295 research outputs found
In-situ Investigation of the Early Stage of TiO2 epitaxy on (001) SrTiO3
We report on a systematic study of the growth of epitaxial TiO2 films
deposited by pulsed laser deposition on Ti-terminated (001) SrTiO3 single
crystals. By using in-situ reflection high energy electron diffraction, low
energy electron diffraction, x-ray photoemission spectroscopy and scanning
probe microscopy, we show that the stabilization of the anatase (001) phase is
preceded by the growth of a pseudomorphic Sr-Ti-O intermediate layer, with a
thickness between 2 and 4 nm. The data demonstrate that the formation of this
phase is related to the activation of long range Sr migration from the
substrate to the film. The role of interface Gibbs energy minimization, as a
driving force for Sr diffusion, is discussed. Our results enrich the phase
diagram of the Sr-Ti-O system under epitaxial strain opening the roudeficient
SrTiO phase.Comment: 8 pages, 7 figure
Time-resolved photoluminescence of n-doped SrTiO_3
Following the recent surge of interest in n-doped strontium titanate as a
possible blue light emitter, a time-resolved photoluminescence analysis was
performed on nominally pure, Nb-doped and oxygen-deficient single-crystal
SrTiO3 samples. The doping-effects on both the electronic states involved in
the transition and the decay mechanism are respectively analyzed by comparing
the spectral and dynamic features and the yields of the emission. Our
time-resolved analysis, besides shedding some light on the basic recombination
mechanisms acting in these materials, sets the intrinsic bandwidth limit of the
proposed blue light emitting optoelectronic devices made of Ti-based
perovskites heterostructures in the GHz range
The ontogeny of continuous quantity discrimination in zebrafish larvae (Danio rerio).
Several studies have investigated the ontogeny of the capacity to discriminate between discrete numerical information in human and non-human animals. Contrarily, less attention has been devoted to the development of the capacity to discriminate continuous quantities. Recently, we set up a fast procedure for screening continuous quantity abilities in adult individuals of an animal model in neurodevelopmental research, the zebrafish. Two different sized holes are presented in a wall that divides the home tank in two halves and the spontaneous preference of fish for passing through the larger hole is exploited to measure their discrimination ability. We tested zebrafish larvae in the first, second and third week of life varying the relative size of the smaller circle (0.60, 0.75, 0.86, 0.91 area ratio). We found that the number of passages increased across the age. The capacity to discriminate the larger hole decreased as the ratio between the areas increased. No difference in accuracy was found as a function of age. The accuracy of larval zebrafish almost overlaps that found in adults in a previous study, suggesting a limited role of maturation and experience on the ability to estimate areas in this species
Charge density waves enhance the electronic noise of manganites
The transport and noise properties of Pr_{0.7}Ca_{0.3}MnO_{3} epitaxial thin
films in the temperature range from room temperature to 160 K are reported. It
is shown that both the broadband 1/f noise properties and the dependence of
resistance on electric field are consistent with the idea of a collective
electrical transport, as in the classical model of sliding charge density
waves. On the other hand, the observations cannot be reconciled with standard
models of charge ordering and charge melting. Methodologically, it is proposed
to consider noise-spectra analysis as a unique tool for the identification of
the transport mechanism in such highly correlated systems. On the basis of the
results, the electrical transport is envisaged as one of the most effective
ways to understand the nature of the insulating, charge-modulated ground states
in manganites.Comment: 6 two-column pages, 5 figure
Size discrimination in adult zebrafish (Danio rerio): Normative data and individual variation.
In humans, aging and neurodegenerative diseases have been found to be associated with impairment in both mathematical abilities and estimation of continuous quantities such as size, weight or distance. Zebrafish (Danio rerio) is rapidly becoming a model for human aging and brain disorders but we currently lack any instrument for rapid assessment of quantity estimation abilities in this species. Here we developed a simple method based on spontaneous preference of zebrafish for using the larger available hole to pass an obstacle. We collected a large amount of data from small groups of zebrafish moving between compartments of their tank and we used these normative data to compare the performance of individually tested fish. Zebrafish significantly discriminated size ratios from 0.60 to 0.91 with their performance decreasing while increasing the size ratio between the smaller and the larger hole presented. On average, individually tested fish showed the same performance, but a large inter-individual variability was observed. Test-retest analyses revealed a good reliability of this test, with 0.60 and 0.75 ratios being the most informative. Experience did not affect individual performance, suggesting the suitability of this test to measure the longitudinal changes and the effects of pharmacological treatments on cognitive abilities
Polar catastrophe and electronic reconstructions at the LaAlO3/SrTiO3 interface: evidence from optical second harmonic generation
The so-called "polar catastrophe", a sudden electronic reconstruction taking
place to compensate for the interfacial ionic polar discontinuity, is currently
considered as a likely factor to explain the surprising conductivity of the
interface between the insulators LaAlO3 and SrTiO3. We applied optical second
harmonic generation, a technique that a priori can detect both mobile and
localized interfacial electrons, to investigating the electronic polar
reconstructions taking place at the interface. As the LaAlO3 film thickness is
increased, we identify two abrupt electronic rearrangements: the first takes
place at a thickness of 3 unit cells, in the insulating state; the second
occurs at a thickness of 4-6 unit cells, i.e., just above the threshold for
which the samples become conducting. Two possible physical scenarios behind
these observations are proposed. The first is based on an electronic transfer
into localized electronic states at the interface that acts as a precursor of
the conductivity onset. In the second scenario, the signal variations are
attributed to the strong ionic relaxations taking place in the LaAlO3 layer
Vis-NIR luminescent lanthanide-doped core-shell nanoparticles for imaging and photodynamic therapy
The preparation of smart Ln:ZrO2@SiO2 nanoplatforms with grafted photosensitizer (Rose Bengal) which couple optical imaging with photo-dynamic therapy (PDT) is presented. A careful control of the lanthanide dopant loading is considered to enhance the photoemission properties of the lanthanide ions (Er, Pr, Yb) inside the ZrO2 crystal structure. The nanosystem with the lowest lanthanide loading maintains the size, phase and morphology of pristine ZrO2 nanoparticles and exhibit the best performances in term of the overall luminescence properties. Upon functionalization with a silica shell to covalently bound Rose Bengal, a theranostic platform is prepared which is very efficient in singlet oxygen generation, as demonstrated by EPR and UV\u2013vis spectroscopy studies. Preliminary cell viability tests show that while both pristine and Ln doped ZrO2 nanoparticles do not exert cytotoxicity, neither upon illumination nor in dark condition, Rose Bengal grafted samples are able to significantly reduce cell viability under light exposure, thus confirming the high potential of these nanoparticles as PDT tools
- …