asia is not expected. In comparison, materials emitted farther to the north apparently are more susceptible to long‐range transport
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