1,054 research outputs found
An innovative, fast and facile soft-template approach for the fabrication of porous PDMS for oil-water separation
Oil wastewater and spilled oil caused serious environmental pollution and
damage to public health in the last years. Therefore, considerable efforts are
made to develop sorbent materials able to separate oil from water with high
selectivity and sorption capacity. However most of them are low reusable, with
low volume absorption capacity and poor mechanical properties. Moreover, the
synthesis is time-consuming, complex and expensive limiting its practical
application in case of emergency. Here we propose an innovative approach for
the fabrication of porous PDMS starting from an inverse water-in-silicone
procedure able to selectively collect oil from water in few seconds. The
synthesis is dramatically faster than previous approaches, permitting the
fabrication of the material in few minutes independently from the dimension of
the sponges. The porous material evidenced a higher volume sorption capacity
with respect to other materials already proposed for oil sorption from water
and excellent mechanical and reusability properties.This innovative fast and
simple approach can be successful in case of emergency, as oil spill accidents,
permitting in situ fabrication of porous absorbents
APPLICATION IN CULTURAL HERITAGE OF STEREOLITOGRAPHY TECHNIQUES FOR THE 3D REPRODUCTION
With the use of stereolithography, one of the most widespread and old rapid prototyping techniques, it is possible to reproduce objects, damaged or missing parts, faithful replicas of interest in the field of Cultural Heritage. In this work, some of the applications of the stereolithography technique to replicate objects or missing parts of artistic or cultural interest, are illustrated. The aim of the Authors is to highlight the potential, the advantages, and also the limits if any, of this technique when applied in the field of Cultural Heritage for various needs, reporting some real cases of objects obtained in the laboratory with stereolithography
Aging effects of aqueous environment on mechanical properties of calcium carbonate-modified epoxy resin
The purpose of this study was to assess the effects of different aqueous environments (i.e., demineralised, distilled and spring water) on the mechanical properties of a cold-cured bisphenolic epoxy resin modified with the addition of calcium carbonate filler, typically employed as structural adhesive. The parameters selected for the analysis have been; the kind of curing agent employed to cure the epoxy resin at ambient temperature (i.e., Mannich base and triethylenetetramine); the load of calcium carbonate added to liquid epoxy (i.e., from 1 to 3 g per 100 g of resin) and; the duration of the exposure to the different aging conditions (i.e., from 1 to 10 months). Cylindrical specimens of calcium carbonate-modified epoxy systems were tested in compression mode, before and after each of the aging regimes. The effect of the selected curing agents is very small, and they are both suitable for a cure at ambient temperature, on the unfilled epoxy on compressive maximum strength and strain at break; the choice of the hardener affects instead the compressive modulus. The CaCO3 amount was demonstrated to have a significant effect on the mechanical characteristics of un-aged epoxy systems, leading to growth in compressive modulus and maximum strength with reductions in strain at break. Generally speaking, the aging time noticeably affects the compressive properties of calcium carbonate-modified epoxies while almost negligible is the kind of water employed in each exposure regime. Notwithstanding the adverse effects of an aqueous environment on compressive mechanical properties of CaCO3-filled epoxies, these systems keep compressive modulus and maximum strength greater than, and close to, respectively, the same characteristics measured on unaged unfilled control epoxies, demonstrating the positive effect of the addition of this kind of filler to epoxy-based structural adhesives, especially with the addition of 2 and 3 g of CaCO3 per 100 g resin. The results obtained in this study demonstrated that it is possible to contrast the detrimental effects observed in cold-cured epoxy-based structural adhesives due to their aging in water upon the addition of limited amounts (particularly at 2 and 3 g per 100 g resin) of a cheap CaCO3 filler
Decoupling the role of verbal and non-verbal audience behavior on public speaking anxiety in virtual reality using behavioral and psychological measures
Analysis of the Technological Evolution of Materials Requirements Included in Reactor Pressure Vessel Manufacturing Codes
The growth of green energy technologies within the frame of the 7th Sustainable Development Goal (SDG) along with the concern about climatic changes make nuclear energy an attractive choice for many countries to ensure energy security and sustainable development as well as to actively address environmental issues. Unlike nuclear equipment (immovable goods), which are often well-catalogued and analyzed, the design and manufacturing codes and their standardized materials specifications can be considered movable and intangible goods that have not been thoroughly studied based on a detailed evaluation of the scientific and technical literature on the reactor pressure vessel (RPV) materials behavior. The aim of this work is the analysis of historical advances in materials properties research and associated standardized design codes requirements. The analysis, based on the consolidated U.S. Nuclear Regulatory Commission (NRC) Regulatory Guide (RG) 1.99 Rev.2 model, enables determination of the best materials options, corresponding to some of the most widely used material specifications such as WWER 15Kh2MFAA (used from the 1970s and 1980s; already in operation), ASME SA-533 Grade B Cl.1 (used in pressurized water reactor-PWR 2nd–4th; already in operation), DIN 20MnMoNi55 and DIN 22NiMoCr37 (used in PWR 2nd–4th) as well as ASTM A-336 Grade F22V (current designs). Consequently, in view of the results obtained, it can be concluded that the best options correspond to recently developed or well-established specifications used in the design of pressurized water reactors. These assessments endorse the fact that nuclear technology is continually improving, with safety being its fundamental pillar. In the future, further research related to the technical heritage from the evolution of materials requirements for other clean and sustainable power generation technologies will be performed
Study of the effect of the outer-strike point location on the divertor neutral pressure in JET-ILW using EDGE2D/EIRENE
Tomato oil encapsulation by α-, β-, and γ-Cyclodextrins: A comparative study on the formation of supramolecular structures, antioxidant activity, and carotenoid stability
Cyclodextrins (CDs) are oligosaccharides, comprising 6 (α), 7 (β), or 8 (γ) glucose residues, used to prepare oil-in-water emulsions and improve oil stability towards degradation. In this research, the aptitude of α-, β-, and γ-CDs to form complexes with a supercritical CO2 extracted lycopene-rich tomato oil (TO) was comparatively assessed. TO/CD emulsions and the resulting freeze-dried powders were characterized by microscopy, Fourier transform infrared-attenuated total reflection (FTIR-ATR), and differential scanning calorimetry (DSC), as well as for their antioxidant activity. Furthermore, carotenoid stability was monitored for 90 days at 25 and 4 ◦C. Confocal and SEM microscopy revealed morphological differences among samples. α- and β-CDs spontaneously associated into microcrystals assembling in thin spherical shells (cyclodextrinosomes, Ø ≈ 27 µm) at the oil/water interface. Much smaller (Ø ≈ 9 µm) aggregates were occasionally observed with γ-CDs, but most TO droplets appeared “naked”. FTIR and DSC spectra indicated that most CDs did not participate in TO complex formation, nevertheless structurally different interfacial complexes were formed. The trolox equivalent antioxidant capacity (TEAC) activity of emulsions and powders highlighted better performances of α- and β-CDs as hydrophobic antioxidants-dispersing agents across aqueous media. Regardless of CDs type, low temperature slowed down carotenoid degradation in all samples, except all-[E]-lycopene, which does not appear efficiently protected by any CD type in the long storage period
Does Size Matter? The Case of Piezoresistive Properties of Carbon Nanotubes/Elastomer Nanocomposite Synthesized through Mechanochemistry
The growing interest in piezoresistive sensors has favored the development of numerous approaches and materials for their fabrication. Within this framework, carbon nanotubes (CNTs) are often employed. However, CNTs are a heterogeneous material with different morphological characteristics in terms of length and diameter, and, so far, experimental studies have not usually considered the effect of these parameters on the final sensor performances. Here, we observe how, by simply changing the CNTs length in a solvent-free mechanochemistry fabrication method, different porous 3D elastomeric nanocomposites with different electrical and mechanical properties can be obtained. In particular, the use of longer carbon nanotubes allows the synthesis of porous nanocomposites with better mechanical stability and conductivity, and with a nine-times-lower limit of detection (namely 0.2 Pa) when used as a piezoresistive sensor. Moreover, the material prepared with longer carbon nanotubes evidenced a faster recovery of its shape and electrical properties during press/release cycles, thus allowing faster response at different pressures. These results provide evidence as to how CNTs length can be a key aspect in obtaining piezoresistive sensors with better properties
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