The influence of Widmanstätten ferrite, martensite and grain boundary carbides on the strength and impact behaviour of high Al (0.2%) and Nb containing hot rolled steels

The influence of Al and Nb on the strength and impact behaviour of hot rolled 0.06%C, 1.4%Mn steels has been determined after hot rolling to 15 and 30 mm thick plate. When 0.16%Al was added to the plain C-Mn steel, the impact behaviour significantly improved even though Widmanstätten ferrite (WF) was present. This improvement was due to refinement of the grain boundary carbides and removing the N from solution as AlN. The hot rolled steels all contained WF but when Nb was added more WF formed as well as MA giving poor impact behaviour. Reducing the hardenability from that shown in previous work by decreasing C from 0.1 to 0.06%, Nb from 0.03 to 0.02%, and cooling rate from 33 to 17 K/min had no effect in improving the impact performance of hot rolled Nb steels. To ensure optimum properties not only is it necessary to reduce the hardenability, but WF formation must be discouraged by having a high Ar3. This can only be presently achieved by refining the austenite grain size via control rolling the Nb containing steels; the benefit of adding Al can then, readily be seen. Suggestions are made as to how this might be achieved for hot rolling

An overview of laser surface modification of die steels

In recent years, surface modification using advanced heat source like laser has been replacing the conventional methods to produce amorphous microstructure via rapid solidification. Due to the benefits of laser to enhance the tribological and mechanical properties of materials’ surface, several laser surface processing were developed including laser surface modification, namely laser alloying, transformation hardening, surface amorphization, shock hardening and glazing. In high temperature applications, the laser surface modification technique is beneficial to prolong the die life cycle, and also to improve the surface roughness of thermal barrier coatings (TBC). To produce the amorphous layer at a particular depth, laser parameter such as irradiance, frequency, and exposure time are controlled. Variations of parameter may result in modified microhardness properties of heat affected zone and transition zone. Nevertheless, works on laser glazing of bearings, railroad rails and TBC had proven the surface properties were enhanced through laser glazing to cope with excessive load, wear, fatigue, bending and friction demand

Thermal stability of laser treated die material for semi-solid metal forming

This paper presents laser surface modification work performed to improve the lifetime of die materials. Die material AISI H13, with typical hardness in the range of 42 to 48 HRC, offers high wear and corrosion resistance. However the cyclic high temperature conditions along with exposure to high viscosity molten metal in semi-solid forming cause the die to wear and crack with resultant shortened die lifetime. In this study, the thermal stability of die material at elevated temperature was investigated through micro-hardness testing and a metallographic study. AISI H13 samples were laser glazed using CO2 continuous wave mode laser with 10.6 μm wavelength. Samples were attached to a specially designed rotating chuck to enable it to be rotated at speeds up to 1500 rpm and allow flat surface glazing to take place. The micro-hardness was measured for as-glazed samples and annealed samples which were held at temperatures ranging from 550oC to 800oC with 50oC intervals. The metallographic study conducted examined the formation of three zones at different depths which were the glazed zone, the heat affected zone and the substrate. As a result of rapid heating and cooling from the laser glazing process, a metallic glass layer was developed which exhibited an average micro-hardness of 900 HV when exposed to 3.34E+10 W/m2 laser irradiance within a range of 0.0011 to 0.0018 s exposure time. Crystallization in glazed zone increased as the annealing temperature increased. As the annealing temperature reached above approximately 600oC, the micro-hardness decreased to approximately 600 HV (equivalent to approx. 54 HRC) due to local crystallization. These findings show potential direct application of glazed dies for non-ferrous semi-solid forming and the requirement for thermal barrier protection for application at higher temperatures

Impacts of Salinity on Soil Properties of Coastal Areas in Bangladesh

Sea level rise is a growing threat for the coastal regions of Bangladesh. It is one of the most densely populated countries of the world where 28% of the population are living in the coastal area. Bangladesh has already been affected by sea level rise through land erosion, salinity intrusion and loss in biodiversity. Saline soil has a detrimental effect upon soil physical and chemical properties. The dominant soil textural classes that occur in the saline areas of these regions are silty clay. In both of the soils pH value of the surface horizon is slightly lower than those of the subsoil and sub stratums. Cation Exchange Capacity (CEC) of all these soils varies from 12.0 to 27.6 meq/100 g soil expressing medium to high status. The organic matter content is medium to high at Asasuni and pretty low at Kalapara. In both areas, nutrient deficiencies of total nitrogen, phosphorous and potassium were quite dominant but sulphur was high. Exchangeable sodium, potassium, calcium and magnesium were in high level. The dominant water soluble cations were Na+, Ca2+, Mg2+ and K+ and anions Cl- and SO4 2-.The amount of accumulated salt was found higher at the surface and decreases with depth

Parametric study for graphene reinforced aluminum matrix composites production using Box Behnken design

The production of graphene reinforced aluminum matrix composite through powder metallurgical route requires optimization of process parameters to obtain better performance characteristics. One of the advanced method available for statistical analysis of parameters is Response Surface Methodology (RSM). The statistical analysis was carried out with three parameters, weight percentage of graphene reinforcement Wg (0.05%, 0.1% and 0.2%), stirring time ST(1h, 2h and 3h) and compaction pressure Pc(16T, 17T and 19T) while sintering temperature T kept constant. The performance of the Box Behnken design was analyzed and optimized using Design Expert software for the effective production of composites. From the results obtained from the analysis, the best set of parameters were considered for the future production of composites

Graphene and derivatives – Synthesis techniques, properties and their energy applications

2D nanomaterials with exceptional electrical, mechanical and thermal properties are promising reinforcing materials for fabricating high-performance composite materials. Rapid developments in nanotechnology in recent years have facilitated the development of advanced materials for functional devices. In particular, this review is focussed on the application of graphene nanoparticle-based composites (GNP's) and graphene derivatives in the fields of energy storage and conversion devices. This review focuses on these recent developments including the synthesis of graphene-based materials and its derivative, as well as the related achieved electrical, mechanical and thermal properties

Tomato yellow leaf curl virus (TYLCV) alters the phytochemical constituents in tomato fruits.

An investigation was conducted in order to evaluate the responses of field grown tomato varieties (Marglove and Roma VF) to tomato yellow leaf curl virus (TYLCV). Fruit samples from the virus-infected and uninfected plants were collected at 20 (early stage), 40 (intermediate stage) and 60 days (ripening stage) after anthesis. Results showed higher virus RNA content in fruits of infected plants at early (42.48 to 38.24%) and intermediate stages (34.35 to 19.57%). There was a substantial decrease in DNA content (27.27 and 21.05%) at early and (23.08 and 43.75%) at intermediate stages of both Marglove and Roma VF, compared to the control, respectively. Similarly, indole acetic acid content was also decreased (27.08 and 24.29%) in fruits of virus-infected Marglove and Roma VF, respectively. The free ascorbic acid content was found lower (35.29 to 51.52%), while combined ascorbic acid was higher (13.91 to 33.33%) in both varieties. Neither the responses of individual organic acids nor their concentrations in fruits of infected and control plants were identical. Fumaric acid was not detected either in fruits of infected plants of Marglove or in healthy and infected Roma VF. Individual fruit weight and fruit numbers per plant were lower in the virus-infected plants. This study indicates that the yield of infected tomato plants could be reduced by the infection of TYLCV due to the changes in the concentrations of phytochemical constituents. This suggests that monitoring and management of TYLCV incidence is crucial for yield and quality optimization of field grown tomato