2,349 research outputs found
A molecular dynamics computer simulation study of room-temperature ionic liquids. I. Equilibrium solvation structure and free energetics
Solvation in 1-ethyl-3-methylmidazolium chloride and in
1-ethyl-3-methylimidazolium hexafluorophosphate near equilibrium is
investigated via molecular dynamics computer simulations with diatomic and
benzenelike molecules employed as probe solutes. It is found that
electrostriction plays an important role in both solvation structure and free
energetics. The angular and radial distributions of cations and anions become
more structured and their densities near the solute become enhanced as the
solute charge separation grows. Due to the enhancement in structural rigidity
induced by electrostriction, the force constant associated with solvent
configuration fluctuations relevant to charge shift and transfer processes is
also found to increase. The effective polarity and reorganization free energies
of these ionic liquids are analyzed and compared with those of highly polar
acetonitrile. Their screening behavior of electric charges is also
investigated.Comment: 12 page
Built Environment Factors Influencing Walking to School Behaviors: A Comparison between a Small and Large US City
Citation: Kim HJ and Heinrich KM (2016) Built Environment Factors Influencing Walking to School Behaviors: A Comparison between a Small and Large US City. Front. Public Health 4:77. doi: 10.3389/fpubh.2016.00077A growing body of evidence supports the association between the built environment and children walking to school (WTS), but few studies have compared WTS behaviors in cities of different sizes. This case-comparison study utilized WTS data from fourth graders in the small city of Manhattan, KS, USA (N = 171, from all eight schools) and data from fourth graders in the large city of Austin, TX, USA (N = 671 from 19 stratified-sampled schools). The same survey instrument was used in both locations. After controlling for socioeconomic and demographic variables, built environment, neighborhood, and attitudinal differences were demonstrated by the odds ratios for WTS in the small city vs. the large city. WTS in the small city was more likely to be associated with walking paths/trails and sidewalk landscape buffers en route to school despite lower perceived neighborhood social cohesion, school bus availability, and parental concerns about crime, compared to WTS in the large city. Also, the small city lacked key pedestrian infrastructure elements that were present in the large city. This study highlights important differences related to WTS behaviors and, thus, provides key insights for encouraging WTS in cities of different sizes
Built Environment Factors Influencing Walking to School Behaviors: A Comparison between a Small and Large US City
Citation: Kim HJ and Heinrich KM (2016) Built Environment Factors Influencing Walking to School Behaviors: A Comparison between a Small and Large US City. Front. Public Health 4:77. doi: 10.3389/fpubh.2016.00077A growing body of evidence supports the association between the built environment and children walking to school (WTS), but few studies have compared WTS behaviors in cities of different sizes. This case-comparison study utilized WTS data from fourth graders in the small city of Manhattan, KS, USA (N = 171, from all eight schools) and data from fourth graders in the large city of Austin, TX, USA (N = 671 from 19 stratified-sampled schools). The same survey instrument was used in both locations. After controlling for socioeconomic and demographic variables, built environment, neighborhood, and attitudinal differences were demonstrated by the odds ratios for WTS in the small city vs. the large city. WTS in the small city was more likely to be associated with walking paths/trails and sidewalk landscape buffers en route to school despite lower perceived neighborhood social cohesion, school bus availability, and parental concerns about crime, compared to WTS in the large city. Also, the small city lacked key pedestrian infrastructure elements that were present in the large city. This study highlights important differences related to WTS behaviors and, thus, provides key insights for encouraging WTS in cities of different sizes
125 GeV Higgs as a pseudo-Goldstone boson in supersymmetry with vector-like matters
We propose a possibility of the 125 GeV Higgs being a pseudo-Goldstone boson
in supersymmetry with extra vector-like fermions. Higgs mass is obtained from
loops of top quark and vector-like fermions from the global symmetry breaking
scale f at around TeV. The mu, Bmu/mu \sim f are generated from the dynamics of
global symmetry breaking and the Higgs quartic coupling vanishes at f as tan
beta \simeq 1. The relation of msoft \sim with f \sim mu \sim m_soft
\sim TeV is obtained and large mu does not cause a fine tuning for the
electroweak symmetry breaking. The Higgs to di-photon rate can be enhanced from
the loop of uncolored vector-like matters. The stability problem of Higgs
potential with vector-like fermions can be nicely cured by the UV completion
with the Goldstone picture.Comment: 28 pages, 8 figure
Quantum operations with the time axis in a superposed direction
In the quantum theory, it has been shown that one can see if a process has
the time reversal symmetry by applying the matrix transposition and examining
if it remains physical. However, recent discoveries regarding the indefinite
causal order of quantum processes suggest that there may be other, more general
symmetry transformations of time besides the complete reversal. In this work,
we introduce an expanded concept of matrix transposition, the generalized
transposition, that takes into account general bipartite unitary
transformations of a quantum operation's future and past Hilbert spaces,
allowing for making the time axis definitely lie in a superposed direction,
which generalizes the previously studied `indefinite direction of time', i.e.,
superposition of the forward and the backward time evolution. This framework
may have applications in approaches that treat time and space equally like
quantum gravity, where the spatio-temporal structure is explained to emerge
from quantum mechanics. We apply this generalized transposition to investigate
a continuous generalization of perfect tensors, a dynamic version of tracing
out a subsystem, and the compatibility of multiple time axes in bipartite
quantum interactions. Notably, we demonstrate that when a bipartite interaction
is consistent with more distinct local temporal axes, there is a reduced
allowance for information exchange between the two parties in order to prevent
causality violations.Comment: 23 pages, 3 figures, typos corrected. An error was found in the proof
of Theorem 5 in the prvious version, thus it is replaced with Conjecture
A definitive number of atoms on demand: controlling the number of atoms in a-few-atom magneto-optical trap
A few 85Rb atoms were trapped in a micron-size magneto-optical trap with a
high quadrupole magnetic-field gradient and the number of atoms was precisely
controlled by suppressing stochastic loading and loss events via real-time
feedback on the magnetic field gradient. The measured occupation probability of
single atom was as high as 99%. Atoms up to five were also trapped with high
occupation probabilities. The present technique could be used to make a
deterministic atom source.Comment: 3 pages, 4 figure
The Stream-Stream Collision after the Tidal Disruption of a Star Around a Massive Black Hole
A star can be tidally disrupted around a massive black hole. It has been
known that the debris forms a precessing stream, which may collide with itself.
The stream collision is a key process determining the subsequent evolution of
the stellar debris: if the orbital energy is efficiently dissipated, the debris
will eventually form a circular disk (or torus). In this paper, we have
numerically studied such stream collision resulting from the encounter between
a 10^6 Msun black hole and a 1 Msun normal star with a pericenter radius of 100
Rsun. A simple treatment for radiative cooling has been adopted for both
optically thick and thin regions. We have found that approximately 10 to 15% of
the initial kinetic energy of the streams is converted into thermal energy
during the collision. The angular momentum of the incoming stream is increased
by a factor of 2 to 3, and such increase, together with the decrease in kinetic
energy, significantly helps the circularization process. Initial luminosity
burst due to the collision may reach as high as 10^41 erg/sec in 10^4 sec,
after which the luminosity increases again (but slowly this time) to a steady
value of a few 10^40 erg/sec in a few times of 10^5 sec. The radiation from the
system is expected to be close to Planckian with effective temperature of
\~10^5K.Comment: 19 pages including 12 figures; Accepted for publication in Ap
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