Titanium dioxide nanoparticles catalyzed synthesis of Hantzsch esters and polyhydroquinoline derivatives

1,4-Dihydropyridine and polyhydroquinoline derivatives have been prepared efficiently in a one-pot synthesis via Hantzsch condensation using nanosized titanium dioxide as a heterogeneous catalyst. The present methodology offers several advantages such as excellent yields, short reaction times (30-120 min), environmentally benign, and mild reaction conditions. The catalyst can be readily separated from the reaction products and recovered in excellent purity for direct reuse

On the well-posedness of uncalibrated photometric stereo under general lighting

Uncalibrated photometric stereo aims at estimating the 3D-shape of a surface, given a set of images captured from the same viewing angle, but under unknown, varying illumination. While the theoretical foundations of this inverse problem under directional lighting are well-established, there is a lack of mathematical evidence for the uniqueness of a solution under general lighting. On the other hand, stable and accurate heuristical solutions of uncalibrated photometric stereo under such general lighting have recently been proposed. The quality of the results demonstrated therein tends to indicate that the problem may actually be well-posed, but this still has to be established. The present paper addresses this theoretical issue, considering first-order spherical harmonics approximation of general lighting. Two important theoretical results are established. First, the orthographic integrability constraint ensures uniqueness of a solution up to a global concave-convex ambiguity , which had already been conjectured, yet not proven. Second, the perspective integrability constraint makes the problem well-posed, which generalizes a previous result limited to directional lighting. Eventually, a closed-form expression for the unique least-squares solution of the problem under perspective projection is provided , allowing numerical simulations on synthetic data to empirically validate our findings

Urban solid waste landfill selection by SDSS. Case study: Hamadan

One of the major problems human beings are confronted with in urban setting is the removal of urban waste. This problem has persuaded the urban authorities to use various tools such as Geographic Information System (GIS) to locate landfills. To do that, Sloan Digital Sky Survey (SDSS) has been used in which or multi-criteria decision making (MCDM) methods and GIS are combined. The selection of the burial place and landfill has great importance and different criteria must be considered. SDSS, using MCDM is able to investigate locating landfill using various criteria simultaneously and it determines its importance. This research aims at presenting suitable solution through using computer and GIS related to solid urban waste and their locating in Hamadan based on standard criteria. A comprehensive model based on GIS, to get the suitable burial place and landfill can help to save time and cost. The model of locating burial place of urban solid waste has been presented

Réversibilité symbolique, hétérogénéité et socialisation.

Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and possessing inter-system correlations. Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a "temperature"-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature. We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.Comment: Accepted for publication in Quantum. v3 has 25+1 pages, 9 figures, significantly improved presentation after referees' comments, formatted using quantumarticle.cls; v2 has a new co-author added, a few lemmas are generalize

Spatial assessment of meteorological drought features over different climate regions in iran

Iran has a predominantly arid and semi-arid climate where the drought hazards and their variability are the crucial concerns for water resources management. This study assesses the characteristics and trends of meteorological droughts features in different climate regions of Iran. Monthly rainfall data are analysed using Standardized Precipitation Index (SPI) to reconstruct meteorological droughts for different time steps (1, 3, 6, 9 and 12). The drought events are decomposed into three features, namely Severity (S), Duration (D) and Peak (P) to assess their spatial variations in different climate regions. The Mann–Kendall (MK) test is used to detect the trends in drought features in different climate regions. The percentage area (PA) of increasing/decreasing trend in drought features is computed to assess the spatial variations of trends in each region. Besides, SPI is compared with Standardized Precipitation Evapotranspiration Index (SPEI) to understand the importance of evapotranspiration on meteorological droughts. The high correlations between SPI and SPEI indicate that the results obtained using SPI would not vary if a similar analysis is conducted using SPEI. The results obtained using SPI reveal that short-duration droughts (6 months or less) are more frequent and severe in the northwest and the north along the Caspian plains while the longer-duration droughts (more than 6 months) are more frequent and severe in the south, southeast and southwest. Overall, the northwest region of Iran is found most susceptible to droughts in terms of S, P and D. Moderate (40% 60%) increase in the drought features are observed in all climate regions for shorter SPI (3 months or less) except northwest, while no drought feature is found to increase significantly for SPI-12. Overall, the higher increase in drought S, P and D are found in the central arid region and at higher altitudes

On the well-posedness of uncalibrated photometric stereo under general lighting

International audienceUncalibrated photometric stereo aims at estimating the 3D-shape of a surface, given a set of images captured from the same viewing angle, but under unknown, varying illumination. While the theoretical foundations of this inverse problem under directional lighting are well-established, there is a lack of mathematical evidence for the uniqueness of a solution under general lighting. On the other hand, stable and accurate heuristical solutions of uncalibrated photometric stereo under such general lighting have recently been proposed. The quality of the results demonstrated therein tends to indicate that the problem may actually be well-posed, but this still has to be established. The present paper addresses this theoretical issue, considering first-order spherical harmonics approximation of general lighting. Two important theoretical results are established. First, the orthographic integrability constraint ensures uniqueness of a solution up to a global concave-convex ambiguity , which had already been conjectured, yet not proven. Second, the perspective integrability constraint makes the problem well-posed, which generalizes a previous result limited to directional lighting. Eventually, a closed-form expression for the unique least-squares solution of the problem under perspective projection is provided , allowing numerical simulations on synthetic data to empirically validate our findings