NUMERICAL SIMULATION OF PHOTOCURRENT IN A SOLAR CELL BASED AMORPHOUS SILICON

We propose in this work, a method of simulation based on the resolution of the equations of continuities for homostructures of silicon-based solar, and used a method of calculation the photocurrent delivered by the silicon solar cell applying the equations of continuities and the currents by analogy to the phenomena of loads transport according to the model of an homojunction n-a-Si:H/p-a-Si:H. We used Matlab software to simulate and optimize the layers thicknesses to achieve the maximum photocurrent generated under AM1.5 solar spectrum. The optimization of donor layer thickness shows clearly that the best results are obtained with the finest structures.  We worked out a numerical model based on the resolution of the equations of continuities who gave the results in good agreement with literature and which allowed, moreover a better control of the performances of the cells based on silicon, for their improvement

Isolation, synthesis and optimization of cyclopropanation process of 4-allyl-2-methoxyphenol

The synthesis of 4-((2,2-dichlorocyclopropyl)methyl)-2-methoxyphenol 2 have been accomplished by using cyclopropanation process and Reponse Surface Methodology [1,2]. This methodology was used to determine the optimal conditions for the cyclopropanation reaction of eugenol 1. The reaction time (X1) and the ratio of the reaction mixture’s solvent (X2) were the two investigated factors. The statistical analysis of this study indicates that both of these factors had significant effects on the cyclopropanation yield. The central composite design showed that polynomial regression models were in good agreement with the experimental results of the coefficient determination (0.95) of product 2 yield. The optimal conditions were 17.44 and 5.78 hours. In such condition, the predicted yield of the product 2 was 43.96%. Keywords: Eugenol; 4-((2,2-dichlorocyclopropyl)methyl)-2-methoxyphenol; Central composite design; Optimization experiment

Synthesis of pyrazolo-enaminones, bipyrazoles and pyrazolopyrimidines and evaluation of antioxidant and antimicrobial properties

A novel pyrazolo-enaminones, bipyrazoles and bipyrazolopyridines from 1-(5-hydroxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)butane-1,3-dione and 4-methyl-2-phenyl-2H-pyrazolo[3,4-b]pyridine-3,6(3aH,7H)-dione have been synthesized by assisted heating with microwave radiation without any catalyst. The pyridine and pyrazole ring formation has been developed from easily accessible enamino keto esters by formylation followed by intramolecular cyclization. The general applicability for the synthesis of the important pyrazolo-enaminones, bipyrazoles and pyrazolo-pyridines heterocycles was attributed to simplicity of operation, synthesis without catalyst, energy efficiency (shorter reaction time under microwave irradiation), good yields, more environmentally friendly and more cost-effective procedure. The antioxidant activity of new heterocyclic compounds was evaluated by free radical scavenging by DPPH assay. Several of these compounds showed good activity against both Gram-positive (S. aureus) and Gram-negative (E. coli) bacteria

Interaction of some essential amino acids with synthesized poorly crystalline hydroxyapatite

This study focused on the release of two essential amino acids, l-lysine and dl-leucine, previously adsorbed onto poorly crystalline hydroxyapatite of Ca/P = 1.59, synthesis by precipitation methods. The composition of the calcium-deficient hydroxyapatite (CDHA) is chemically and structurally similar to the bone mineral. Their surface reactivity is indeed linked to the existence of hydrated surface particles (HPO42- and Ca2+). The adsorption kinetics is very fast while the release kinetics is relatively slow. The adsorption rate reached approximately 70%, but the release rate did not exceed 12%. The chemical composition of solution has an influence on the release processes. The presence of phosphate ions favored the release of amino acids, while the calcium ions inhibited it. Also, the release process is slightly influenced by Ra (ml/mg) ratio and incubation temperature of the medium. The charged –COO− and NH3+ of amino acids are the strongest groups that interact with the surface of hydroxyapatite, the adsorption is mainly due to the electrostatic interaction between the groups –COO− of amino acids and calcium Ca2+ ions of the hydroxyapatite. dl-Leucine (non-polar) and l-Lysine (polar–basic) interact with the hydroxyapatite surface in the zwitterionic and cationic forms, respectively. The study of interactions between amino acids and hydroxyapatite is carried out in vitro by using UV–vis and infrared spectroscopy IR techniques

Growth and characterization of ZnO nanostructured thin films by successive ionic layer adsorption and reaction

The zinc oxide (ZnO) thin films were deposited onto the glass substrates by a novel chemical method, which is based on the alternate dipping of substrate in an alkaline zinc with ammonia formed zinc ammonia complex ([Zn(NH3)4]2+) solution and double-distilled water containing H2O2 (1%) at room temperature. The time duration for which the substrate is dipped in the precursor solution, plays an important role and it has been shown in this work that the time period for which a substrate is dipped in dilute H2O2 solution, which we referred as reaction period, affects significantly on the structural, surface morphological and optical properties. The as-deposited films were annealed at 300 and 400°C for 1h in air to improve the quality of the films. The as prepared nanostructured seed layer was characterized by X- ray diffraction (XRD) and scanning electron microscopy (SEM) studies showed that the films are covered well with glass substrates and have good polycrystalline structure and crystalline levels. The film thickness effect on band gap values was investigated and band gap values were found to be within the range of 3.8 – 3.2 eV

Removal of fluoride from aqueous solution by adsorption on hydroxyapatite (HAp) using response surface methodology

A study on the adsorption of fluoride onto hydroxyapatite was conducted and the process parameters were optimized using Response Surface Methodology (RSM). Hydroxyapatite has been characterized by using different physicochemical methods. In order to determine the effects of process parameters namely temperature (20–40 °C), initial solution pH (4–11), adsorbent dose (0.1–0.3 g) and initial fluoride concentration (10–20 mg L−1) on fluoride uptake from aqueous solution, a three-level, four-factor, Box–Behnken design has been employed. The second order mathematical model was developed by regression analysis of the experimental data obtained from 29 batch runs. The optimum pH, temperature, adsorbent dose and initial concentration were found by desirability function to be 4.16, 39.02 °C, 0.28 g and 20 mg L−1, respectively. Fluoride removal was 86.34% at the optimum combination of process parameters. Dynamic adsorption data were applied to pseudo-first-order and pseudo-second-order rate equations. The time data fitted well to pseudo second order kinetic model. According to the correlation coefficients, the adsorption of fluoride on the hydroxyapatite was correlated well with the Langmuir and Freundlich models

Interaction of adsorption of reactive yellow 4 from aqueous solutions onto synthesized calcium phosphate

The interaction of reactive yellow 4 with Apatitic Tricalcium Phosphate (PTCa) has been investigated in aqueous medium to understand the mechanism of adsorption and explore the potentiality of this phosphate toward controlling pollution resulting from textile dyes. Transmission electron microscopy (TEM) analysis demonstrates that the adsorbent is composed of needle-like nanoparticles and the SAED pattern exhibits spotted sharp and continuous rings that evidence polycrystalline grains. X-ray diffraction results showed that, the crystallinity of the dye decreased after interaction with RY4 indicatating incorporation of the dye into the micropores and macropores of the adsorbent. The results of Fourier transform infrared (FTIR) spectroscopy indicate that the adsorption is due to the electrostatic interaction between the –SO3- groups of dye and the surface of the Phosphate. The desorption efficiency was very high at about 99.4%. The presence of calcium ions favored the adsorption of the dye, while the phosphate ions inhibited it