Coulometry and Calorimetry of Electric Double Layer Formation in Porous Electrodes

Coulometric measurements on salt-water-immersed nanoporous carbon electrodes reveal, at a fixed voltage, a charge decrease with increasing temperature. During far-out-of-equilibrium charging of these electrodes, calorimetry indicates the production of both irreversible Joule heat and reversible heat, the latter being associated with entropy changes during electric double layer (EDL) formation in the nanopores. These measurements grant experimental access --for the first time-- to the entropic contribution of the grand potential; for our electrodes, this amounts to roughly 25% of the total grand potential energy cost of EDL formation at large applied potentials, in contrast with point-charge model calculations that predict 100%. The coulometric and calorimetric experiments show a consistent picture of the role of heat and temperature in EDL formation and provide hitherto unused information to test against EDL models.Comment: 11 pages, 10 figure

Proton structure corrections to hyperfine splitting in muonic hydrogen

We present the derivation of the formulas for the proton structure-dependent terms in the hyperfine splitting of muonic hydrogen. We use compatible conventions throughout the calculations to derive a consistent set of formulas that reconcile differences between our results and some specific terms in earlier work. Convention conversion corrections are explicitly presented, which reduce the calculated hyperfine splitting by about 46 ppm. We also note that using only modern fits to the proton elastic form factors gives a smaller than historical spread of Zemach radii and leads to a reduced uncertainty in the hyperfine splitting. Additionally, hyperfine splittings have an impact on the muonic hydrogen Lamb shift/proton radius measurement, however the correction we advocate has a small effect there.Comment: 6 pages, 3 figure

Higher twist analysis of the proton g_1 structure function

We perform a global analysis of all available spin-dependent proton structure function data, covering a large range of Q^2, 1 < Q^2 < 30 GeV^2, and calculate the lowest moment of the g_1 structure function as a function of Q^2. From the Q^2 dependence of the lowest moment we extract matrix elements of twist-4 operators, and determine the color electric and magnetic polarizabilities of the proton to be \chi_E = 0.026 +- 0.015 (stat) + 0.021/-0.024 (sys) and \chi_B = -0.013 -+ 0.007 (stat) - 0.010/+0.012 (sys), respectively.Comment: 6 pages, 2 figures, to appear in Phys. Lett.

Self-Consistent Data Analysis of the Proton Structure Function g1 and Extraction of its Moments

The reanalysis of all available world data on the longitudinal asymmetry A|| is presented. The proton structure function g1 was extracted within a unique framework of data inputs and assumptions. These data allowed for a reliable evaluation of moments of the structure function g1 in the Q2 range from 0.2 up to 30 GeV2. The Q2 evolution of the moments was studied in QCD by means of Operator Product Expansion (OPE).Comment: Proceeding of 3rd International Symposium on the Gerasimov-Drell-Hearn Sum Rule and its extensions, Old Dominion University, Norfolk, Virginia June 2-5, 200

Сучасні глобальні процеси у світовій економіці та їх вплив на економічну безпеку держави

Мета роботи. Визначення особливостей формування системи економічної безпеки держави, взагалі, та України, зокрема, в сучасних умовах глобального розвитку світового господарства

Differential photoproduction cross sections of the Sigma(0)(1385), Lambda(1405), and Lambda(1520)

We report the exclusive photoproduction cross sections for the Sigma(0)(1385), Lambda(1405), and Lambda(1520) in the reactions gamma + p -\u3e K+ + Y* using the CLAS detector for energies from near the respective production thresholds up to a center-of-mass energy W of 2.85 GeV. The differential cross sections are integrated to give the total exclusive cross sections for each hyperon. Comparisons are made to current theoretical models based on the effective-Lagrangian approach and fit to previous data. The accuracy of these models is seen to vary widely. The cross sections for the Lambda(1405) region are strikingly different for the Sigma(+)pi(-), Sigma(0)pi(0), and Sigma(-)pi(+) decay channels, indicating the effect of isospin interference, especially at W values close to the threshold