Thermal Desorption of Water-Ice in the Interstellar Medium

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity, and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H2O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (~50 molecular layers) is found to occur with zero order kinetics characterised by a surface binding energy, E_{des}, of 5773 +/- 60 K, and a pre-exponential factor, A, of 10^(30 +/- 2) molecules cm^-2 s^-1. These results imply that, in the dense interstellar medium, thermal desorption of H2O ice will occur at significantly higher temperatures than has previously been assumed.Comment: 9 pages, 4 figures, accepted for publication in MNRA

Chemical chronology of the Southern Coalsack

We demonstrate how the observed H2O ice column densities toward three dense globules in the Southern Coalsack could be used to constrain the ages of these sources. We derive ages of ~10^5 yr, in agreement with dynamical studies of these objects. We have modelled the chemical evolution of the globules, and show how the molecular abundances are controlled by both the gas density and the initial chemical conditions as the globules formed. Based on our derived ages, we predict the column densities of several species of interest. These predictions should be straightforward to test by performing molecular line observationsComment: 10 pages, 4 figures, in press at MNRA

The Working Group on Meteor Showers Nomenclature: a History, Current Status and a Call for Contributions

During the IAU General Assembly in Rio de Janeiro in 2009, the members of Commission 22 established the Working Group on Meteor Shower Nomenclature, from what was formerly the Task Group on Meteor Shower Nomenclature. The Task Group had completed its mission to propose a first list of established meteor showers that could receive officially names. At the business meeting of Commission 22 the list of 64 established showers was approved and consequently officially accepted by the IAU. A two-step process is adopted for showers to receive an official name from the IAU: i) before publication, all new showers discussed in the literature are first added to the Working List of Meteor Showers, thereby receiving a unique name, IAU number and three-letter code; ii) all showers which come up to the verification criterion are selected for inclusion in the List of Established Meteor Showers, before being officially named at the next IAU General Assembly

Palaeolithic extinctions and the Taurid Complex

Intersection with the debris of a large (50-100 km) short-period comet during the Upper Palaeolithic provides a satisfactory explanation for the catastrophe of celestial origin which has been postulated to have occurred around 12900 BP, and which presaged a return to ice age conditions of duration ~1300 years. The Taurid Complex appears to be the debris of this erstwhile comet; it includes at least 19 of the brightest near-Earth objects. Sub-kilometre bodies in meteor streams may present the greatest regional impact hazard on timescales of human concern.Comment: 7 pages, 3 figures; accepted for Monthly Notices of the Royal Astronomical Society (definitive version will be available at www.blackwell-synergy.com

Oxygen Isotope Composition of Almahata Sitta

The name Almahata Sitta is applied collectively to some hundreds of stones that were found in a linear strewn field in the Nubian Desert coincident with the projected Earth-impacting orbit of the Asteroid 2008 TC3. Fragments of the meteorite were collected in December 2008 and March 2009, 2 to 5 months after the asteroid exploded in Earths atmosphere on 7 October 2008

Unusually Weak Diffuse Interstellar Bands toward HD 62542

As part of an extensive survey of diffuse interstellar bands (DIBs), we have obtained optical spectra of the moderately reddened B5V star HD 62542, which is known to have an unusual UV extinction curve of the type usually identified with dark clouds. The typically strongest of the commonly catalogued DIBs covered by the spectra -- those at 5780, 5797, 6270, 6284, and 6614 A -- are essentially absent in this line of sight, in marked contrast with other lines of sight of similar reddening. We compare the HD 62542 line of sight with others exhibiting a range of extinction properties and molecular abundances and interpret the weakness of the DIBs as an extreme case of deficient DIB formation in a dense cloud whose more diffuse outer layers have been stripped away. We comment on the challenges these observations pose for identifying the carriers of the diffuse bands.Comment: 20 pages, 4 figures; aastex; accepted by Ap

Noble Gases in Two Fragments of Different Lithologies from the Almahata Sitta Meteorite

The Almahata Sitta meteorite, whose preat-mospheric body was the asteroid 2008 TC3, fell on October 7, 2008 in the Nubian Desert in northern Sudan [e.g., 1, 2]. Numer-ous fragments have been recovered during several expeditions organized from December 2008 [2]. The meteorite was classified as an anomalous polymict ureilite with several different kinds of chondritic fragments [e.g., 3-5]. Noble gas studies performed on several fragments from the meteorite showed cosmic-ray expo-sure ages of about 20 My [e.g., 6-8], although slightly shorter ages were also reported in [9, 10]. Concentrations of trapped heavy noble gases are variable among the fragments of different lithologies [9, 10]. We report noble gas data on two samples from the #1 and #47 fragments [2], which were the same as those re-ported by Ott et al. [9]. Experimental Procedure: Weights of bulk samples #1 and #47 used in this work were 16.1 mg and 17.6 mg, respectively. Noble gases were extracted by stepwise heating at the tempera-tures of 800, 1200 and 1800C for #1 and 600, 800, 1000, 1200, 1400, 1600 and 1800C for #47. Concentrations and isotopic ra-tios of noble gases were measured with a modified-VG5400/MS-III at the Geochemical Research Center, University of Tokyo. Results and Discussion: Cosmogenic He and Ne are domi-nant in both #1 and #47, but trapped Ar, Kr and Xe concentra-tions are much higher in #47 than in #1, showing that noble gas compositions in #47 are similar to those of ureilites. 3He/21Ne and 22Ne/21Ne of cosmogenic He and Ne are 4.8 and 1.12 for #1 and 3.6 and 1.06 for #47, respectively, both of which plot on a Bern line [11]. This indicates negligible loss of cosmogenic 3He from #1 in our sample, unlike the low 3He/21Ne of 3.1 for #1 by Ott et al. [9]. Concentrations of cosmogenic 3He and 21Ne (10-8 cc/g) are 30 and 6.3 for #1 and 32 and 9.0 for #47, respectively, which are higher than those in [9] and give cosmic-ray exposure ages of ca. 20 My depending on assumed production rates. Rela-tive abundances of trapped 36Ar, 84Kr and 132Xe for #1 resemble those of Q-component, which is a dominant trapped noble gas component in chondrites. In contrast to #1, #47 plots below a trend for ureilites [12] as well as Q, which implies a partial loss of trapped 36Ar from the lithology of #47

Airborne Observation of the Hayabusa Sample Return Capsule Re-Entry

The Japan Aerospace Exploration Agency (JAXA) recently completed their Hayabusa asteroid exploration mission. Launched in 2003, Hayabusa made contact with, and retrieved a sample from, the near-Earth asteroid Itokawa in 2005. The sample return capsule (SRC) re-entered over the Woomera Test Range (WTR) in southern Australia on June 13, 2010, at approximately 11:21 pm local time (09:51 UTC). The SRC re-entry velocity was 12.2 km/s, making it the second-fastest Earth return velocity behind NASA s Stardust sample return capsule re-entry in 2006. From a space technology development perspective, Hayabusa s re-entry functioned as a rare flight experiment of an entry vehicle and its thermal protection system. In collaboration with the SETI Institute, NASA deployed its DC-8 airborne laboratory and a team of international researchers to Australia to observe the re-entry of the SRC. The use of an airborne platform enables observation above most clouds and weather and greatly diminishes atmospheric absorption of the optical signals. The DC-8 s flight path was engineered and flown to provide a view of the spacecraft that bracketed the heat pulse to the capsule. A suite of imaging instruments on board the DC-8 successfully recorded the luminous portion of the re-entry event. For approximately 70 seconds, the spectroscopic and radiometric instruments acquired images and spectra of the capsule, its wake, and destructive re-entry of the spacecraft bus. Figure 1 shows a perspective view of the WTR, the SRC re-entry trajectory, and the flight path of the DC-8. The SRC was jettisoned from the spacecraft bus approximately 3 hours prior to entry interface. Due to thruster failures on the spacecraft, it could not be diverted from the entry path and followed the trajectory of the SRC, where it burned up in the atmosphere between approximately 100 and 50 km altitude. Fortuitously, the separation distance between the spacecraft and SRC was sufficient to clearly resolve the SRC from the debris field of the burning spacecraft. Figure 2 shows a frame from a high-definition television camera on board the aircraft and denotes the locations of the SRC and spacecraft bus debris

A very public fireball

An appeal for witnesses to a fireball on 24 September produced an excellent response from the public; 55 eyewitnesses sent accounts. From their observations we calculated the radiant azimuth as 320degrees, and altitude,angle less than or equal to 20degrees. Without video or CCTV footage for control on the fireball's velocity or pre-entry orbit, we used software developed for dust impact experiments, to assess the most likely orbital trajectory. The highest probability solutions have a semimajor axis between 1.6 and 2.0 AU and an eccentricity of 0.4 to 0.5, corresponding to a typical near-Earth asteroid orbit. Of possible comet showers, the kappa Aquarids are within the calculated constraints. No fragments were found, despite considerable public interest, consistent with the absence of reports of a dust trail. Public response to this fireball demonstrates the great interest in meteoritic phenomena, particularly when, as in this case, participation in the scientific enquiry is actively encouraged

High-Density Amorphous Ice, the Frost on Interstellar Grains

Most water ice in the universe is in a form which does not occur naturally on Earth and of which only minimal amounts have been made in the laboratory. We have encountered this 'high-density amorphous ice' in electron diffraction experiments of low-temperature (T less than 30 K) vapor-deposited water and have subsequently modeled its structure using molecular dynamics simulations. The characteristic feature of high-density amorphous ice is the presence of 'interstitial' oxygen pair distances between 3 and 4 A. However, we find that the structure is best described as a collapsed lattice of the more familiar low-density amorphous form. These distortions are frozen in at temperatures below 38 K because, we propose, it requires the breaking of one hydrogen bond, on average, per molecule to relieve the strain and to restructure the lattice to that of low-density amorphous ice. Several features of astrophysical ice analogs studied in laboratory experiments are readily explained by the structural transition from high-density amorphous ice into low-density amorphous ice. Changes in the shape of the 3.07 gm water band, trapping efficiency of CO, CO loss, changes in the CO band structure, and the recombination of radicals induced by low-temperature UV photolysis all covary with structural changes that occur in the ice during this amorphous to amorphous transition. While the 3.07 micrometers ice band in various astronomical environments can be modeled with spectra of simple mixtures of amorphous and crystalline forms, the contribution of the high-density amorphous form nearly always dominates