Hydrogen Re-Embrittlement of Aerospace grade High Strength Steels

Hydrogen Re-Embrittlement on anodically coated high strength steels is a relevant risk for aerospace structures due to the possibility of hydrogen uptake during the operative life of the components. AISI 4340 and Maraging 250 unnotched tensile specimens were subjected to SSRT in order to evaluate the influence of test environment on time to failure. Fracture surfaces were examined by SEM analysis to evaluate the degree of embrittlement and to correlate it with hydrogen diffusivity of the tested steels

Hydrogen Re-embrittlement of Aerospace Grade High Strength Steels

Hydrogen Re-Embrittlement on anodically coated high strength steels is a relevant risk for aerospace structures due to the possibility of hydrogen uptake during the operative life of the components. AISI 4340 and Maraging 250 unnotched tensile specimens were subjected to SSRT in order to evaluate the influence of test environment on time to failure. Fracture surfaces were examined by SEM analysis to evaluate the degree of embrittlement and to correlate it with hydrogen diffusivity of the tested steels

Study of 13CR-4NI-(MO) (F6NM) steel grade heat treatment for maximum hardness control in industrial heats

The standard NACE MR0175 (ISO 15156) requires a maximum hardness value of 23 HRC for 13Cr-4Ni-(Mo) steel grade for sour service, requiring a double tempering heat treatment at temperature in the range 648–691°C for the first tempering and 593–621°C for the second tempering. Difficulties in limiting alloy hardness after the tempering of forged mechanical components (F6NM) are often faced. Variables affecting the thermal behavior of 13Cr-4Ni-(Mo) during single and double tempering treatments have been studied by means of transmission electron microscopy (TEM) observations, X-ray diffraction measurements, dilatometry, and thermo-mechanical simulations. It has been found that relatively low Ac1 temperatures in this alloy induce the formation of austenite phase above 600°C during tempering, and that the formed, reverted austenite tends to be unstable upon cooling, thus contributing to the increase of final hardness via transformation to virgin martensite. Therefore, it is necessary to increase the Ac1 temperature as much as possible to allow the tempering of martensite at the temperature range required by NACE without the detrimental formation of virgin martensite upon final cooling. Attempts to do so have been carried out by reducing both carbon (<0.02% C) and nitrogen (<100 ppm) levels. Results obtained herein show final hardness below NACE limits without an unacceptable loss of mechanical strength

Confirming the function of a Final Bronze Age wine processing site in the Nuraghe Genna Maria in Villanovaforru (South Sardinia)

The stone artefact in the hut γ of the NuragheGenna Maria, object of this study, is part of a compound still unpublished today and dated to the Nuragic period. It was found during a 1991 excavation, revealing a situation unchanged since the collapse occurred between the 10th and 9th century B.C., thus preserving the situation at the time of the collapse to this day. The presence of tartaric acid - the marker considered to determinate the presence of wines or products deriving from grapes - has been determined using HPLC-DAD and UHPLC-HQOMS. So the findings under examination, together with the overall evaluation of the archaeological aspects examined, suggests to positively consider the stone artifact as a "laccus" (the latin word for wine presses, still used in the Sardinian language today ) for grape crushing. The internal slope of the floor of the "laccus" allowed the extraction of juice with rapid separation of juice from berry skins. The presence in Sardinia of a large number of "stone wine presses" ("palmenti" in Italian) such as that of the Nuraghe Genna Maria studied in this article, brings a contribution to their dating and confirm the existence of an oenological industry on the island in the Archaic period (9th-10th century B.C.)

Application of Collagen I and IV in Bioengineering Transparent Ocular Tissues.

Collagens represent a major group of structural proteins expressed in different tissues and display distinct and variable properties. Whilst collagens are non-transparent in the skin, they confer transparency in the cornea and crystalline lens of the eye. There are 28 types of collagen that all share a common triple helix structure yet differ in the composition of their α-chains leading to their different properties. The different organization of collagen fibers also contributes to the variable tissue morphology. The important ability of collagen to form different tissues has led to the exploration and application of collagen as a biomaterial. Collagen type I (Col-I) and collagen type IV (Col-IV) are the two primary collagens found in corneal and lens tissues. Both collagens provide structure and transparency, essential for a clear vision. This review explores the application of these two collagen types as novel biomaterials in bioengineering unique tissue that could be used to treat a variety of ocular diseases leading to blindness

Considerations on the European wild grapevine (Vitis vinifera L. ssp. sylvestris (Gmelin) Hegi) and Phylloxera infestation

Research Note 

Hydrogen Re-Embrittlement of Aerospace grade High Strength Steels

Hydrogen Re-Embrittlement on anodically coated high strength steels is a relevant risk for aerospace structures due to the possibility of hydrogen uptake during the operative life of the components. AISI 4340 and Maraging 250 unnotched tensile specimens were subjected to SSRT in order to evaluate the influence of test environment on time to failure. Fracture surfaces were examined by SEM analysis to evaluate the degree of embrittlement and to correlate it with hydrogen diffusivity of the tested steels

Corrosione sotto sforzo su conserve di tonno sott’olio in banda stagnata

Nel presente lavoro sono stati analizzati alcuni casi di corrosione sotto sforzo (Stress Corrosion Cracking, SCC)su scatolette metalliche in banda stagnata per la conserva di tonno sott’olio. I contenitori metalliciprovenivano da due diversi fabbricanti di barattoli, con carni di diversi operatori del settore alimentare.In entrambi i casi sono state osservate microcricche fini e ramificate da SCC a ridosso delle regioni disaldatura. Dalle analisi chimiche del liquido associato ai prodotti sono state rilevate quantità sensibili di faseacquosa ed elevate concentrazioni di fosfati e cloruri, assieme a concentrazioni minori di bicarbonati e solfati.Gli esami in microscopia elettronica in scansione (SEM/EDS) hanno evidenziato all’interno delle lesionila presenza di prodotti di corrosione dell’acciaio frammisti a quantità sensibili soprattutto di fosfati.Tra i fattori scatenanti l’innesco della SCC hanno sicuramente importanza la separazione di fase acquosae le autotensioni in regione di saldatura. Occorre però anche una specificità dell’accoppiamento metalloambientee, in tal senso, l’ipotesi più probabile è l’abbondante presenza di fosfati in un ambiente acquosopraticamente deaerato. Da quanto osservato, questi anioni sembrano indurre anche inversione di polaritàtra acciaio al carbonio e deposito di stagno. Nel lavoro sono infine dati suggerimenti per minimizzarel’insorgenza di tali danneggiamenti

Metallic materials compatibility in E22 and M15 motor fuel blends

Factors influencing the potential corrosiveness of E22 and M15 motor fuels were studied using immersionand electrochemical corrosion tests. The latter were carried out using fuels at 18 °C and 50 °Cwith and without additions of water contaminants (inorganic acids, chloride ions, and salts).The corrosion behaviour of carbon steels (St 52, 100Cr6), stainless steels (AISI 304, AISI 440 C)and aluminium alloys (AlMg3, 6056 aluminium alloy) was evaluated.AISI 304 was fully compatible either in as-received or modified fuels in all experimental conditionshere imposed. AISI 440 C steel was able to develop a homogeneous passive film when was exposed at 18 °C,but a loss of corrosion resistance was detected when the temperature raised to 50 °C. Aluminium alloyswere the poorest performers in these fuels, exhibiting significant damaging under the form of surface pitting.Carbon steels exhibited reasonable resistances only in E22 and M15 fuels at 18 °C